All Stories

  1. The contrarotational fluxionality of [3,3-(PMe2Ph)2-closo-3,1,2-PtC2B9H11] and related species
  2. Borane Polyhedra as Building Blocks for Unknown but Potentially Isolatable New Molecules – Extensions based on Computations of the Known B18H22 Isomers
  3. Nine-vertex metallaborane chemistry. Preparation and characterisation of [1,1,1-(PMe3)2H-isocloso-IrB8H7-8-X], where X = H or Cl
  4. A DFT and crystallographic reinvestigation of the [L2RuC2B7H9] and [L3RuC2B7H9] ‘hypercloso’ and closo systems
  5. Chemistry of 11-vertex rhodathiaboranes: reactions with monodentate phosphines
  6. Polymethylated [Fe(η6-arene)2]2+ dications: methyl-group rearrangements and application of the EINS mechanism
  7. ChemInform Abstract: Macropolyhedral Boron-Containing Cluster Chemistry [S2B16H17]-. A New Eighteen-Vertex Thiaborane Anion.
  8. The Effect of Interbond Angles at Tin Upon 119Sn Chemical Shifts in Organotin Alkane-α, ω-Dithiolates and Some Related Compounds
  9. ChemInform Abstract: Macropolyhedral Boron-Containing Cluster Chemistry: Isolation and Characterization of the First Macropolyhedral Thiaborane, the arachno- Type (9,9′-S2B17H18)- Ion.
  10. ChemInform Abstract: Macropolyhedral Boron-Containing Cluster Chemistry. Cluster Fusion to give the Novel nido-nido Eighteen-Vertex Dithiaoctadecaborane (anti)-( 9,9′-S2B16H16).
  11. ChemInform Abstract: Macropolyhedral Boron-Containing Cluster Chemistry - The Nineteen- Vertex Oxaborane Anion, (OB18H21)-.
  12. New Iridathiaboranes with Reversible Isonido ↔ Nido Cluster Flexibility
  13. ChemInform Abstract: Macropolyhedral Boron-Containing Cluster Chemistry. Triple Cluster Fusion and the Molecular Structure of [(PMe3)2IrB26H24Ir(CO) (PMe3)2]. A 28-Vertex Metallaborane Cluster with a Polyboron Core.
  14. An Experimental Solution to the “Missing Hydrogens” Question Surrounding the Macropolyhedral 19-Vertex Boron Hydride Monoanion [B 19 H 22 ] − , a Simplification of Its Synthesis, and Its Use As an Intermediate in the First Example of syn -B 18 H 22 to...
  15. Macropolyhedral boron-containing cluster chemistry [S2B16H17]–. A new eighteen-vertex thiaborane anion
  16. Synthesis and characterization of dicarboranylmethylammonium polyoxometallates
  17. ChemInform Abstract: Structural Paradigms in Macropolyhedral Boranes.
  18. ChemInform Abstract: Vibrational Spectrum and Electronic Structure of the [B11H11]2- Dianion.
  19. Borane reaction chemistry. Alkyne insertion reactions into boron-containing clusters. Products from the thermolysis of [6,9-(2-HCC–C5H4N)2-arachno-B10H12]
  20. Ten-vertex polyhedral azametallaborane chemistry: a unique nido-6,9 to nido-6,8-cluster isomerization
  21. Macropolyhedral boron-containing cluster chemistry. The reversible disassembly and reassembly of the hexagonal pyramidal {B7} feature in the [S2B18H19]− anion
  22. Metallaborane reaction chemistry. A predicted and found tailored facile and reversible capture of SO2 by a B-frame-supported bimetallic: structures of [(PMe2Ph)2PtPd(phen)B10H10] and [(PMe2Ph)2Pt(SO2)Pd(phen)B10H10]
  23. Vibrational Spectrum and Electronic Structure of the [B11H11]2– Dianion
  24. Macropolyhedral boron-containing cluster chemistry: The reaction of syn-B18H22 with SMe2 and I2 in monoglyme: Structure of [7-(SMe2)-syn-B18H20]
  25. Macropolyhedral boron-containing cluster chemistry. Novel intercluster linkages from the reaction of [Pt(cod)Cl2] and [PtMe2(PMe2Ph)2] with 6,6′-(B10H13)2O
  26. Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes.
  27. Dimethylsulfide-dicarbaborane chemistry. Isolation and characterisation of isomers [9-(SMe2)-nido-7,8-C2B9H10-X-Me] (where X = 1, 2, 3 and 4) and some related compounds. An unusual skeletal rearrangement
  28. Macropolyhedral boron-containing cluster chemistry. The unique nido-five-vertex-〈B2〉-nido-ten-vertex conjuncto structure of [(η5-C5Me5)2Rh2B11H15] via an unexpected cluster-dismantling
  29. Macropolyhedral boron-containing cluster chemistry. Synthesis of the nineteen vertex monocarbaborane [9-(terBuNH2)-(anti)-9-CB18H20] by direct carbon-atom Aufbau
  30. Macropolyhedral Boron-Containing Cluster Chemistry. Intermolecular Coordination via Hydrogen-Metal Interaction. The Solvent-Free Synthesis and Dimeric Constitution of [Pd2B36H40(PMe2Ph)4]
  31. Polyhedral Dipalladaborane Chemistry. The Molecular Structure and Cluster Electron Count of [7,8-(PPh3)2-7,8-(μ-PPh2)-9,11-(OEt)2-nido-7,8-Pd2B9H8]
  32. Polyhedral iridaborane chemistry: Elements of the 10-vertex closo–isonido–isocloso continuum
  33. Twelve-vertex polyhedral carbaborane chemistry. Isostructural cations and anions: The ‘globule–globule’ salt [H3NCH2C2B10H11][H3CCH2CB11H11]
  34. Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(η6-MeC6H4isoPr)RuS2B16H16<...
  35. Pentahapto-bonded gold heteroborane clusters [3-(R3P)-closo-2,1-AuTeB10H10]? and [3-(R3P)-closo-3,1,2-AuAs2B9H9]?
  36. Macropolyhedral boron-containing cluster chemistry. A synthetic approach via the auto-fusion of [6,9-(SMe2)2-arachno-B10H12]
  37. Polyhedral monocarbaborane chemistry. Some C-phenylated seven, eight, nine, ten, eleven and twelve-vertex species
  38. Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20with [{(IrCl2(η5-C5Me5)}2]. Synchrotron X-ray structures...
