All Stories

  1. [FeFe]‐Hydrogenase Mimics Bearing Germylene Ligands: Synthesis, Protonation, and Electrochemical Properties
  2. Pyridylalkenolato-Stabilized Heavier Tetrylenes: Air-Stability Studies and Preliminary Coordination Chemistry
  3. Mechanochemical access to NDI-bridged Janus di-NHC complexes for light-driven redox-responsive catalysis
  4. Transition Metal–NHC Complexes with Embedded [FeFe]-Hydrogenase Mimics
  5. Tetrylenes are Able to Discern between Isomeric Structures of Unsaturated Osmium(IV) Polyhydrides
  6. A Lead-μ2-Tetrylide Complex with Osmium(IV) Terminal Components
  7. Attaching Metal-Containing Moieties to β-Lactam Antibiotics: The Case of Penicillin and Cephalosporin
  8. Polydentate Amidinato‐Silylenes, ‐Germylenes and ‐Stannylenes
  9. Cover Feature: Nucleobase Stacking Sustained by Pt−Pt Interactions (ChemistryEurope 2/2024)
  10. Amidinatotetrylenes Donor Functionalized on Both N Atoms: Structures and Coordination Chemistry
  11. Nucleobase Stacking Sustained by Pt−Pt Interactions
  12. A cross-metathesis approach for polymetallic [FeFe]-hydrogenase mimics
  13. Synthesis and Some Coordination Chemistry of Phosphane-Difunctionalized Bis(amidinato)-Heavier Tetrylenes: A Previously Unknown Class of PEP Tetrylenes (E = Ge and Sn)
  14. Synthesis, Structure, and Photophysical Properties of Platinum(II) (N,C,N′) Pincer Complexes Derived from Purine Nucleobases
  15. Frontispiece: Tetrelanes versus Tetrylenes as Precursors to Transition Metal Complexes Featuring Tridentate PEP Tetryl Ligands (E=Si, Ge, Sn)
  16. Tetrelanes versus Tetrylenes as Precursors to Transition Metal Complexes Featuring Tridentate PEP Tetryl Ligands (E=Si, Ge, Sn)
  17. Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe3)2}2 (E = Ge, Sn, Pb) and ECl{N(SiMe3)2} (E = Ge, Sn)
  18. Dipyrromethane‐Based PGeP Pincer Germyl Rhodium Complexes
  19. Advances in the synthesis and reactivity of group 6 metal allenyls
  20. Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid
  21. Cyclometallation of Heavier Tetrylenes: Reported Complexes and Applications in Catalysis
  22. Dipyrromethane‐Based PGeP Pincer Methylgermyl and Methoxidogermyl Nickel and Palladium Complexes
  23. Reactions of Late First‐Row Transition Metal (Fe‐Zn) Dichlorides with a PGeP Pincer Germylene
  24. Stannylenes based on pyrrole-phosphane and dipyrromethane-diphosphane scaffolds: syntheses and behavior as precursors to PSnP pincer palladium(ii), palladium(0) and gold(i) complexes
  25. Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe2(η4-cod)]: cis- versus trans-[PtMe2L2] Complexes and Cyclometalation Reactions
  26. Front Cover: The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes (Eur. J. Inorg. Chem. 10/2020)
  27. The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes
  28. The Transition Metal Chemistry of PGeP and PSnP Pincer Heavier Tetrylenes
  29. Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes
  30. A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex
  31. Two octahedral σ-borane metal (MnI and RuII) complexes containing a tripod κ3N,H,H-ligand: Synthesis, structural characterization, and theoretical topological study of the charge density
  32. A Germylene Supported by Two 2‐Pyrrolylphosphane Groups as Precursor to PGeP Pincer Square‐Planar Group 10 Metal(II) and T‐Shaped Gold(I) Complexes
  33. Two Types of sigma‐Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes
  34. Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement
  35. Mesityl(amidinato)tetrylenes as ligands in iridium(i) and iridium(iii) complexes: silicon versus germanium and simple κ1-coordination versus cyclometallation
  36. A dipyrromethane-based diphosphane–germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes
  37. Reversible Carbene Insertion into a Ge−N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes
  38. From a PGeP Pincer-Type Germylene to Metal Complexes Featuring Chelating (Ir) and Tripodal (Ir) PGeP Germyl and Bridging (Mn2) and Chelating (Ru) PGeP Germylene Ligands
  39. Ruthenium Carbene Complexes Analogous to Grubbs-I Catalysts Featuring Germylenes as Ancillary Ligands
  40. Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular stru...
