All Stories

  1. High-resolution structural study on pyridin-3-yl ebselen and its N-methylated tosylate and iodide derivatives
  2. Synthesis and structure of clozapine N-oxide hemi(hydrochloride): an infinite hydrogen-bonded poly[n]catenane
  3. Structures of the hydrate and dihydrate forms of the DNA-binding radioprotector methylproamine
  4. Total synthesis of (±)-nicolaioidesin B via a highly regio- and diastereoselective Diels–Alder reaction
  5. The effects of σC—Se–π hyperconjugation in 1-methoxy- and 1-nitro-4-[(phenylselanyl)methyl]benzene
  6. Crystal structure of 2-(4-chlorophenyl)-2-oxoethyl 3-bromobenzoate
  7. Total syntheses of cis-cyclopropane fatty acids: dihydromalvalic acid, dihydrosterculic acid, lactobacillic acid, and 9,10-methylenehexadecanoic acid
  8. Oxidative damage of aromatic dipeptides by the environmental oxidants NO2˙ and O3
  9. Synthesis, Structural Characterization, and Gas-Phase Unimolecular Reactivity of the Silver Hydride Nanocluster [Ag3((PPh2)2CH2)3(μ3-H)](BF4)2
  10. Copper and Silver Complexes of Tris(triazole)amine and Tris(benzimidazole)amine Ligands: Evidence that Catalysis of an Azide–Alkyne Cycloaddition (“Click”) Reaction by a Silver Tris(triazole)amine Complex Arises from Copper Impurities
  11. Morphology Change and Improved Efficiency in Organic Photovoltaics via Hexa-peri-hexabenzocoronene Templates
  12. Preparation and X-ray analysis of potassium (2,3-dichlorophenyl)glucosinolate
  13. Radiolabelling and evaluation of a novel sulfoxide as a PET imaging agent for tumor hypoxia
  14. Convergent Access to Polycyclic Cyclopentanoids from α,β-Unsaturated Acid Chlorides and Alkynes through a Reductive Coupling, Nazarov Cyclization Sequence
  15. Simplified Silvestrol Analogues with Potent Cytotoxic Activity
  16. Understanding Electrogenerated Chemiluminescence Efficiency in Blue‐Shifted Iridium(III)‐Complexes: An Experimental and Theoretical Study
  17. Synthesis of the C1–C18 Fragment of Rhizopodin: Late-State Introduction of the Oxazole
  18. Mobile Proton Triggered Radical Fragmentation of Nitroarginine Containing Peptides
  19. Application of the Variable Oxygen Probe to Determine the π-Electron Donor Ability of the Alkyne Group
  20. Development of the Claisen Rearrangement/Organocatalytic Diels-Alder Approach for the Synthesis of Eunicellins*
  21. Phenylphenalenones and oxabenzochrysenones from the Australian plant Haemodorum simulans
  22. Diagnostic Imaging Agents for Alzheimer’s Disease: Copper Radiopharmaceuticals that Target Aβ Plaques
  23. Synthesis, characterization and metal ion complexation and extraction capabilities of calix[4]arene Schiff base compounds
  24. Asymmetric Synthesis of (+)- and (−)-Pauciflorol F: Confirmation of Absolute Stereochemistry
  25. A Click Chemistry Approach to 5,5′-Disubstituted-3,3′-Bisisoxazoles from Dichloroglyoxime and Alkynes: Luminescent Organometallic Iridium and Rhenium Bisisoxazole Complexes
  26. Structural Characterization and Unusual Reactivity of Oxosulfido-Mo(V) Compounds: Implications for the Structure and Electronic Description of the Very Rapid Form of Xanthine Oxidase
  27. Structural effects of potentially hexadentate Schiff base ligands involving pyrrolic, etheric or thioetheric donors towards zinc(II) cation: Synthesis, characterization and crystal structures
  28. Using Distonic Radical Ions to Probe the Chemistry of Key Combustion Intermediates: The Case of the Benzoxyl Radical Anion
  29. Halide-ion-templated Ag8Cu6 rhombic dodecahedrons: synthesis, structure and reactivity of [Ag8Cu6(CCtBu)12X]BF4 (X = Cl, Br)
  30. Hyperconjugation involving strained carbon–carbon bonds. Application of the variable oxygen probe to ester and ether derivatives of cubylmethanol
  31. Synthesis and photo-induced charge separation of confined conjugation length phenylene vinylene-based polymers
  32. Structure Correlation Study of Some Diels?Alder Cycloadducts of Anthracene