  39. Macropolyhedral boron-containing cluster chemistry. An unusual ‘neonido ’ ten-vertex subcluster configuration in a [(PPh3)2RuB16H20] species
  40. Macropolyhedral borane reaction chemistry: Reductive oligomerisation of terBuNC by anti-B18H22 to give the boron-coordinated {(terBuNHCH){terBuNHC(CN)}CH2:} carbene residue
  41. Macropolyhedral boron-containing cluster chemistry
  42. Metallaborane reaction chemistry. Part 10. Phenylacetylene incorporation via [4,4-(PMe2Ph)2-arachno-4-PtCB8H12] in a ‘converse’ metalladicarbaborane synthesis of [7,7-(PMe2Ph)2-isonido-7,6,8-PtC2B6H7-6-Ph]
  43. Polyhedral ruthenaborane chemistry. Approaches to encapsulated boron cores. The isolation and characterisation of the partially encapsulated isocloso 10-vertex {RuB9} cluster compound [(PPh3)RuB9H9{RuCl2(PPh3)2}2]
  44. Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20and B14H18with [PtMe2(PMe2Ph)2] to give [(PMe2Ph)2PtB16H17
  45. Macropolyhedral boron-containing cluster chemistry. Synchrotron X-ray structural analysis of [(PMe2Ph)2Pd2B16H20(PMe2Ph)2] and [(PMe2Ph)3Pt2B16H18(PMe2Ph)]: models of intermediates to more condensed metallaboranes from the [(PMe2Ph)2PtB8H12] thermolysi...
  46. Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(η5-C5H5)FeP2CB8H9] complexes
  47. Coordination and cluster compounds of ruthenium with the [hypho-1,2-S2B6H9]– ligand
  48. The capture of dioxygen, carbon monoxide and sulfur dioxide by [(PMe2Ph)4Pt2B10H10]
  49. Macropolyhedral Boron-Containing Cluster Chemistry. A Metallathiaborane from S2B17H17: Isolation and Characterisation of [(PMe2Ph)2PtS2B16H16]; A neo-arachno Ten-Vertex Cluster Shape, and the Constitution of the [arachno-B10H15]- Anion
  50. Polyhedral Monocarbaborane Chemistry. Functionality and Isomerism: Reactions of the [6-Ph-nido-6-CB9H11]- Anion with Aminopyridines NC5H4NH2 to Yield Neutral arachno and closo Ten-Vertex Monocarbaborane Derivatives
  51. Polyhedral Oxaruthenaborane Chemistry. Characterisation of a [(η6-C6Me6)RuOB9H13] Species of arachno Eleven-Vertex Cluster Character and Other Aspects of Oxaborane Chemistry
  52. Macropolyhedral Boron-Containing Cluster Chemistry: Pointers Towards the Mechanism of Homofusions of Nine-Vertex Arachno Metallaboranes
  53. Macropolyhedral boron-containing cluster chemistry: two-electron variations in intercluster bonding intimacy. Contrasting structures of 19-vertex [(η5-C5Me5)HIrB18H19(PHPh2)] and [(η5-C5Me5)IrB18H18(PH2Ph)]
  54. Monocarbaborane anion chemistry. {COOH}, {CH2OH} and {CHO} units as functional groups on ten-vertex monocarbaborane anionic compounds
  55. Polyhedral monocarbaborane chemistry. Carboxylic acid derivatives of the [closo-2-CB9H10]? anion
  56. Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)4(O2)Pt2B10H10]
  57. Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex [(η5-C5Me5)HIrB18H19(PMe2Ph)] a...
  58. Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)2MoB16H15C2Ph2]? anion
  59. Ten-vertex osmamonocarbaboranes via arachno and nido {CB9} monocarbaboranes. Polyhedral contraction promoted by [OsCl2(PPh3)3] in MeOH and the crystal and molecular structure of [1-H-1,1-(PPh3)2-2-Ph-3-(OMe)-isocloso-1,2-OsCB8H7]
  60. Macropolyhedral boron-containing cluster chemistry. Aspects of the S2B16H16 system. Preparation, structure, NMR spectroscopy and isomerism
  61. Polyhedral monocarbaborane chemistry. Routes to neutral, monoanionic and dianionic carbo-carbaborane rods
  62. Azacarbaborane chemistry. Butyl nitrite synthesis of the new eight-, nine- and ten-vertex azacarbaboranes exo- and endo-7-CH3-hypho-7,8-NCB6H11, nido-6,8,9-NC2B7H10, arachno-6,5,9-NC2B7H12 and arachno-6,5,10-C2NB7H12
  63. Metallaheteroborane chemistry: Part 16. Contrasting metal to heteroborane bonding modes in isoelectronic {MC2B9} and {MAs2B9} clusters. Synthesis and characterisation of [9-{Fe(CO)2(η5-C...
  64. Macropolyhedral boron-containing cluster chemistry
  65. Macropolyhedral thiaboranes with unusual arachno subclusters—a computational investigation
  66. Macropolyhedral boron-containing cluster chemistry
  67. Monocarbaborane anion chemistry. An interesting encapsulation of the Pd2I2{P(C6H4-4-Me)3}4]2+ cation by a pair of [PhCB9H4I(C6H4Me)4]??? anions
  68. Preparation and Characterization of Macropolyhedral Metallaborane Clusters from the anti -B 18 H 22 Borane Cluster:  Crystal Structure of [(CH 3 ) 4 N][ a nti- B 18 H 20 Co(CO) 3 ]
  69. Monocarbaborane anion chemistry. The substantiation of the C-arylated [PhCB6H6]– seven-vertex closo cluster anion by single-crystal synchrotron X-ray diffraction analysis
  70. Polyhedral Monocarbaborane Chemistry. A Review of Recent Developments Among C-Aryl Monocarbaborane Systems
  71. Monocarbaborane Anion Chemistry. Syntheses and Structures Within the closo Nine-Vertex System
  72. Monocarbaborane chemistry. Preparation and characterisation of [4-CB8H9]–, the ‘missing’ closo-carbaborane anion
  73. Monocarbaborane anion chemistry. The elusive C-arylated [PhCB11H11]–, [PhCB9H9]– and [PhCB8H8]– anions
  74. Triple linking of the decaboranyl cluster. Structure of [(SMe2)2B10H10(B10H13)2] as determined by synchrotron X-ray diffraction analysis
  75. Macropolyhedral boron-containing cluster chemistry. Further progress beyond the icosahedron. July 1999
  76. Macropolyhedral boron-containing cluster chemistry. Isolation and structure of the twenty-one-vertex globular cluster compound [(η5-C5Me5)3Ir3B18H15(OH)]