  41. From a Diphosphanegermylene to Nickel, Palladium and Platinum Complexes Containing Germyl PGeP Pincer Ligands
  42. First Insertions of Carbene Ligands into Ge−N and Si−N Bonds
  43. Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene
  44. Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine–borane as a tripod κ3N,H,H-ligand
  45. Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes
  46. 2-(Methylamido)pyridine–Borane: A Tripod κ 3 -N,H,H Ligand in Trigonal Bipyramidal Rhodium(I) and Iridium(I) Complexes with an Asymmetric Coordination of Its BH 3 Group
  47. Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic Media
  48. [MnBrL(CO)4] (L = Amidinatogermylene): Reductive Dimerization, Carbonyl Substitution, and Hydrolysis Reactions
  49. Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO
  50. Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO
  51. A topological analysis of the bonding in [M2(CO)10] and [M3(μ-H)3(CO)12] complexes (M = Mn, Tc, Re)
  52. Amidinatogermylene Complexes of Copper, Silver, and Gold
  53. Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate ­Ligands
  54. The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes
  55. Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ 2 N , Ge -Amidinatogermylene Ligand
  56. Amidinatogermylene Derivatives of Ruthenium Carbonyl: New Insights into the Reactivity of [Ru 3 (CO) 12 ] with Two-Electron-Donor Reagents of High Basicity
  57. ELECTRON DENSITY STUDIES ON THE REGIOSELECTIVITY OF DEPROTONATION REACTIONS
  58. Conversion of a Monodentate Amidinate–Germylene Ligand into Chelating Imine–Germanate Ligands (on Mononuclear Manganese Complexes)
  59. Ring Opening and Bidentate Coordination of Amidinate Germylenes and Silylenes on Carbonyl Dicobalt Complexes: The Importance of a Slight Difference in Ligand Volume
  60. Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative
  61. Reactivity of a (Bis-NHC)tricarbonylruthenium(0) Complex with Methyl Triflate and Methyl Iodide. Formation of Methyl- and Acetylruthenium(II) Derivatives: Experimental Results and Mechanistic DFT Calculations
  62. Organic Amides as Suitable Precursors to Stabilize Stannylenes
  63. Deprotonation of C‐Alkyl Groups of Cationic Triruthenium Clusters Containing Cyclometalated C‐Alkylpyrazinium Ligands: Experimental and Computational Studies
  64. Synthesis and Reactivity of Cationic Triruthenium Clusters Derived from 2‐Methyl‐ and 4‐Methylpyrimidines: From Conventional Cyclometalated Ligands to Novel Types of N‐Heterocyclic Carbenes
  65. Easy abstraction of a hydride anion from an alkyl C–H bond of a coordinated bis(N-heterocyclic carbene)
  66. Expanding the coordination chemistry of donor-stabilized group-14 metalenes
  67. Reactivity of a Bis(N-heterocyclic carbene) with Ruthenium Carbonyl. Synthesis of Mono- and Trinuclear Derivatives and Ligand Modification via C–H Bond Activation
  68. Reactivity of a Quinoline-Tethered N-Heterocyclic Carbene with Polynuclear Ruthenium Carbonyls
  69. Reactivity of [Ru4(μ-H)4(CO)12] with bidentate ligands containing at least one N-heterocyclic carbene moiety
  70. QTAIM Analysis of the Bonding in Mo–Mo Bonded Dimolybdenum Complexes
  71. Reactions of CS2 and C(S)NPh Adducts of N‐Heterocyclic Carbenes with [Ru3(CO)12]: Remarkable Reactivity of These Betaines Involving One or Two C–S Bond Activation Processes
