Professor Jean-Yves Saillard

Cyclometallated 2‐Phenylpyrimidine Derived Platinum Complexes: Synthesis and Photophysi...

• European Journal of Inorganic Chemistry
• April 2021

Intercluster exchanges leading to hydride-centered bimetallic clusters: a multi-NMR, X-...

• Dalton Transactions
• January 2021

Metal–metal bonded alkaline-earth distannyls

• Chemical Science
• January 2021

Toward the Formation of N-Heterocyclic-Carbene-Protected Gold Clusters of Various Nucle...

• Inorganic Chemistry
• October 2020

Theoretical Analysis of the Mackay Icosahedral Cluster Pd55(PiPr3)12(μ3‐CO)20: An Open‐...

• Chemistry - A European Journal
• April 2020

Copper Clusters Containing Hydrides in Trigonal Pyramidal Geometry

• Inorganic Chemistry
• January 2020

Electron count and electronic structure of bare icosahedral Au32and Au33ionic nanoclust...

• Physical Chemistry Chemical Physics
• January 2020

Electron counting and bonding patterns in assemblies of three and more silver-rich supe...

• Nanoscale
• January 2020

Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates

• Chemical Communications
• January 2020

Stabilizing heteroatom‐centered 16‐vertex group 11 tetrahedral architectures: Bonding a...

• International Journal of Quantum Chemistry
• August 2019

Homoleptic Platinum/Silver Superatoms Protected by Dithiolates: Linear Assemblies of Tw...

• Journal of the American Chemical Society
• August 2019

DFT study of inter-ring haptotropic rearrangement in CpRu+ complexes of polycyclic arom...

• Journal of Organometallic Chemistry
• July 2019

Elucidating the Electronic Structure of the Ligated Cuboctahedral Palladium Cluster [Pd...

• Journal of Cluster Science
• June 2019

Synthesis of Bimetallic Copper‐Rich Nanoclusters Encapsulating a Linear Palladium Dihyd...

• Angewandte Chemie
• March 2019

Synthesis of Bimetallic Copper-Rich Nanoclusters Encapsulating a Linear Palladium Dihyd...

• Angewandte Chemie International Edition
• March 2019

Mono- and hexa-palladium doped silver nanoclusters stabilized by dithiolates

• Nanoscale
• January 2019

Redox-switching of ternary Ni(ii) and Cu(ii) complexes: synthesis, experimental and the...

• New Journal of Chemistry
• January 2019

Organometallic chemistry of new carbon materials. Structure and dynamic behavior of gro...

• New Journal of Chemistry
• January 2019

Cover Picture: The Mackay-Type Cluster [Cu43 Al12 ](Cp*)12 : Open-Shell 67-Electron Sup...

• Angewandte Chemie International Edition
• October 2018

Titelbild: Der Mackay-Cluster [Cu43 Al12 ](Cp*)12 : Ein offenschaliges 67-Elektronen-Su...

• Angewandte Chemie
• October 2018

Structurally Precise Dichalcogenolate-Protected Copper and Silver Superatomic Nanoclust...

• Accounts of Chemical Research
• September 2018

Heteroatom-Doping Increases Cluster Nuclearity: From an [Ag20 ] to an [Au3 Ag18 ] Core

• Chemistry - A European Journal
• August 2018

Der Mackay-Cluster [Cu43 Al12 ](Cp*)12 : Ein offenschaliges 67-Elektronen-Superatom mit...

• Angewandte Chemie
• July 2018

The Mackay-Type Cluster [Cu43 Al12 ](Cp*)12 : Open-Shell 67-Electron Superatom with Eme...

• Angewandte Chemie International Edition
• July 2018

Why is bis-indenylchromium a dimer? A DFT investigation

• Journal of Organometallic Chemistry
• March 2018

[M16Ni24(CO)40]4–: Coinage Metal Tetrahedral Superatoms as Useful Building Blocks Relat...

• The Journal of Physical Chemistry C
• February 2018

Synthesis and structural characterization of inverse-coordination clusters from a two-e...

• Chemical Science
• January 2018

Synthesis, structural characterization and transformation of an eight-electron superato...

• Nanoscale
• January 2018

Encapsulating Iodine and Copper into Copper(I) Clusters Stabilized by Dichalcogenolate ...

• Inorganic Chemistry
• October 2017

Coinage Metal Superatomic Cores: Insights into Their Intrinsic Stability and Optical Pr...

• Chemistry - A European Journal
• August 2017

Eight-Electron Silver and Mixed Gold/Silver Nanoclusters Stabilized by Selenium Donor L...

• Angewandte Chemie International Edition
• June 2017

Eight-Electron Silver and Mixed Gold/Silver Nanoclusters Stabilized by Selenium Donor L...