  77. Macropolyhedral boron-containing cluster chemistry. The [SB17H19]− anion: a nido-ten-vertex : arachno-ten-vertex cluster architecture and the first single-sulfur macropolyhedral thiaborane
  78. Isolation and Structure of [(PPh3)3(PPh2)2Pd4B20H16]. A Possible Prognostic for New Globular Borane-Based Cluster Architectures
  79. Metallaborane Reaction Chemistry. Part 7. B-Frame Supported Bimetallics: Ligand-to-β-Metal Organometallic Interaction in Dimetallaboranes and an Interesting Ligand Displacement Cascade
  80. NMR Assignments of [6-R-nido-5,6-C2B8H10]- Anions (where R = H, Me, and n-C6H13). An Irreversible 5 → 6 Alkyl Migration via a B9 Vertex-Swing Mechanism
  81. Polyhedral Azaplatinaborane Chemistry. Reaction of Members of the hypho-Type Family R'H2NB8H11NHR with [PtCl2(PMe2Ph)2] and [PtCl2(PPh3)2]. Formation of Members of the Family of Open Seven-Boron Species [3,3-(PMe2Ph)2-3-PtB7H10-μ-5,6-(NHR)]
  82. Macropolyhedral boron-containing cluster chemistry. Isolation and characterisation of the 27-vertex contiguous triple-cluster species [(PMe2Ph)PtB26H26(PMe2Ph)]
  83. Polyhedral ruthenaborane chemistry. The ten-vertex isocloso cluster geometries of [(pcym)RuB9H9] and [(pcym)2Ru2B8H8]
  84. Macropolyhedral boron-containing cluster chemistry. An interesting angular change in relative subcluster orientation in the oxidative protonation of [S2B17H18]− to [S2B17H17]
  85. Macropolyhedral boron-containing cluster chemistry. [PtMe2(PMe2Ph)2] as a cluster metallating agent. Isolation and characterisation of nineteen-vertex [(PMe2Ph)HPt-η4-syn-B18H19(PMe2Ph)] and eighteen-vertex [(PMe2Ph)2PtS2B15H14(NHCOMe]
  86. Metallaborane reaction chemistry. Macropolyhedral metallaheteroborane synthesis by direct heteroatom insertion. Formation of the twenty-vertex [(η5-C5Me5)IrB18H19S]− anion from nineteen-vertex syn-[(η5-C5Me5)IrB18H20]
  87. Macropolyhedral boron-containing cluster chemistry. The [S2B18H19]− anion, and the reversible dismantling and regeneration of an apical boron cluster site with cluster connectivity six
  88. Polyhedral azaborane chemistry. Nitrogen-vertex incorporation in metallaazaborane formation from 4-(NHEt2)B9H13. Two isomers of [(η5-C5Me5)RhB9H12(NEt2)]
  89. Macropolyhedral boron-containing cluster chemistry. Mixed and multiple cluster fusion in platinaborane chemistry and the structure of [(PMe2Ph)2PtB16H17PtB10H11(PMe2Ph)] as determined by synchrotron X-ray diffraction analysis
  90. Theisonido-Metalladicarbaborane [1,1,1-H{P(CH3)3}2-6-Cl-1,2,4-IrC2B8H9]
  91. Macropolyhedral boron-containing cluster chemistry. Assessment of the possibilities of thermolytic mixed-cluster fusion, and of the use of synchrotron X-radiation for the examination of small single crystals of metallaboranes. Isolation and structure o...
  92. Polyhedral azadirhodaborane chemistry. Reaction of [{RhCl2(η5-C5Me5) }2] with [EtH2NB8H11NHEt] to give contiguous ten-vertex [1-Et-6,7-(η5-C5Me5)2- closo-6,7,1-Rh2NB7H7 ]
  93. Polyhedral azaborane chemistry. The establishment of members of the hypho-type family [(RH2N)B8H11NHR], where groups R are now other than ethyl
  94. exo,endo and exo,exo isomers of 6,9-(PMe2Ph)2-arachno-B10H12 and its halogenated derivatives. Molecular structures of exo,endo- and exo,exo-6,9-(PMe2Ph)2-arachno-B10H12 and exo-6,endo-9-(PMe2Ph)2-2-Br-arachno-B10H11
  95. Macropolyhedral boron-containing cluster chemistry. Characterisation of rigid 77-atom [Pt(B18H20)2]2− dianion isomers and an unusual metallaborane homophilic interaction
  96. Macropolyhedral boron-containing cluster chemistry. Triple cluster fusion and the molecular structure of [(PMe3)2IrB26H24Ir(CO)(PMe3)2]. A 28-vertex metallaborane cluster with a polyboron core†
  97. Macropolyhedral boron-containing cluster chemistry: isolation and characterization of twenty-one-vertex [(PMe2Ph)3HReB20H15Ph(PHMe 2)]
  98. Effects of metal-centre orbital control on cluster character and electron distribution between borane and hydrocarbon ligands; significance of the structures of [μ-9,10-(SMe)-8,8-(PPh3)2-nido-8,7-IrSB 9H9] and [μ-9,10-(SMe)-8-(η4-C5Me5H)- nido-8,7-RhSB...
  99. Ten-vertex monocarbaborane chemistry. Synthesis of carbon-substituted ligand derivatives 1-L-closo-1-CB9H9 and crystal and molecular structure of 1-(Me3N)-closo-1-CB9H9
  100. Metallaborane Reaction Chemistry. Part 4. Polyhedral Thiametallaborane Synthesis via Direct Incorporation of Sulfur Into Metallaboranes
  101. A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12
  102. Metallaborane Reaction Chemistry. Part 3. Reaction of Carbon Monoxide with [6-H-6-(PPh3)-6P,5C-μ-(2-Ph2PC6H4)-nido-6-IrB9H12] and the Isolation and Characterisation of Two arachno-6-Monoiridadecaboranes [6-(CO)-6-H-6,9-(PPh3)2-6P,5C-μ-(2-Ph2PC6H4)-arac...
  103. Conformational polymorphism and fluxional behaviour of M(PR3)2units in closo-twelve-atom metallaheteroboranes with MX2B9(X = C or As) and MZB10cages (Z = S, Se or Te)
  104. Macropolyhedral boron-containing cluster chemistry. syn- and anti-[(C5Me5)2Rh2S2B15H14(OH)]; an interesting nineteen-vertex isomeric pair
  105. Macropolyhedral boron-containing cluster chemistry. Isolation and characterisation of the eighteen-vertex nido-5′-iridaoctaborano[3′,8′ : 1′,2]-closo-4-iridadodecaborane, [(CO)(PMe3)2IrB16H14Ir(CO)(PMe3<...