  72. Diaminogermylene and Diaminostannylene Derivatives of Gold(I): Novel AuM and AuM2(M = Ge, Sn) Complexes
  73. Reaction of [Ru3(CO)12] with Phenazine: Synthesis of C-Metalated Derivatives That Formally Arise from a C–H Oxidative Addition or a Long-Distance C-to-N Prototropy
  74. Synthesis of Mixed Tin–Ruthenium and Tin–Germanium–Ruthenium Carbonyl Clusters from [Ru3(CO)12] and Diaminometalenes (M = Sn, Ge)
  75. Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands
  76. Reactions of phthalazine, quinazoline, 4,7-phenanthroline and 2,3′-bipyridine with ruthenium carbonyl
  77. Reactivity of Phosphine- and Thioether-Tethered N-Heterocyclic Carbenes with Ruthenium Carbonyl
  78. Theoretical topological analysis of the electron density in a series of triosmium carbonyl clusters: [Os3(CO)12], [Os3(μ-H)2(CO)10], [Os3(μ-H)(μ-OH)(CO)10], and [Os3(μ-H)(μ-Cl)(CO)10]
  79. Reactivity of Diaminogermylenes with Ruthenium Carbonyl: Ru3Ge3 and RuGe2 Derivatives
  80. Different Reactivities of Pyrid-2-yl- and 6-Picol-2-yl-Functionalized NHC Ligands with [Ru3(CO)12]: C(sp2)−H and Double C(sp3)−H Bond Activation Reactions
  81. Reactivity of Cationic Triruthenium Carbonyl Clusters: From Pyrimidinium Ligands to N-Heterocyclic Carbenes
  82. Reactivity of [Ru3(CO)12] with a Phosphine-Functionalized Imidazol-2-ylidene and Its Imidazolium Salt
  83. The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters
  84. Trapping of Pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated Pyrid-2-ylidenes in Triruthenium Clusters
  85. ChemInform Abstract: Carbonyl Metal Clusters as Homogeneous Catalysts: Hydrogenation of Alkynes Mediated by Hydridotriruthenium Clusters Containing Bridging N- Donor Ligands
  86. The Bridging Acetylene to Bridging Vinylidene Rearrangement in a Triruthenium Carbonyl Cluster: A DFT Mechanistic Study
  87. Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic Carbenes: A Combined Experimental and DFT Computational Study
  88. Reductive Dimerization of Triruthenium Clusters Containing Cationic Aromatic N‐Heterocyclic Ligands
  89. From Allenes to Edge-Bridging Allyl Ligands or Face-Capping Alkenyl Ligands on a Triruthenium Hydrido Carbonyl Cluster: An Experimental and DFT Computational Study
  90. Cationic Heterocycles as Ligands: Synthesis and Reactivity with Anionic Nucleophiles of Cationic Triruthenium Clusters Containing C‐Metalated N‐Methylquinoxalinium or N‐Methylpyrazinium Ligands
  91. DFT Mechanistic Study of the Transformation of Cyclohexa-1,3-diene into a Bridging Allyl Ligand upon Reaction with a Triruthenium Hydrido Carbonyl Cluster
  92. Topological Analysis of the Electron Density in the N-Heterocyclic Carbene Triruthenium Cluster [Ru3(μ-H)2(μ3-MeImCH)(CO)9] (Me2Im = 1,3-dimethylimidazol-2-ylidene)
  93. Reactivity of [Ru4(μ-H)4(CO)12] with N-Heterocyclic Carbenes
  94. Reactivity of Protons, Tertiary Stannanes, and Alkynes with a Triruthenium Dihydrido Cluster Containing a Face-Capping NHC Ligand
  95. A Simple Preparation of Pyridine‐Derived N‐Heterocyclic Carbenes and Their Transformation into Bridging Ligands by Orthometalation
  96. A Simple Preparation of Pyridine‐Derived N‐Heterocyclic Carbenes and Their Transformation into Bridging Ligands by Orthometalation