• Angewandte Chemie International Edition
• June 2017

Thermally induced inter-ring haptotropic rearrangements in π-complexes of molybdenum wi...

• Journal of Organometallic Chemistry
• February 2017

Ag13-Centered Cuboctahedral Architecture in Inorganic Cluster Chemistry: A DFT Investig...

• Inorganic Chemistry
• January 2017

ChemInform Abstract: Metal-Catalyzed Azide-Alkyne “Click” Reactions: Mechanistic Overvi...

• ChemInform
• November 2016

[Cu13 {S2 CN n Bu2 }6 (acetylide)4...

• Angewandte Chemie International Edition
• October 2016

[Cu13 {S2 CN n Bu2 }6 (acetylide)4...

• Angewandte Chemie International Edition
• October 2016

Metal-catalyzed azide-alkyne “click” reactions: Mechanistic overview and recent trends

• Coordination Chemistry Reviews
• June 2016

Ten-Electron Donor Indenyl Anion in Binuclear Transition-Metal Sandwich Complexes: Elec...

• ChemistrySelect
• April 2016

Atompräzise organometallische Zinkcluster

• Angewandte Chemie International Edition
• February 2016

Atom-Precise Organometallic Zinc Clusters

• Angewandte Chemie International Edition
• February 2016

Structure and Bonding Patterns in Large Molecular Ligated Metal Clusters

• January 2016

Reaction mechanisms of transition-metal-catalyzed azide–alkyne cycloaddition “click” re...

• Computational and Theoretical Chemistry
• December 2015

Geometry Flexibility of Copper Iodide Clusters: Variability in Luminescence Thermochromism

• Inorganic Chemistry
• May 2015

[Cu32(H)20{S2P(OiPr)2}12]: The Largest Number of Hydrides Recorded in a Molecular Nanoc...

• Chemistry - A European Journal
• April 2015

[Ag21{S2P(OiPr)2}12]+: An Eight-Electron Superatom

• Angewandte Chemie International Edition
• February 2015

Improvement of the quadratic non-linear optical properties of pyrimidine chromophores b...

• Dyes and Pigments
• February 2015

[Ag21{S2P(OiPr)2}12]+: An Eight-Electron Superatom

• Angewandte Chemie International Edition
• January 2015

[(η5-C5Me5)Ru]+ fragments ligated to polyaromatic hydrocarbons: an experimental and com...

• Dalton Transactions
• January 2015

Four-coordinate nickel(ii) and copper(ii) complex based ONO tridentate Schiff base liga...

• Dalton Transactions
• January 2015

A DFT investigation of some (formally) redox isomerization reactions of bis(pentalenyl)...

• Polyhedron
• January 2015

ChemInform Abstract: Dipolar and V-Shaped Structures Incorporating Methylenepyran and D...

• ChemInform
• August 2014

Addition and elimination reactions of H2 in ruthenaborane clusters: A computational study

• Journal of Organometallic Chemistry
• July 2014

Titelbild: Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball (Angew. Chem....

• Angewandte Chemie International Edition
• May 2014

Cover Picture: Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball (Angew. C...

• Angewandte Chemie International Edition
• May 2014

Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball

• Angewandte Chemie International Edition
• May 2014

Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball

• Angewandte Chemie International Edition
• May 2014

ChemInform Abstract: Encapsulating Hydrides and Main-Group Anions in D10-Metal Clusters...

• ChemInform
• April 2014

Dipolar and V-shaped structures incorporating methylenepyran and diazine fragments

• Tetrahedron
• April 2014

A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton

• Inorganic Chemistry
• February 2014

Molecular brass: Cu4Zn4, a ligand protected superatom cluster

• Chemical Communications
• January 2014

Anion Encapsulation and Geometric Changes in Hepta- and Hexanuclear Copper(I) Dichalcog...

• Inorganic Chemistry
• November 2013

A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: L...

• Journal of the American Chemical Society
• March 2013

Structural and spin diversity of M(indenyl)2 transition-metal complexes: a DFT investig...

• New Journal of Chemistry
• January 2013

Foreword

• Journal of Organometallic Chemistry
• December 2012

Molecular transition-metal boron compounds. Any interest?

• Solid State Sciences
• November 2012

Can high-hydride content hypoelectronic rhenaborane clusters take up dihydrogen? A theo...

• Polyhedron
• August 2012

A μ9-Iodide in a Tricapped Trigonal-Prismatic Geometry

• Inorganic Chemistry
• July 2012

Computational Methods: Transition Metal Clusters

• December 2011

Thermochromic Luminescence of Copper Iodide Clusters: The Case of Phosphine Ligands

• Inorganic Chemistry
• November 2011

An eleven-vertex deltahedron with hexacapped trigonal bipyramidal geometry

• Chemical Communications
• January 2011

ChemInform Abstract: Rare Earth Metal Borocarbides Examples of Coordination Compounds i...