  33. Hyperconjugation Involving Strained Carbon–Carbon Bonds. Structural Analysis of Ester and Ether Derivatives and One-Bond 13C–13C Coupling Constants of α- and β-Nopinol
  34. Preventing Protein Oxidation with Sugars: Scavenging of Hypohalous Acids by 5-Selenopyranose and 4-Selenofuranose Derivatives
  35. Synthesis, molecular structure, NMR spectroscopic and computational analysis of a selective adenosine A2A antagonist, ZM 241385
  36. Total Synthesis of 2‴,5‴-Diepisilvestrol and Its C1‴ Epimer: Key Structure Activity Relationships at C1‴ and C2‴
  37. Simple and Efficient One-Pot Synthesis, Spectroscopic Characterization and Crystal Structure of Methyl 5-(4-Chlorobenzoyloxy)-1-phenyl-1H-pyrazole-3-carboxylate
  38. Diastereoselective synthesis of highly functionalized β2,2,3-substituted amino acids from 4-substituted-1,3-oxazinan-6-ones
  39. Ethyl 2,6-Dimethoxybenzoate: Synthesis, Spectroscopic and X-ray Crystallographic Analysis
  40. Oxazolidinone-Promoted, Torquoselective Nazarov Cyclizations
  41. Synthesis and Characterization of Novel 2-Amino-3-benzoylthiophene Derivatives as Biased Allosteric Agonists and Modulators of the Adenosine A1 Receptor
  42. Diastereoselectivity in unusual intermolecular tandem Michael reactions
  43. Copper complexes of a novel non-innocent quadridentate ligand
  44. The Synthesis of a Cubane-Substituted Dipeptide
  45. Electronic energy transfer in pendant MEH-PPV polymers
  46. Synthesis and X-Ray Crystal Structure of Cynandione B Analogues
  47. Structures of N,N-Dialkoxyamides: Pyramidal Anomeric Amides with Low Amidicity
  48. Solution and Gas-Phase Investigations of Trimethylsilylpropyl-Substituted Pyridinium Ions. Manifestation of the Silicon δ Effect
  49. Gallium-68 Complex of a Macrobicyclic Cage Amine Chelator Tethered to Two Integrin-Targeting Peptides for Diagnostic Tumor Imaging
  50. Formal total synthesis of the myxobacteria metabolite apicularen A via a transannular oxy-Michael addition
  51. Structural Systematics of the Anhydrous 1:1 Proton-Transfer Compounds of 3,5-Dinitrosalicylic Acid with Aniline and Monosubstituted Anilines
  52. A New Process for Synthesis of Apricitabine, 2-(R)-Hydroxymethyl-4-(R)-(cytosin-1′-yl)-1,3-oxathiolane, an Anti-HIV NRTI
  53. Synthesis of β,γ-Dihydroxyhomotyrosines by a Tandem Petasis–Asymmetric Dihydroxylation Approach
  54. Paramagnetic Oxotungsten(V) Complexes Containing the Hydrotris(3,5-dimethylpyrazol-1-yl)borate Ligand
  55. Synthesis and Fluorescence Characterization of MEHPPV Oligomers
  56. Synthesis of glycoconjugate fragments of mycobacterial phosphatidylinositol mannosides and lipomannan
  57. Orbital Interactions in Selenomethyl-Substituted Pyridinium Ions and Carbenium Ions with Higher Electron Demand
  58. Novel paramagnetic AT1 receptor antagonists
  59. Synthesis and antioxidant capacity of 5-selenopyranose derivatives
  60. Damage of aromatic amino acids by the atmospheric free radical oxidant NO3˙ in the presence of NO2˙, N2O4, O3 and O2
  61. Structure and unimolecular chemistry of protonated sulfur betaines, (CH3)2S+(CH2)nCO2H (n = 1 and 2)
  62. Quaternary Ammonium Spiroborate Esters and Mixed Anhydrides Derived from Aliphatic α-Hydroxy Acids and Diacids and their Wood Protection Properties
  63. The structures of four new himbacine-like Galbulimima alkaloids
  64. Water-soluble Bis(thiosemicarbazonato)copper(II) Complexes
  65. Cellular Up-regulation of Nedd4 Family Interacting Protein 1 (Ndfip1) using Low Levels of Bioactive Cobalt Complexes
  66. 1,3-Dipolar Cycloaddition−Decarboxylation Reactions of an Azomethine Ylide with Isatoic Anhydrides: Formation of Novel Benzodiazepinones
  67. A Reductive-Coupling plus Nazarov Cyclization Sequence in the Asymmetric Synthesis of Five-Membered Carbocycles
  68. cis-Dioxo- and cis-(Hydroxo)oxo-Mo(V) Complexes Stabilized by Intramolecular Hydrogen-Bonding