  97. Double C−H Bond Activation of an NHC N-Methyl Group on Triruthenium and Triosmium Carbonyl Clusters: A DFT Mechanistic Study
  98. Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Carbonyl Clusters: Synthesis, Structure, and Reactivity
  99. From an N‐Methyl N‐Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple CH and CN Bond Activations
  100. From an N‐Methyl N‐Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple CH and CN Bond Activations
  101. Reactions of Conjugated Dienes with a Triruthenium Hydrido Carbonyl Cluster: Synthesis and Reactivity of Trinuclear Derivatives Having an Edge-Bridging Allyl Ligand
  102. Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters
  103. Reactivity of a triruthenium alkenyl cluster complex with conjugated diynes: Coupling of two diyne molecules via a face-capping diyne intermediate
  104. Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
  105. Mononuclear ruthenium complexes containing chiral aminooxazolines: Syntheses, X-ray studies and catalytic activity
  106. Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N′-dipyrid-2-ylurea
  107. A new coordination mode for (pyrid-2-yl)thiolate (L) ligands: Synthesis and characterization of [Ru6(μ3-H)(μ5-κ2-L)(μ-CO)(CO)15]
  108. High-Nuclearity Osmium Carbonyl Cluster Complexes Containing (6-Methylpyrid-2-yl)imido Ligands. Synthesis of Hepta-, Octa-, and Nonanuclear Derivatives
  109. Ruthenium Cluster Mediated Transformation of Linear Alkenes into Trienyl Ligands. Activation of Five C(sp3)−H Bonds of 1-Octene, 1-Nonene, and 1-Decene
  110. Reactivity of Indene, Fluorene, Azulene, and Acenaphthylene with a Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Dihydride
  111. Dinuclear Methoxy, Cyclooctadiene, and Barrelene Complexes of Rhodium(I) and Iridium(I)
  112. Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton:  Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms
  113. Reactions of μ3‐Alkenyl Triruthenium Carbonyl Clusters with Alkynes: Synthesis of Trinuclear μ‐//‐Alkyne, μ‐Vinylidene, and μ‐Dienoyl Derivatives
  114. High-Nuclearity Ruthenium Carbonyl Cluster Complexes Derived from 2-Amino-6-methylpyridine:  Synthesis of Nonanuclear Derivatives Containing μ 4 - and μ 5 ...
  115. Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a Basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride
  116. Methyl Levamisolium Triflate as a Precursor to a Chiral Bifunctional N-Heterocyclic Carbene-Thiolate Ligand:  Palladium(II) Complexes
  117. Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond
  118. Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine — Novel coordination modes for 2-imidopyridines
  119. Ruthenium‐Cluster‐Mediated Activation of All Bonds of a Methyl Group of 6,6′‐Dimethyl‐2,2′‐bipyridine and 2,9‐Dimethyl‐1,10‐phenanthroline: Transformation of the Latter into a 2‐Alkenyl‐9‐methyl‐1,10‐phenanthroline Ligand
  120. Triruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisole
  121. Triruthenium carbonyl clusters derived from chiral aminooxazolines: synthesis and catalytic activity
  122. Reactivity of Alkynes Containing α‐Hydrogen Atoms with a Triruthenium Hydrido Carbonyl Cluster: Alkenyl versus Allyl Cluster Derivatives