  106. Macropolyhedral boron-containing cluster chemistry: nineteen-vertex [(PPh3)NiS2B16H12(PPh3)] and eighteen-vertex S2B16H14(PPh3)
  107. An air-stable, cationic metallacarborane without a charge-compensated carborane ligand
  108. Macropolyhedral boron-containing cluster chemistry. Nineteen-vertex [S2B17H17(SMe2)]. An unusual apical boron atom of cluster connectivity six that introduces a new polyhedral borane building block
  109. Macropolyhedral boron-containing cluster chemistry. An X-ray diffraction and nuclear magnetic resonance study of the double cluster 11-vertex: 11-vertex tetracarbaborane C4B18H22
  110. Ten-vertex polyhedral monoheteroborane chemistry: syntheses, molecular structures, and nuclear magnetic resonance characterization of some 9-substituted 6-aza- and 6-thia-arachno-decaboranes
  111. Reactions of carbon disulfide with open nido-6-iridadecaboranes. The formation of closed ten-vertex cluster compounds with boron-to-metal dithioformate bridges and a novel isocloso→closo cluster conversion
  112. Polyhedral Azaborane Chemistry: NMR Parameters for the Unique Eight-Boron Polyhedral Species [(C2H5NH2)B8H11NHC2H5]
  113. Macropolyhedral boron-containing cluster chemistry—the nineteen-vertex oxaborane anion, [OB18H21]–
  114. Macropolyhedral boron-containing cluster chemistry. The eighteen-vertex monocarbaborane [(Me3CNH2)CB17H18(CN)]
  115. Eight-vertex polyhedral monocarbaborane chemistry. Three closo anions, [CB7H8]–, [CB7H7I]–and [CB7H6I2]–. Preparation and structural studies
  116. Macropolyhedral Boron-Containing Cluster Chemistry: Isolation and Characterization of the First Macropolyhedral Thiaborane, thearachno-Type[9,9′-S2B17H18]− Ion
  117. Chemie makropolyedrischer Borcluster: Isolierung und Charakterisierung des ersten makropolyedrischen Thiaborans, des Anions [9,9′-S2B17H18]− vomarachno-Typ
  118. Polyhedral carbathiaborane chemistry. Ten-vertex nido and arachno, eleven-vertex nido, and eight-vertex hypho families of carbathiaboranes
  119. Novel phosphonium-betaine ligands [SC(H)PPh3-C,S]–and [S(H)CC(PPh3)S-S,S′]–stabilised in rhodacarborane complexes
  120. Macropolyhedral boron-containing cluster chemistry. Cluster fusion to give the novel nido–nido eighteen-vertex dithiaoctadecaborane (anti)-[9,9′-S2B16H16]
  121. Macropolyhedral boron-containing cluster chemistry. A reductive trimerisation of MeNC to give an imidazole-based carbene stabilized by coordination to boron in an eighteen-vertex cluster compound
  122. Eleven- and twelve-vertex polyhedral metalladithiaborane chemistry. Novel compounds from the arachno-[S2B9H10]–anion: [(PPh3)3H2IrS2B9H10], [(...
  123. Nine-vertex polyhedral iridamonocarbaborane chemistry. Products of thermolysis of [(CO)(PPh3)2IrCB7H8] and emerging alternative cluster-geometry patterns
  124. Synthesis and crystal structure of [Pd(PPh3)S2B6H8]2: a dimeric metallaheteroborane with heteroatoms acting both as cluster atoms and two-electron donor sites
  125. Macropolyhedral boron-containing cluster chemistry. The isolation and characterisation of the eighteen-vertex azaborane anti-[9-NB17H20]
  126. Nine-Vertex Polyhedral Monoazaborane Chemistry: Synthesis and NMR Characterization of exo-6-Ligand-arachno-4-azanonaboranes(11), 6-L-4-NB8H11
  127. Nine-Vertex Polyhedral Monothiaborane Chemistry. The First nido Thianonaborane: Isolation and Characterization by NMR of the [nido-9-SB8H9]- Anion, and its Conversion to Compounds of the 6-L-arachno-4-SB8H10 Series (where L = SMe2 and Pyridine)
  128. Nine- and Eight-Vertex Polyhedral Dicarbaborane Chemistry: New arachno and hypho Dicarbaboranes from arachno-4,5-C2B7H13: Isolation and Characterization of the [arachno-4,5-C2B7H12]- and [hypho-7,8-C2B6H13]- Anions, and of the Neutral Ligand Derivative...
  129. Nine-vertex polyhedral monocarbaplatinaborane chemistry. Isolation, molecular structure and nuclear magnetic resonance properties of [6,6-(PPh3)2-arachno-6,4-PtCB7H11]
  130. Eleven-vertex polyhedral stannadicarbaborane chemistry. ‘naked tin’{closo-1,2,3-SnC2B8}-cluster compounds
  131. Letters
  132. Additions and corrections
  133. An alternative route to cationic metallaheteroboranes
  134. Metallaheteroborane chemistry. Part 12. Synthesis of cationic metallaheteroboranes [2-L-2-(PPh3)-closo-2,1-PdTeB10H9(PPh3)][BF4]; molecular structures of the compounds with L = H2O or CO
  135. Metallaborane reaction chemistry. Part 1. Two interesting closed cluster compounds from the reaction of acetylene with an open nido-6-iridadecaborane
  136. Metallaheteroborane chemistry. Part 11. Selective syntheses of the palladium heteroborane complexes [2,2-(PR3)2-closo-2,1-PdEB10H10](R3= Ph3, MePh2 or Me2Ph; E = Se or Te) and [2-X-2-(PPh3)-closo-2,1-PdTeB10H9(PPh3)](X = Cl, Br, I, CN, SCN or O2CMe)
  137. Eleven-vertex polyhedral monocarbaplatinaborane chemistry. Structure and fluxionality of [8,8-(PMe2Ph)2-nido-8,7-PtCB9H11]
  138. The first cluster azathiaboranes: isolation and characterisation of eight-vertex hypho-7,8-NSB6H11and ten-vertex arachno-6,9-NSB8H11
  139. Eleven-Vertex Polyhedral Dicarbaplatinaborane Chemistry. Aspects of the Chemistry of Some closo-Structured {1,2,3-PtC2B8} Species and Some Related Compounds
  140. Ten-Vertex Polyhedral Monocarbaborane Chemistry. The Novel High-Yield Formation of the Ten-Vertex closo Compound [6-(PMe2Ph)-closo-1-CB9H9] from the Thermolysis of [8,8-(PMe2Ph)2-nido-8,7-PtCB9H11]
  141. Ten-Vertex Polyhedral Rhodadicarbaborane Chemistry. Molecular Structure, NMR Properties, and Cluster Dynamic Behaviour of [2,2,2-(PPh3)2H-closo-2,1,6-RhC2B7H9]
  142. Organoruthenaborane Chemistry. X. The SM2-catalysed formation of [ l-(?6-C6Me6)-isocloso-RuB9H9], and some B-phenylamino derivatives. NMR and X-ray diffraction studies
  143. Metallaheteroborane chemistry. Part 10. Synthesis and characterisation of closo-structured rhodathiaborane complexes [1-(CO)-1-L-3-L′-1,2-RhSB9H8](L = L′= PPh3; L = PMe2Ph, L′= PMe2Ph or PPh3<...
  144. Ten-vertex metallaborane chemistry. Aspects of the iridadecaborane closo→isonido→isocloso structural continuum
  145. Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
  146. Ten-Vertex Monocarbaborane Chemistry. A Convenient New Preparation of the [closo-1-CB9H10]- Anion and the Crystal and Molecular Structure of [(η5-C5Me5)2Ir2Cl3]+ [closo-1-CB9H10]-
  147. Additions and corrections
  148. Metallaheteroborane chemistry. Part 9. Syntheses and spectroscopy of platinum and palladium phosphine complexes containing η5-{As2B9}-based cluster ligands. Crystal structures of [3,3-L2-closo-3,1,2-PtAs...