  69. Effects of Conformational Restriction of 2-Amino-3-benzoylthiophenes on A1 Adenosine Receptor Modulation
  70. Self‐Terminating Radical Cyclizations: How Are Thiyl Radicals Performing?
  71. Novel O,O′‐Donor Oxo‐MoIV Hydrotris(3‐isopropylpyrazolyl)borate Complexes Formed by Chelation of Potentially Hydrogen‐Bonding Phenolate Ligands on Reduction of Dioxo‐MoVI Complexes
  72. A Water-Soluble Bis(thiosemicarbazone) Ligand. A Sensitive Probe and Metal Buffer for Zinc
  73. Tricyclic-isoxazolidine analogues via intramolecular 1,3-dipolar cycloaddition reactions of nitrones
  74. Versatile New Bis(thiosemicarbazone) Bifunctional Chelators: Synthesis, Conjugation to Bombesin(7−14)-NH2, and Copper-64 Radiolabeling
  75. A hexadentate bis(thiosemicarbazonato) ligand: rhenium(v), iron(iii) and cobalt(iii) complexes
  76. Synthesis of the Leu–Trp Component of the Celogentin Family of Cyclic Peptides Through a C–H Activation–Cross-Coupling Strategy
  77. Asymmetric Synthesis of a Hydroxylated Nine-membered Lactone from Tartaric Acid using the Claisen Rearrangement
  78. Carbon−Germanium Hyperconjugation: Solid-State and Gas-Phase Investigations of (Trialkylgermyl)methyl-Substituted Pyridinium Ions
  79. 1,2-Borotropic shifts and B–N bond cleavage reactions in molybdenum hydrotris(3-isopropylpyrazolyl)borate chemistry: Mixed-valence MoVIMo2V and pyrazole-rich oxo-MoIV complexes
  80. Synthesis, crystal structure and luminescent behaviour of coordination complexes of copper with bi- and tridentate amines and phosphonic acids
  81. Synthesis and Single Chain Fluorescence of a Sulfonated Conjugated Polymer
  82. X-ray Structural Analysis for the Prediction on the Nature of the Retro Diels–Alder Pathway: Concerted or Stepwise. Structural Studies on Nitrosobenzene Cycloadducts
  83. Synthesis of supramolecular metallo-amine-oxy acid systems via crystal disassembly/reassembly
  84. A new bifunctional chelator for copper radiopharmaceuticals: a cage amine ligand with a carboxylate functional group for conjugation to peptides
  85. Enantioselective Preparation of a Stable Boronate Complex Stereogenic Only at Boron
  86. A Novel Ligand Modification and Diamond-core Molybdenum(IV) 2,6-Bis(2,2-diphenyl-2-thioethyl)pyridinate(2-) Complex
  87. Asymmetric total synthesis of the myxobacteria metabolites crocacins A–D
  88. Structural Investigations into the β-Effect of Pentavalent Silicon
  89. X-Ray Structural Analysis of Ester and Ether Derivatives of 4,5- endo , endo -9,10-Dimethanonaphthalene-11-ol: Evidence for π– σ CO * Participation in the Ground State
  90. The Reaction of 5-Substituted-2-Norbornenes with Phenylselenyl Chloride
  91. ‘Click’ cycloaddition catalysts: copper(i) and copper(ii) tris(triazolylmethyl)amine complexes
  92. Synthesis of 1,1,3,3-Tetraalkylisoindolines Using a Microwave-Assisted Grignard Reaction
  93. Structural Studies on Cycloadducts of Furan, 2-Methoxyfuran, and 5-Trimethylsilylcyclopentadiene with Maleic Anhydride and N-Methylmaleimide
  94. Electronic Structure of the Sulfonyl and Phosphonyl Groups: A Computational and Crystallographic Study
  95. Pinastric acid revisited: a complete NMR and X-ray structure assignment
  96. Manifestations of the Alder−Rickert Reaction in the Structures of Bicyclo[2.2.2]octadiene and Bicyclo[2.2.2]octene Derivatives
  97. Carbon−Silicon Hyperconjugation and Strain-Enhanced Hyperconjugation:  Structures ofN-Methyl 2- and 4-tert-Butyldimethylsilylmethyl Pyridinium Cations