  123. Dichlorobis[(S)-2,3,5,6-tetrahydro-6-phenylimidazo[2,1-b]thiazole]nickel(II)
  124. Can μ4-Alkyne and μ3-Alkenyl Ligands Be Considered as Six- and Five-Electron Donors, Respectively?
  125. η2-Edge-Bridging and η3-Face-Capping Coordination of Conjugated Ynenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from 1,1-Dimethylhydrazine
  126. Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives
  127. Easy activation of two C–H bonds of an N-heterocyclic carbene N-methyl group
  128. Crystallographic report: [N,N′-Bis-(6-methylpyrid-2-ylium)-(1R,2R)-1,2-diaminocyclohexane] bis-[(p-cymene)- trichlororuthenate(II)]
  129. Edge‐Bridging and Face‐Capping Coordination of Alkenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from Hydrazines: Synthetic, Structural, Theoretical, and Kinetic Studies
  130. η3-Edge-Bridging versus η3-Face-Capping Coordination of a Conjugated Ynenyl Ligand on a Triruthenium Cluster Core
  131. Photolysis of diruthenium hexacarbonyl tetrahedrane compounds in Nujol glass matrices
  132. Hexaruthenium Carbonyl Cluster Complexes with Basal Edge-Bridged Square Pyramidal Metallic Skeleton:  Efficient Synthesis of 2-Imidopyridine Derivatives and Determination of Their Reactive Sites in Carbonyl Substitution Reactions
  133. Activation of All Bonds of a Methyl Group Attached to an Organic Fragment
  134. Activation of All Bonds of a Methyl Group Attached to an Organic Fragment
  135. Reactivity of a Triruthenium Cluster Complex Containing a μ3-η3(C,N2) Ligand Derived from 2-Amino-7,8-benzoquinoline. Coupling of This Ligand with C3 Fragments and Characterization of μ3
  136. Triruthenium, Hexaruthenium, and Triosmium Carbonyl Derivatives of 2-Amino-6-phenylpyridine
  137. Di‐ and Trinuclear Ruthenium and Osmium Bis(2‐pyridyl) Ketone Oximate Derivatives
  138. Influence of the bridging ligand on the substitution chemistry of neutral and cationic triruthenium carbonyl cluster complexes derived from 1,1-dimethylhydrazine
  139. Methylidyne–diyne coupling reactions onto a triruthenium cluster core
  140. Reactivity of Triosmium and Triruthenium Carbonyls with 2,2‘-Diamino-1,1‘-binaphthalene. Synthesis of C-and N-Metalated Derivatives
  141. Formation of a Highly Functionalized Azulene Ligand by Metal Cluster-Mediated Coupling of Three Conjugated Diynes
  142. Hexaruthenium cluster complexes of basal edge-bridged square pyramidal metallic skeleton. First efficient synthesis and reactivity studies
  143. Reactivity of a Triruthenium Ynenyl Cluster Complex with Diynes: Cluster-Mediated Combination of up to Three Substituted Butadiyne Molecules into a Carbon-Rich Hydrocarbyl Ligand
  144. Carbonyl substitution chemistry of neutral and cationic triruthenium cluster complexes derived from 1,1-dimethylhydrazine.
  145. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Bridging Ligands Derived from 2-Amino-7,8-benzoquinoline
  146. Facile C−S Bond Activation of Levamisole Hydrochloride on a Triruthenium Cluster Core
  147. The Important Role of Some Ancillary Ligands in the Chemistry of Carbonylmetal Cluster Complexes − Selected Reactivity of Triruthenium Clusters Containing Deprotonated 2-Aminopyridines
  148. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Deprotonated Di(2-pyridyl)amine in Unusual Coordination Modes
  149. Bis(μ-η2-benzene-1,2-dithiolato-κ3S,S′:S′)bis[(η6-p-cymene)ruthenium(II)]
  150. Benzophenone iminium tetrafluoroborate
  151. Reactivity of [Ru3(μ3-NPh)(μ3-CO)(CO)9] towards Activated Alkynes and Diynes − Isolation of a Trinuclear Intermediate During the Formation of Bi- and Tetranuclear Products
  152. Formation of a Diynedienyl Ligand by Coupling of Hexa-2,4-diyne and Hex-2-yn-4-en-4-yl Ligands onto a Triruthenium Cluster Core
  153. Reactivity of [Ru2(μ-η1:η1-NCPh2)(μ-η1:η2-PhCCHPh)(CO)6] with Alkynes. Insertion Reactions of Nonactivated Alkynes into Ru−C and Ru−N Bonds