  149. Polyhedral iridathiaborane chemistry. Reactions of nido-6-SB9H11and of [arachno-6-SB9H12]–with [{Ir(η5-C5Me5)Cl2}2] to give nido-8,7-iridathia...
  150. Polyhedral osmaborane chemistry: the platination of [4,4,4-(CO)(PPh3)2-nido-4-OsB5H9] and the isolation, nuclear magnetic resonance properties, and molecular structures of two seven-vertex nido-type dimetallaheptaboranes [(CO)(PPh3)2HOs(PMe2Ph)ClPtB5H7...
  151. Two new ten-vertex arachno mixed-atom diheteroboranes, 6,9-CNB8H13and 6,9-CSB8H12
  152. Polyhedral platinadicarbaborane chemistry. The molecular structure and some NMR properties of [9,9-(PPh3)2-arachno-9,5,6-PtC2B7H11]
  153. Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
  154. Polyhedral organoiridaazaborane chemistry. The preparation of the eleven-vertex nido compound [9-Cl-8-(η5-C5Me5)-nido-8,7-IrNHB9H10] and its characterization by single-crystal X-ray diffraction analysis and nuclear magnetic resonance spectroscopy
  155. Ten-vertex metallaborane chemistry. Structure of 3-(OC2H5)-4,9-(PPh3)2-7,7-Cl(Ph2P-ortho-C6H4)-isonido-7-IrB9H5-10-.CH2Cl2
  156. Polyhedral metallaphosphaborane chemistry: the preparation, molecular structure, and nuclear magnetic resonance study of [2-Ph-1,1-(PMe2Ph)2-closo-1,2-PtPB10H10], and some related chemistry
  157. Metallaheteroborane chemistry. Part 6. Synthesis of closo-[2-(η-ligand)-1,2-TeMB10H10] complexes with M(η-ligand)= Rh(η5-C5Me5)(1), Ru(η6-p- MeC6H4Pri...
  158. Arachno-6,9-diazadecaborane(12), [6,9-N2B8H12], an unsubstituted contiguous cluster diazaborane
  159. Polyhedral metallacarbaborane chemistry: preparation, molecular structure, and nuclear magnetic resonance investigation of [3-(η5-C5Me5)-closo-3,1,2-MC2B9H11] (M = Rh or Ir)
  160. An unusual direct conversion of metallaboranes to metallacarbaboranes and the isolation of a novel isoarachno twelve-vertex cluster compound
  161. Organoruthenaborane chemistry. Part 7. Preparation, molecular structure, and nuclear magnetic resonance properties of eleven-vertex closo-type clusters: [2,4-Me2-1 -(pcym)-1,2,4-RuC2B8H8], [2,3-Me2-1 -(pcym)-1,2,3-RuC2B8H8], [1-(pcym)-1-RuB10H10] and s...
  162. Ten-vertex metallaborane chemistry: facile, thermally induced, nido→isocloso cluster-closure oxidation reactions in iridadecaborane clusters
  163. Polyhedral iridamonocarbaborane chemistry. Two ten-vertex arachno-6,9-iridacarbadecaboranes and some related ten-vertex carbaborane chemistry. Comparative nuclear magnetic resonance studies and the molecular structure of [asym-9-(CO)-9,9-(PPh3
  164. Ten-vertex metallaborane chemistry: synthesis and characterization of some ortho-cycloboronated nido-5- and -6-iridadecaboranes; crystal structures of [5-H-5-(PPh3)-5-(PPh2-o-C6H4)-nido-5-IrB9H12-2] and [5-H-5,7-(PPh3)2-5-(PPh2-o-C6H4)-nido-5-IrB9H12-2]]
  165. Novel rhodathiaborane complexes derived from [(PPh3)2RhSB9H10]
  166. Oxarhodaborane chemistry: the formation of [µ-9,9′-O-{5-(η5-C5Me5)-nido-5-RhB9H12}2] and [7-(η5-C5Me5)-10-(NEt3)-nido-7, 12-RhOB10H...
  167. Metallaheteroborane chemistry. Part 7. Synthesis, crystal structure, and characterisation of two dinuclear rhodatelluraboranes, [{(PPh3)2RhTeB10H10}2] and [(PPh3)(CO)Rh2Te2B20H20]
  168. Novel bonding mode and reaction of a phosphonium-betaine ligand S2C(H)(PPh3). Synthesis of the [Rh(XB10H10){S2C(H)(PPh3)}]2 dimers (X = Se, Te) and X-ray diffraction study of the te-compound
  169. Additions and corrections
  170. Stepwise reduction of MeNC to Me2NH on a metallaborane substrate: an interesting reaction sequence and the molecular structure of [µ-6,9-(NMe2)-10-(PMe2Ph)-5-(η6-C6Me6)-arachno-5-RuB
  171. Heterobimetallic B-frame complexes: novel isonido eleven-vertex rhodairidaboranes with Rh–H–Ir and B–H–B bridges
  172. Direct evidence for N→B π-donation into a polyhedral borane cluster
  173. Oxidative and cluster Aufbau reactions of nido-6-metalladeaboranes induced by Lewis bases such as SMe2: high-yield formation of [1-(η6-C6Me6)-isocloso-1-RuB9H9] and the molecular structure of the Rh-commo-(isonido-eleven-vertex)-(closo-ten-vertex)conju...
  174. A unique acetylene-induced reductive PPh3→ PH3stripping of phenyl groups from triphenylphosphine ligands bound to a metallaborane ‘B-frame’ matrix
  175. Metallaheteroborane chemistry. Part 5. Synthesis of closo-[2,2-(PR3)2-1,2-SePtB10H10](R3= Et3, Bun 3 or Me2Ph) and arachno-[9,9-(PMe2Ph)2-6,9-SePtB8H10] and their characterisation by nuclear magnetic resonance techniques: the crystal and molecular stru...
  176. Polyhedral organoiridaborane chemistry. The reaction of MeNC with [6-(η5- C5Me5)-nido-6-IrB9H13]. Nuclear magnetic resonance studies and the crystal and molecular structure of [4,4-(η5-C...
  177. The high-yield preparation of arachno-thiaboranes 4-SB8H12 and 4-SB8H−11
  178. Signs of interphosphorus nuclear spin coupling constants in octahedral transition-metal complexes containing chelated phosphine ligands
  179. Boron-11 and proton nuclear magnetic resonance study of anti-B18H22and its anions, anti-[B18H21]–and anti-[B18H20]2–. The crystal and molecular structure of [NMe
  180. Organoruthenaborane chemistry. Part 6. The reaction of [{Ru(η6-C6Me6)Cl2}2] with the closo-[B10H10]2–anion: characterisation of some closo-type eleven-vertex 1-ruth...