• ChemInform
• June 2010

“Chain-Like” Trimetallic Ruthenium Complexes with C7Carbon-Rich Bridges: Experimental a...

• Journal of the American Chemical Society
• April 2010

The Coordination Chemistry of Azulene: A Comprehensive DFT Investigation

• Organometallics
• April 2010

Computational Methods: Transition Metal Clusters

• September 2009

Octanuclear Copper(I) Clusters Inscribed in a Se12Icosahedron: Anion-Induced Modulation...

• Journal of the American Chemical Society
• August 2009

The coordination of azepine to transition-metal complexes: A DFT analysis

• Inorganica Chimica Acta
• August 2009

Substituent effect in unsymmetrical lutetium bisphthalocyanines: a DFT analysis

• New Journal of Chemistry
• January 2009

Molecular Clusters. A Bridge to Solid State Chemistry. Von Thomas P. Fehlner, Jean-Fran...

• Angewandte Chemie
• November 2008

Dramatic Remote Substitutent Effects on the Electronic Spin State of Bis(scorpionate) I...

• Angewandte Chemie International Edition
• October 2008

Dramatic Remote Substitutent Effects on the Electronic Spin State of Bis(scorpionate) I...

• Angewandte Chemie International Edition
• October 2008

Electron-Sponge Behavior, Reactivity and Electronic Structures of Cobalt-Centered Cubic...

• European Journal of Inorganic Chemistry
• April 2008

Haptotropic Rearrangements in Sandwich (Fluorenyl)(Cyclopentadienyl) Iron and Ruthenium...

• Organometallics
• February 2008

Theoretical and electrochemical studies on organometallic symmetrical Schiff base compl...

• Dalton Transactions
• January 2008

Solid State and Electronic Structure of Rare Earth Metal Intercalated Graphite from Fir...

• ChemInform
• September 2007

Alkynyl Ruthenium Colorimetric Sensors:  Optimizing the Selectivity toward Fluoride Anion

• Inorganic Chemistry
• July 2007

Stabilization of Acepentalene by Coordination to Transition Metals:  A DFT Investigation

• Inorganic Chemistry
• April 2007

Metallaborane Reactivity. A Stoichiometric Mechanism for the Insertion of Two Alkynes i...

• Journal of the American Chemical Society
• March 2007

Molecular Clusters

• January 2007

Solid State and Electronic Structure of Rare Earth Metal Intercalated Graphite from Fir...

• Zeitschrift für Naturforschung B
• January 2007

Electron-Sponge Behavior and Electronic Structures in Cobalt-Centered Pentagonal Prisma...

• Inorganic Chemistry
• January 2007

The Versatility of Pentalene Coordination to Transition Metals: A Density Functional Th...

• Chemistry - A European Journal
• February 2006

Theoretical aspects of the bonding in acetylide-bridged organometallic dinuclear complexes

• Comptes Rendus Chimie
• August 2005

Groups 2 and 3 metal complexes incorporating fluorenyl ligands

• Coordination Chemistry Reviews
• June 2005

The electronic structure of the electron–reservoir complex CpFe(hexamethylbenzene) revi...

• Inorganica Chimica Acta
• March 2005

Bonding Analysis of Square-Antiprismatic and Fused Square-Antiprismatic Copper(I)-Selen...

• Journal of Cluster Science
• September 2004

Bonding in Tetrahedral Cu4(μ3-X)4L4Copper(I) Clusters:  A DFT Investigation†

• Inorganic Chemistry
• June 2004

Gd5Si2B8: A Ternary Rare-Earth-Metal Silicide Boride Compound

• Angewandte Chemie International Edition
• April 2004

Gd5Si2B8: A Ternary Rare-Earth-Metal Silicide Boride Compound

• Angewandte Chemie International Edition
• April 2004

Bis-allenylidene Metal Complex and Unique Related Radical with Delocalization of One El...

• Journal of the American Chemical Society
• April 2004

Synthesis and Characterization of Hypoelectronic Rhenaboranes. Analysis of the Geometri...

• Journal of the American Chemical Society
• March 2004

The X-Ray and Electronic Structures of GdB4.

• ChemInform
• September 2003

Structure and bonding in the hydrothermally synthesized copper(I) complex Cu4(μ2-Cl)4(B...

• Inorganica Chimica Acta
• July 2003

The X-ray and electronic structures of GdB4

• Solid State Sciences
• May 2003

Electron probe microanalysis in the ternary Gd–B–C system

• Solid State Sciences
• September 2002

Homodimetallic iron(II) hydrazones: syntheses, spectroscopic, electrochemical, and theo...

• New Journal of Chemistry
• February 2002

Theoretical, Thermodynamic, Spectroscopic, and Structural Studies of the Consequences o...