  154. Formation of Cyclopentadienyl and Ruthenacyclopentadienyl Derivatives through Ynenyl-Diyne and Ynenyl-Alkyne Couplings onto a Triruthenium Cluster Core
  155. (tert-Butyl isocyanide)tetracarbonyl[N-(1,2,3,4-tetraphenylbutadienyl)benzophenone imine]diruthenium(I)
  156. (Benzylamine-N)(η5-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate
  157. (Benzophenone imine-N)nonacarbonyldirhenium(0)(Re—Re)
  158. Reactivity of [Ru3(μ-H)(μ-Me2pz)(CO)10] with 2,4-hexadiyne. Characterization of the first tetranuclear ynenyl complex
  159. Reactivity of Diynes with a 1-Azavinylidene-Bridged Triruthenium Carbonyl Cluster. Insertion Reactions of Diynes into Ru−H, Ru−C, and Ru−N Bonds
  160. Reactivity of Triosmium Carbonyl Clusters with 1,8-Diaminonaphthalene − Synthesis and Structural Characterization of Amido, Diamido, andC-Metalated Trinuclear Derivatives
  161. Reactivity of Triosmium Carbonyl Clusters with 1,8-Diaminonaphthalene − Synthesis and Structural Characterization of Amido, Diamido, and C-Metalated Trinuclear Derivatives
  162. Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Amido, and Orthometalated Imino Derivatives
  163. Reactivity of the Anionic Carbonyltrirhenium Cluster [Re3(µ-H)3(µ3-ampy)(CO)9]− − Synthesis of Neutral Phosphane and Alkenyl Derivatives
  164. Reactivity of the Anionic Carbonyltrirhenium Cluster [Re3(µ-H)3(µ3-ampy)(CO)9] − Synthesis of Neutral Phosphane and Alkenyl Derivatives
  165. Reactivity of [Re3(μ-H)3(μ3-ampy)(CO)9]-. Preparation of Heteronuclear Re3Au Carbonyl Cluster Complexes Containing Face-Capping and Edge-Bridging Gold Atoms
  166. Reactivity of 2-(Diphenylphosphanyl)thiophenol (HSC6H4PPh2) with Ruthenium and Osmium Carbonyl Complexes; Breaking of HSC6H4PPh2 into Sulfide, Phenyl and Diphenylphosphanyl Ligands on a Triruthenium Cluster
  167. Homogeneous Catalysis with Ruthenium Carbonyl Cluster Complexes: Hydrogenation of Alkynes
  168. Derivative Chemistry of [Ru2(μ-bdt)(CO)6], a Binuclear Ruthenium(I) Carbonyl Complex Containing a Bridging Benzene-1,2-dithiolate Ligand
  169. Derivative Chemistry of [Ru2(μ-bdt)(CO)6], a Binuclear Ruthenium(I) Carbonyl Complex Containing a Bridging Benzene-1,2-dithiolate Ligand
  170. Reactivity of 2-(Diphenylphosphanyl)thiophenol (HSC6H4PPh2) with Ruthenium and Osmium Carbonyl Complexes; Breaking of HSC6H4PPh2 into Sulfide, Phenyl and Diphenylphosphanyl Ligands on a Triruthenium Cluster
  171. Neutral Binuclear and Anionic Trinuclear Rhenium Carbonyl Complexes Containing Bridging Ligands Derived from 2-Amino- and 2-Mercaptopyridines
  172. Advances in the Reactivity of Amido-Bridged Binuclear Carbonylruthenium Complexes – Derivative Chemistry of the Cationic Complex [Ru2(μ-dan)(μ-H)(CO)6][BF4] (H2dan = 1,8-Diaminonaphthalene)
  173. Reactivity of the 1-azavinylidene cluster [Ru3(μ-H)(μ-NCPh2)(CO)10] with hydrogen, tertiary silanes and tertiary stannanes
  174. Reactivity of a 1-Azavinylidene-Bridged Triruthenium Carbonyl Cluster with Alkynes. Synthesis of Binuclear Derivatives Containing New C−H or C−N and C−C Bonds Formed by Alkyne Insertion into M−H or M−N and M−C Bonds
  175. Binuclear Iron(I), Ruthenium(I), and Osmium(I) Hexacarbonyl Complexes Containing a Bridging Benzene-1,2-dithiolate Ligand. Synthesis, X-ray Structures, Protonation Reactions, and EHMO Calculations
  176. Protonation of triruthenium carbonyl cluster complexes containing a bridging 1-azavinylidene ligand. Experimental results and EHMO calculations
  177. Reactivity studies on cationic non-hydridic triruthenium carbonyl clusters. Reactions of [Ru3(μ3-ampy)(CO)10][BF4] with hydrogen, triethylsilane and triphenylstannane
  178. Neutral and cationic diphenylphosphine and diphenylphosphido derivatives of a trinuclear ruthenium carbonyl cluster containing a bridging 1-azavinylidene ligand
  179. Carbonyl−Metal Clusters with Mixed O,N-Donor Ligands:  Reactivity of the Ureato Cluster [Ru3(μ-H)(μ3-HNCONMe2)(CO)9] with Phosphines. Structural Characterization of a Triphenylphosphine Derivative and of a Bi...