  98. 3,5-Dinitrosalicylic Acid in Molecular Assembly. III. Proton-Transfer Compounds of 3,5-Dinitrosalicylic Acid with Polycyclic Aromatic and Heteroaromatic Amines, and Overall Series Structural Systematics
  99. Structures of oxygenated cyclohexa-1,3-diene–maleic anyhydride cycloadducts. Structural evidence suggests a stepwise retro-Diels–Alder reaction
  100. On the stability of 2-aminoselenophene-3-carboxylates: potential dual-acting selenium-containing allosteric enhancers of A1 adenosine receptor binding
  101. Effect of ring substituents on crystal packing and H-bonding in a series of halobis(phen)copper(II) arylphosphonic acid complexes
  102. New bimetallic compounds based on the bis(thiosemicarbazonato) motif
  103. A Serendipitous Synthesis of the Novel Spiroacetal Core of Cynandione B
  104. Receptor-Mediated DNA-Targeted Photoimmunotherapy
  105. F‐18 labelled N,N‐bis‐haloethylamino‐phenylsulfoxides — a new class of compounds for the imaging of hypoxic tissue
  106. π-Acid/π-Base Carbonyloxomolybdenum(IV) Complexes and Their Oxomolybdenum(VI/IV) Precursors
  107. Molecular Recognition in Proton-Transfer Compounds of Brucine with Achiral Substituted Salicylic Acid Analogues
  108. The regioselective synthesis of aryl pyrroles
  109. Preparation of 2,3-dihydroselenolo[2,3-b]pyridines and related compounds by free-radical means
  110. Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
  111. Synthesis of 11C labelled methyl esters: transesterification of enol esters versus BF3 catalysed esterification—a comparative study
  112. Copper Complexes of Thiosemicarbazone−Pyridylhydrazine (THYNIC) Hybrid Ligands:  A New Versatile Potential Bifunctional Chelator for Copper Radiopharmaceuticals
  113. Models for the Molybdenum Hydroxylases:  Synthesis, Characterization and Reactivity of cis-Oxosulfido-Mo(VI) Complexes
  114. Syntheses, crystal structure and cytotoxicity of diamine platinum(II) complexes containing maltol
  115. Brucinium toluene-4-sulfonate trihydrate at 130 K
  116. Synthesis of the Putative Structure of Tridachiahydropyrone
  117. Comparison of Carbon−Silicon Hyperconjugation at the 2- and 4-Positions of the N-Methylpyridinium Cation
  118. Synthesis and Fluorescence of a Series of Multichromophoric Acenaphthenyl Compounds
  119. A comparison of the intramolecular and intermolecular hydrogen bonding of N,N′-ethylenebis(aminobenzylidene) in the solid state with its salen analogue
  120. Synthesis of an Analogue of the Marine Polypropionate Tridachiahydropyrone
  121. Synthesis and characterisation of second-generation metallodithiolene complexes of the type [Tp*ME(dithiolene)](M = Mo, W; E = O, S) and a novel ‘organoscorpionate’ complex of tungsten
  122. The Through-Bond Interaction of a Sulfur Lone Pair with Oxygenated Substituents in the Thiacyclohexane Framework
  123. Enantiospecific synthesis of (–)-trachyspic acid
  124. Determining the σ-donor ability of the cyclopropane C–C bond
  125. Structural manifestations of the cheletropic reaction
  126. 5-Nitrosalicylic Acid and its Proton-Transfer Compounds with Aliphatic Lewis Bases
  127. Novel copper materials based on the self-assembly of organophosphonic acids and bidentate amines
  128. Experimental Support for Planar Pseudopericyclic Transition States in Thermal Cheletropic Decarbonylations
  129. Isolation and Characterization of Salts of the Organometallic Synthon [Tp*W(NCMe)(CO)3]+ and Its Propionitrile Analogue
  130. The Silicon-Directed Tiffeneau–Demjanov Reaction: Some Theoretical Studies