  181. Polyhedral thiaborane chemistry: a comparative nuclear magnetic resonance study of arachno-[6-SB9H12]? and nido-6-SB9H11
  182. Metallaheteroborane chemistry. Part 3. Synthesis of [2,2-(PR3)2-1,2-TePtB10H10](R3= Et3, Bun 3, or Me2Ph), their characterisation by nuclear magnetic resonance spectroscopy, and the crystal and molecular structure of [2,2-(PEt3)2-1,2-TePtB10H10]
  183. A novel eleven-vertex closo-type azametallaborane: [1-(η6-MeC6H4-4-Pri)-closo-1,2-RuNB9H10]
  184. Pentamethylcyclopentadienylrhodaborane chemistry. Part 5. Preparation, molecular structure, and nuclear magnetic resonance spectra of the arachno ten-vertex rhodadecaboranes [6-(η5-C5Me5)-6,9-(RNC)2-arachno-6...
  185. Facile pathway-defined fluxional cluster isomerization in ten-vertex closo-2,1,6-metalladicarbaboranes of ruthenium and rhodium
  186. Metallaheteroborane chemistry. Part 4. The synthesis of closo-[2,2-(PPh3)2-2-H-1,2-XMB10H10](X = Se or Te, M = Rh or Ir) compounds, their characterisation by nuclear magnetic resonance techniques, and the crystal and molecular structure of the X = Te, ...
  187. Comparative metallaborane chemistry: preparation and nuclear magnetic resonance studies of some nido-5-metalladecaboranes of rhodium, iridium, ruthenium, and osmium
  188. Pentamethylcyclopentadienylrhodaborane chemistry. Part 4. The isolation, molecular structure, and nuclear magnetic resonance study of an interesting phosphino-bridged arachno-type nine-vertex rhodaborane [2,5-(µ-PPh2)-1-(PHPh2)-2-...
  189. Preparation, structure, and nuclear magnetic resonance properties of the nine-vertex nido-rhenaborane [(PMe2Ph)3H2ReB8H11] and some related chemistry
  190. A double cluster of ruthenium and boron; [1-η2-{(η6-C6Me6)2Ru2H4}-isocloso-1-RuB10H8-2,3-(OEt)2]
  191. Homobimetallic B-frame species: [{(PPh3)2Ru}-(µ-MeCO2)3-(µ-H)2-{RuB10H7}], a unique diruthenaborane in which the metal atoms are linked by one-, two-, three-, and four-membere...
  192. Additions and corrections
  193. Organoruthenaborane chemistry. Part 5. Products of the reaction between closo-[B10H10]2–and [(η6-C6Me6)ClRuB3H8]. Nuclear magnetic resonance studies and the crystal and molecular structure of [{(η6-C6Me6)2Ru2H4}RuB10H8(OEt)2]
  194. Pentamethylcyclopentadienylrhodaborane chemistry. Part 2. The reaction of [6-(η5-C5Me5)-nido-6-RhB9H13] with dimethylphenylphosphine, and the characterization of [5-(η5-C5Me5)-nido-5-RhB9H11-7-(PMe2Ph)], [2-(η5-C5Me5)-closo-2-RhB9H7-3,10-(PMe2Ph)2],* a...
  195. The preparation of [Ru(NCMe)6][7-(η6-C6Me6)-nido-7-RuB10H13]2and its characterization by single-crystal X-ray diffraction analysis and nuclear magnetic resonance spectroscopy:...
  196. Determination of the relative signs of2J(31P–31P) in complexes of tungsten(0) and molybdenum(0) using two-dimensional [31P–31P]-COSY-45 nuclear magnetic resonance chemical shi...
  197. The isolation and characterisation of the 1- and 2-isomers of nido-[(η6-C6Me6)RuB9H13]—but is the 1-isomer nido or arachno?
  198. Quantitative thermal rearrangement of an eleven-vertex metalladicarbaborane to give the isomeric cluster nido-[2-(η6-C6Me6)-8,10-Me2-2,8,10-OsC2B8H8] with an unexpected BCBCB ...
  199. Ruthenium(II) complexes of closo-dodecaboranyl anions and the molecular structure of the pileo thirteen-vertex ruthenaborane [(PPh3)2ClRuB12H11(NEt3)]
  200. Identification of the endo,exo isomer of 6,9-(PMe2Ph)2-arachno-B10H12 by nuclear magnetic resonance spectroscopy
  201. Pentamethylcyclopentadienylrhodaborane chemistry. Part 3. The reaction of [{Rh(η5-C5Me5)Cl2}2] with closo-[B10H10]2–and arachno-B10H12-6,9-(PM...
  202. An interesting arachno eight-vertex tungstaborane: isolation and characterisation of the fluxional anion [3,3,3,3-(CO)4-arachno-WB7H12]?
  203. Synthesis, molecular structure, and nuclear magnetic resonance spectra of the anionic monocarbametallaborane [NEt4][(CO)3(PPh3)(OH)-closo-MoCB10H10]·CH2Cl2
  204. Boron
  205. Silicon, Germanium, Tin, and Lead
  206. Synthesis, reactions, and nuclear magnetic resonance studies of some substituted arachno-decaborane and arachno-nonaborane derivatives, and the isolation of novel polyhedral diplatinaboranes. Crystal and molecular structure of [Pt2(PMe2...
  207. Comparative ten-vertex metallaborane chemistry: some nido-6-metalladecaboranes of tungsten, rhenium, ruthenium, osmium, and iridium; including the crystal and molecular structures of [6,6,6,6,6-(PMe2Ph)3H2-nido-6-WB9H13] and [6,6,6-(PMe2Ph)3-nido-6-OsB...
  208. Preparation and nuclear magnetic resonance properties of eleven-vertex closo-type osmaundecaboranes and the X-ray crystal structure of the ortho-cycloboronated compound [2,5-(OEt)2-1-(PPh3)-1-(o-Ph2PC6H4)-closo-1-OsB10H7-3]
  209. Synthesis, molecular structures, and nuclear magnetic resonance properties of the macropolyhedral metallaboranes [(PMe2Ph)4Pt3B14H16] and [(PMe2Ph)PtB16H18(PMe2Ph)], and a discussion of the bonding at platinum in these and some related platinaborane cl...