  180. Reactivity of a 1-Azavinylidene Ligand with Diphenylacetylene on a Ruthenium Carbonyl Cluster. A Remarkable Alkyne Insertion into a Metal−Nitrogen Bond
  181. Reversible Thermal Activation of a Triphenylphosphine P−C Bond on a Cationic Non-Hydridic Triruthenium Carbonyl Cluster Complex. Structural Characterization of a μ-η1:η2-Benzoyl Derivative
  182. Reactivity of a Cationic Non-Hydridic Triruthenium Carbonyl Cluster Complex with Anionic Reagents. Synthesis of New Tri- and Hexanuclear Derivatives
  183. Triosmium carbonyl complexes containing bridging ligands derived from ortho-functionalized anilines
  184. Neutral and anionic pyrazolyl-bridged triruthenium carbonyl cluster complexes. Reactions with bis(diphenylphosphino) methane, triphenylphosphine and diphenylphosphine
  185. Bi- and trinuclear carbonylruthenium clusters: a crystallographic and electronic comparative study
  186. Synthesis and Reactivity of Triruthenium Carbonyl Cluster Complexes Containing a Bridging 1-Azavinylidene Ligand Derived from Benzophenone Imine
  187. Tri- and binuclear ruthenium carbonyl complexes containing bridging ligands derived from ortho-substituted anilines. A comparative study of their syntheses using RuCl3 · nH2O or [Ru3(CO)12] as starting materials
  188. Reactivity of a cationic triruthenium hydridoalkenylcarbonyl cluster complex toward nucleophilic reagents. Carbonyl substitution versus alkene elimination reactions
  189. Homogeneous Hydrogenation of Diphenylacetylene Promoted by a Cationic Hydridoalkenyltriruthenium Cluster Complex. Kinetic Evidence for Cluster Catalysis
  190. Pyrazolate‐Bridged Ruthenium(I) Carbonyl Complexes
  191. IR studies and hydrogenation catalytic activity of heterogeneous catalysts prepared by thermal treatments of a face-bridged triruthenium carbonyl cluster supported on silica and alumina
  192. Alkyne, Triorganosilyl, and Triorganostannyl Derivatives of Anionic Triruthenium Carbonyl Cluster Complexes Containing Bridging Pyrazolyl Ligands
  193. Derivative Chemistry of Cationic Triruthenium Carbonyl Cluster Compounds. Reactions Leading to a Neutral Hexanuclear Complex Consisting of Two Vertex-Linked Metal Triangles
  194. Carbonyl Metal Clusters as Homogeneous Catalysts: Hydrogenation of Alkynes Mediated by Hydridotriruthenium Clusters Containing Bridging N-Donor Ligands
  195. Carbonyl clusters as homogeneous catalysts. Kinetic and molecular aspects of the hydrogenation of diphenylacetylene promoted by an alkenyl-bridged triruthenium cluster complex. [Erratum to document cited in CA122:9301]
  196. Synthesis, characterization, reactivity, and catalytic hydrogenation activity of the hexanuclear hexahydrido carbonyl cluster compound [Ru6(μ-H)60(μ3,ν2-ampy)2(CO)14 ] (Hampy = 2-amino-6-methylpyridine)
  197. Cationic Trinuclear 48-Electron Ruthenium Carbonyl Cluster Complexes Containing No Hydride Ligands
  198. Reactivity of [PPN][Ru3(.mu.-NO)(CO)10] with Tertiary Silanes and Stannanes
  199. Carbonyl Clusters as Homogeneous Catalysts. Kinetic and Molecular Aspects of the Hydrogenation of Diphenylacetylene Promoted by an Alkenyl-Bridged Triruthenium Cluster Complex
  200. Tricyclohexylphosphine- versus Triphenylphosphine-Substituted Derivatives of a Face-Bridged Triruthenium Carbonyl Cluster Complex. A Comparative Study of Their Synthesis, Structure, and Catalytic Activity in the Homogeneous Hydrogenation of Diphenylace...