• Journal of the American Chemical Society
• October 2001

Stability of Tetraoxocyclobutane Revised:  Perturbation Theory and Density Functional S...

• The Journal of Physical Chemistry A
• June 2001

Search for New Allotropic Forms of Carbon Dioxide and Carbon Disulfide:  A Density Func...

• Journal of the American Chemical Society
• June 2000

Theoretical Investigation of Electron-Deficient and/or Paramagnetic Complexes Composed ...

• Organometallics
• June 1999

Different Ways To Distort a Tetracapped Tetrahedron on Route to Forming an E4M4Cubane: ...

• Journal of the American Chemical Society
• May 1999

The Distorted Pd9(μ:η5,η2-As2)4(PPh3)8 Architecture

• European Journal of Inorganic Chemistry
• April 1999

Rare earth metal borocarbides

• Coordination Chemistry Reviews
• December 1998

First 17−18−19-Electron Triads of Stable Isostructural Organometallic Complexes. The 17...

• Journal of the American Chemical Society
• November 1998

Is Ti(η8-pentalene)2 a 20-electron complex? A theoretical investigation of a pseudo ele...

• Chemical Communications
• January 1998

Electrooxidation of porphyrin free bases: fate of the π-cation radical

• New Journal of Chemistry
• January 1998

Electrochemistry of [Mo2Cp2(CO)4{μ-η2:η3-HC⋮C−C(R1)(R2)}]+Complexes (R1 = H, R2 = H, Me...

• Organometallics
• October 1997

Reactivity toward Dioxygen of Dicobalt Face-to-Face Diporphyrins in Aprotic Media. Expe...

• Journal of the American Chemical Society
• July 1997

Can carbon monoxide polymerize? A theoretical investigation of polyketone

• Chemical Communications
• January 1997

Synthesis, Characterization, and Molecular Orbital Analysis of [Et4N]2[(OC)5MoAsMo3(CO)...

• Inorganic Chemistry
• October 1995

Bonding Analysis in Inorganic Transition-Metal Cubic Clusters. 2. Metal-Centered Hexaca...

• Journal of the American Chemical Society
• May 1995

Promoter Effect of Chloride Ions on the Ruthenium-Catalyzed Hydroesterification of Ethy...

• Organometallics
• April 1995

Bonding analysis of inorganic transition-metal cubic clusters. 1. Noncentered hexacappe...

• Journal of the American Chemical Society
• January 1994

Framework expansion versus edge opening in a 50-electron phosphido-bridged triruthenium...

• Inorganic Chemistry
• April 1993

New polymetallic ruthenium carbonyl halide complexes: exotic combinations of electron d...

• Journal of the American Chemical Society
• December 1992

Cluster core isomerization from planar to tetrahedral: experimental and theoretical asp...

• Journal of the American Chemical Society
• July 1991

The possible existence of a heteronuclear octahedral hypercloso cluster: can nitrogen o...

• Inorganic Chemistry
• May 1991

Electronic structure of the new rare earth borocarbide Sc2BC2

• Journal of the Less Common Metals
• March 1990

Structural features of (C5H5)2Mo2S6clusters: an EHMO study

• Canadian Journal of Chemistry
• November 1989

Specific cleavage of a carbon–carbon bond in the complexation of C6Et6by Fe(C5Me5)+. Cr...

• Journal of the Chemical Society Chemical Communications
• January 1989

Six- and five-vertex organometallic clusters

• Inorganic Chemistry
• May 1985

Analyse structurale du phenyl pyruvate d'ethyle obtenu sous forme enolique par activati...

• Journal of Organometallic Chemistry
• June 1984

Carbon-hydrogen and hydrogen-hydrogen activation in transition metal complexes and on s...

• Journal of the American Chemical Society
• April 1984

Organometallic electron reservoirs. 7. One-step multiple formation of carbon-carbon bon...

• Journal of the American Chemical Society
• December 1982

Heteronuclear organotransition-metal clusters: rational syntheses and fluxional behavior

• Organometallics
• May 1982

Racemization of chiral tetrahedral organotransition-metal clusters: a novel fluxional p...

• Organometallics
• January 1982

Etude cristallochimique de derives du chrome(0)

• Journal of Organometallic Chemistry
• August 1975

Introduction

Preface

References

Main-group clusters: geometric and electronic structure

From molecules to extended solids

Transition to the solid state

Transition-metal clusters: geometric and electronic structure

Main-group–transition-metal clusters

Problem Answers

Inter-conversion of clusters and solid-state materials

Appendix: Fundamental concepts: a concise review

Hexacapped Cubic Transition Metal Clusters and Derivatives—a Theoretical Approach

Isolobal relationships between main-group and transition-metal fragments. Connections t...

Electron count versus structural arrangement in clusters based on a cubic transition me...