  210. Pentamethylcyclopentadienylrhodaborane chemistry. Part 1. High-yield planned synthesis, molecular structure, and nuclear magnetic resonance properties of the ten-vertex nido-6-rhodadecaborane [(η5-C5Me5)RhB9H13]
  211. Polyhedral phosphaborane chemistry: crystal and molecular structure of the diphenylphosphido-bridged arachno-decaboranyl cluster compound [PMePh3][6,9-µ-(PPh2)B10H12]
  212. Eleven-vertex isocloso type rhodaundecaboranes: crystal structures and nuclear magnetic resonance properties of [(PMe2Ph)2RhHB10H8(OMe)2] and [(PMe2Ph)2RhHB10H8Cl(OMe)]
  213. Preparation of [(C5Me5)2Rh2B17H19]via a degradative insertion from anti-B18H22, and a possible mechanism for anti→syn macropolyhedral interconversion
  214. Identification and molecular structure of the eighteen-vertex macropolyhedral diplatinaoctadecaborane [(PMe2Ph)2Pt2B16H15(C6H4Me)(PMe2Ph)]
  215. Two-dimensional1H–1H COSY n.m.r. spectroscopy in polyhedral boron hydride chemistry
  216. Correlation of thallium–boron nuclear spin states by two-dimensional n.m.r. spectroscopy: magnitudes and relative signs of couplingsnJ(205Tl–11B) in the nido-thallaundecaborane anion [Me2TlB10H
  217. Polyhedral rhenaborane chemistry: crystal and molecular structures of the nido-6-rhenadecaborane cluster compounds [6,6,6,6-(PMe2Ph)3H-nido-6- ReB9H13] and [2-(PMe2Ph)-6,6,6,6-(PMe2Ph)2ClH-nido-6-ReB9H12]; nuclear magnetic resonance parameters of these...
  218. Preparation and structure of [7-(η5-C5Me5)-8-Cl-11-(PMe2Ph)-nido-7-RhB10H11], a metallaborane analogue of the fluxional borane anion nido-B11H14–
  219. An unusual open twelve-vertex oxametallaborane cluster compound: synthesis and structure of [7-(η5-C5Me5)-8-Cl-11-(PMe2Ph)-nido-7,12-RhOB10H9]
  220. Polyhedral ruthenaborane chemistry: characterization of several new ruthenaboranes by nuclear magnetic resonance spectroscopy, and the crystal and molecular structure of [5,6,6-(PPh3)3-6-H-nido-6-RuB9H12]
  221. Two unusual closo-type ruthenaboranes: preparation, molecular structure, and nuclear magnetic resonance properties of [1,1,1 -(PPh3)HCl-1-RuB9H7-3,5-(PPh3)2] and [1,1 -(PPh3)2-1 -RuB10H8-2,5-(OEt)2]
  222. Reactions of 6,6′-bis(nido-decaboranyl) oxide and 6-hydroxy-nido-decaborane with dihalogenobis(phosphine) complexes of nickel, palladium, and platinum, and some related chemistry; nuclear magnetic resonance investigations and the crystal and molecular ...
  223. The crystal and molecular structure of [1,1,1,1-(CO)H(PPh3)2-arachno-1-IrB3H7] and some bonding considerations in arachno-type four-vertex metal ‘π-allyl’ and ‘borallyl’ clusters
  224. Preparation, crystal and molecular structure of, and NMR parameters for, the exopolyhedral heterocyclic platinaundecaborane [μ-2,7-(SCSNEt2)-7-(PMe2Ph)-NIDO-7-PtB10H11]
  225. The chemistry of isomers of icosaborane(26): Crystal and molecular structure of 1,2′-bi(nido-decaboranyl)
  226. Iridanonaborane chemistry. Some reactions of arachno-4-irida-nonaboranes: nuclear magnetic resonance investigations and the molecular structure of the nido nine-vertex species [2,2,2-(CO)(PMe3)2-nido-2-IrB8H11]
  227. Homo- and hetero-bimetallic B-frame compounds: some novel twelve-vertex Ru/Ru, Os/Os, Ru/Os, and Os/Ru metallaboranes
  228. Synthesis and nuclear magnetic resonance study of the auranonaborane and diauradecaborane arachno-type compounds, [4-(S2CNEt2)-arachno-4-AuB8H12] and [6,9-(S2CNEt2)2-arachno-6,9-Au2B8H10]; crystal and molecular structure of [6,9-(S2CNEt2)2-arachno-6,9-...
  229. Iridanonaborane chemistry: preparation and characterization of some arachno-4-iridanonaboranes by nuclear magnetic resonance spectroscopy and single-crystal X-ray diffraction analysis
  230. The reactions of arachno-decaboranyl complexes L2B10H12(L = two-electron donor ligand) with some platinum(II) compounds; nuclear magnetic resonance studies and the crystal and molecular structure of [8-Cl-7,7-(PMe2Ph)2-nido-7-PtB10H11]
  231. A novel closo-type metallaundecaborane, [1,1-(PPh3)2-2,5-(OEt)2-1-RuB10H8], and its relationship to the ‘isocloso’ series of metallaborane clusters
  232. closo–nido-Cluster isomerism in metallacarbaboranes via a change of metal valency state: molecular structure of µ-1,2-acetato-2-hydrido-2,10-bis(triphenylphosphine)-closo-1,2-carbairidadecaborane
  233. B-frame supported heterobimetallic species; molecular structure of [(Me3P)2Pt(Ph3P)(Ph2PC6H4)HIrB9H10]
  234. A macropolyhedral polymetallaborane cluster: molecular structure of the seventeen-vertex triplatinaheptadecaborane [(PhMe2P)4Pt3B14H16]
  235. An n.m.r. study of the arachno-[B10H12PPh2]–anion: and interesting arachno→arachno topological transition induced by deprotonation
  236. Heterobimetallic B-frame compounds: systematic synthesis and molecular structure of the seven-vertex µ-HOs,Pt-nido-osmaplatinaborane [(Ph3P)2(CO)(Os)(PhMe2P)ClHPtB5H7]
  237. The transition-metal assisted synthesis of the anti-octadecaborate Anion [B18H21]− from the Nido-dodecahydrononaborate anion [B9H12]−
  238. Corrigendum
  239. A novel diplatinadecaborane with a Pt–Pt bond: [(PMe2Ph)2(Pt2B8H14)]
  240. A fluxional arachno-1 -metallapentaborane, [1,1,1 -(CO)(PMe3)2(1-IrB4H9)]
  241. New modes of bonding in some platinum derivatives of B18H22: X-ray crystal structures of [(Pt2B18H16)(PMe2Ph)4] and of three structural lsomers of [(PtB18H20)(PMe2Ph)2]
  242. Proton and boron-11 nuclear spin relaxation and the molecular tumbling of nido-decaborane in perdeuterotoluene solution. An interesting transition in solute–solvent interaction behaviour
  243. Some ten-vertex nido-metallaboranes : oxidative insertion of iridium(I) and rhodium(I) into the arachno-nonaborate anion, [B9H14]–, and the crystal and molecular structure of 6-hydrido-6,6-bis(trip...
  244. Facile thermally-induced cluster oxidations in metallaborane chemistry: arachno→nido→closo reaction sequences exhibited by iridanonaboranes and iridadecaboranes, and the stabilization of the iridium(V) oxidation state
  245. Molecular structure of the 17-vertex conjuncto-platinaheptadecaborane [(PMe2Ph){PtB16H18(PMe2Ph)}]: a 16-vertex η6-hexadecaboranyl ligand
  246. A novel exo-bicyclic closo-six-vertex dimetalla-hexaborane : [1,1,2-(CO)3-1-(PPh3)-2,2-(Ph2PC6H4)2-close-(1,2-Ir2B4H2-3,5-)]. CH2Cl2
  247. Quantitative ortho-cycloboronation of P-phenyl groups in metallaborane chemistry and the crystal and molecular structure of the novel iso-closo-ten-vertex metallaborane [1,1,1-H(PPh3)(Ph2P-ortho-C6H4)-iso-closo-(1-IrB9H8-2-)]
  248. Corrigenda
  249. The chemistry of isomers of icosaborane(26), B20H26: synthesis and nuclear magnetic resonance study of various isomers of platinahenicosaboranes and diplatinadocosaboranes, and the X-ray crystal and molecular structures of 7,7-bis...
  250. A new route to isomers of icosaborane(26), B20H26. The use of 115.5-MHz11B and11B-{1H} nuclear magnetic resonance spectroscopy for the comparison and characterisation of separated isomers and the i...
  251. A novel oxidative insertion of a metal centre into a degraded closo-borane cluster; crystal and molecular structure of the ten-vertex iso-nido cluster [{IrC(OH)B8H6(OMe)}(C6H4PPh2)(PPh3)]
  252. Synthesis, molecular structure, and nuclear magnetic resonance investigation of the platinanonaborane and diplatinadecaborane cluster compounds, [4,4-(PMe2Ph)2-arachno-4-PtB8H12] and [6,6,9,9-(PMe2-Ph)4-arachno-6,9-Pt2B8H10]
  253. The characterisation of 1,1-diphenylstannacyclopentane and 1,1,6,6-tetraphenyl-1,6-distannacyclodecane. An X-ray diffraction study of the distannacyclodecane
  254. Indirect nuclear spin spin coupling constants of tin-119 and lead-207 to nitrogen and phosphorus in organometallic compounds
  255. An NMR investigation of the [B10H12]2− ligand in [Pt(B10H12) (PMe2Ph)2]
  256. Dynamic n.m.r. behaviour of {6,7,8,9-η4-nido-decaborato(2–)}bis(dimethylphenylphosphine)platinum(II), [Pt(η4-B10H12)(PMe2Ph)2]; a novel type of metalloborane fluxionality
  257. Bis-µ-(2,3,4-η3-nido-hexaboranyl)-bis(dimethylphenylphosphine)diplatinum(Pt–Pt), [Pt2(η3-B6H9)2(PMe2Ph)2], an unexpected product from the reaction of (B10
  258. The chemistry of isomeric icosaboranes, B20H26. Molecular structures and physical characterization of 2,2′- bi(nido-decaboranyl) and 2,6′-bi-(nido-decaboranyl)
  259. Reactions of the octahydrotriborate(1–) anion, [B3H8]–, with some complexes of cobalt(I), cobalt(II), rhodium(I), and iridium(I), and the characterization of the ‘borallyl’ co...
  260. NMR Studies on Halogeno-cis-bis(phosphine)-nido-pentaboranyl Derivatives of Nickel, Palladium, and Platinum
  261. The signs of nuclear spin-spin coupling constants in some organoplatinum compounds
  262. Isomers of B20H26: structural characterisation by X-ray diffraction of 2,2′-Bi(nido-decaboranyl)
  263. Cage expansion in metallopentaborane chemistry: the preparation and structure of 2-{carbonylbis(triphenylphosphine)irida}-nido-hexaborane, [(IrB5H8)(CO)(PPh3)2]
  264. Isomers of B20H26: elucidation of the structure of 6,6′-Bi(nido-decaboranyl) by11B-{1H} and1H-{11B} n.m.r. spectroscopy
  265. Isomers of icosaborane(26): some synthetic routes and preliminary characterisations in the bis(nido-decaboranyl) system
  266. N.m.r. evidence for a transition between isotropic and anisotropic thermal motion of nido-decaborane in an aromatic solvent
  267. Dicarbonyl(η-cyclopentadienyl)iron(II) derivatives of pentaborane(9)
  268. Some palladium(II) and platinum(II) derivatives of pentaborane(9)
  269. Formation and X-ray crystal structure of 1,1,6,6-tetraphenyl-1,6-distannacyclodecane
  270. Preparation and structure of 1,4-dichloro-1,1,3,3-tetraphenyl-catena-di-(boraphosphane), BH2Cl·PPh2·BH2·PPh2Cl
  271. N.M.R. studies of dimethyl cadmium partially oriented in the nematic phase of EBBA
  272. Auto-association in organometallic compounds: a nuclear magnetic double resonance study of methyl- and n-butyl-tin alkoxides
  273. Lead-207 shielding in organolead compounds
  274. Magnetic double-resonance measurements of rhodium, phosphorus, fluorine, and proton nuclear magnetic resonance parameters in some rhodium(I) and rhodium(III) compounds
  275. Auto-association in organometallic compounds: a nuclear magnetic resonance study of methylcadmium alkoxides
  276. Indirect nuclear spin-spin coupling of lead-207 to other magnetic nuclei
  277. Phosphorus-31 chemical shift anisotropies in organophosphorus compounds
  278. Nuclear spin–spin coupling between directly bound tin atoms studied by a novel form of INDOR spectroscopy
  279. The signs of nuclear spin coupling constants in some trifluoromethyl derivatives of platinum and of gold
  280. Studies of 199Hg nuclear shielding anisotropies and their relation to isotropic chemical shifts
  281. Magnetic double-resonance studies of platinum-195 chemical shifts in organoplatinum compounds
  282. The geometry of triethynyl phosphine partially oriented in a nematic liquid crystal
  283. Magnetic double resonance studies of trimethyltin chalcogenides
  284. Magnetic double resonance studies of carbon-13 and nitrogen-15 chemical shift anisotropies in methyl cyanide partially oriented in a nematic liquid crystal
  285. Nuclear spin–spin coupling between tin and other directly bound elements
  286. Determination of the sign and magnitude of J(XX) in [A n X] M p nuclear spin systems
  287. Magnetic double resonance studies of tin-119 chemical shifts in compounds with tin–sulphur bonds and related species
  288. The magnitude and sign of 1J(207Pb-207Pb) in hexamethyldilead
  289. Sign and magnitude of1K(Sn–C) in trimethylstannyl-lithium: the first example of a negative reduced nuclear spin–spin coupling constant between two directly bound Group IV elements
  290. Magnetic double resonance studies of some methyltin alkane- and benzene-thiolates
  291. Mercury-199 chemical shift anisotropy in methyl mercuric bromide
  292. Through-space spin coupling between phosphorus and hydrogen in .pi.-C5H5W(CO)2PR3X (R = methyl, phenyl, methoxy, etc. X = iodine, trimethyltin)
  293. Nuclear magnetic double resonance studies of organotin selenides
  294. Auto-association in organotin compounds: butyltin trialkoxides
  295. Electron impact fragmentation of isomeric trimethylstannylnorbornenes and some related compounds
  296. Magnetic double resonance studies of 119Sn chemical shifts in organotin compounds