  201. Synthesis, structure and hydrogenation catalytic activity of [Ru3(μ3,η2-ampy)(μ,η1:η2-PhCCHPh)(CO)6(PPh3) (Hampy = 2-amino-6-methylpyridine)
  202. [RuCl2(PH2Cy)(η6-p-cymene)]
  203. Synthesis and derivative chemistry of [Ru2(μ-PPh2) (μ-OH) 2(μ6-p-cymene) 2]+
  204. Preparation and Characterization of 92-Electron Hexahydridohexaruthenium Carbonyl Cluster Complexes. Their Potential Significance in Homogeneous Catalytic Hydrogenation
  205. .eta.1-Aryl-bridged triruthenium cluster complexes
  206. Reactivity of tertiary silanes and stannanes with an edge-bridged triruthenium carbonyl cluster complex
  207. Molecular clusters in homogeneous catalysis: kinetic and chemical evidence for the participation of triruthenium cluster complexes in a cluster-promoted catalytic hydrogenation of diphenylacetylene
  208. Structure of μ-[bis(chloroacetato-O)-mercury(II)-κ2Hg]-μ-[1,8-naphthalenediamino-κ2NN':κ2NN']-bis[cis-dicarbonyl(triisopropylphosphine-P)ruthenium(I)](Ru–Ru)
  209. Incorporation of silanes and diphenylacetylene into face-bridged triruthenium carbonyl clusters. Attempted hydrosilylation of diphenylacetylene
  210. Ruthenium(I) complexes containing bridging N-donor ligands: structure, synthesis and reactivity patterns
  211. Synthesis and structural characterization of triruthenium cluster complexes containing bridging .eta.1-phenyl and terminal .eta.1-phenyl ligands arising from the cleavage of triphenylphosphine ligands
  212. Reactivity of a face-bridged trinuclear ruthenium carbonyl cluster with diphenylacetylene and triorganotin hydrides. Attempted hydrostannation of diphenylacetylene
  213. Synthesis and reactivity of dithiodiphenylphosphinato-derivatives of rhodium. Crystal structure of the square-pyramidal rhodium(III) complex [RhI(η2-S2PPh2)(COMe)(PPh3)]
  214. Kinetic and chemical evidence for the participation of mononuclear catalytic species in the homogeneous hydrogenation of diphenylacetylene promoted by an edge-bridged triruthenium carbonyl cluster complex
  215. Incorporation of trialkylsilyl and trialkylstannyl groups into ruthenium carbonyl clusters. Carbonyl substitution versus trialkylsilane or trialkylstannane elimination in these clusters
  216. Cationic and neutral 50-electron triruthenium carbonyl clusters containing three bridging diphenylphosphido ligands
  217. Mercury-bridged transition-metal clusters. Synthesis of pentanuclear Ru3HgM (M  Mo, W, or Co) clusters and X-ray structure of [(Ru3(μ3,η2-ampy)(CO)9)-(μ3-Hg)Co(CO)4] (Hampy  2-amino-6-methylpyridine)
  218. Synthesis and reactivity of triruthenium carbonyl clusters containing bis(diphenylphosphino)methane and the face-bridging ligand 2-amido-6-methylpyridi
  219. Addition of mercury(II) electrophiles to [Ru2(C10H8N2)(CO)4(P-iso-Pr3)2] and selective insertion versus addition in the reactions of mercury(II) electrophiles with trinuclear diruthenium mercury clusters. X-ray structures of [Ru2Hg(O2CCF3)2(C10H8N2)(CO...
  220. Hydrogenation activity of [Ru3(μ-H)-(μ3-ampy)(CO)9] under homogeneous conditions (Hampy = 2-amino-6-methylpyridine)
  221. The chemical and electrochemical oxidation of pyridonate-bridged ruthenium(I) dimers. X-Ray structure of [Ru2(μ-pyO)2(CO)4(pyOH)2] (pyOH = 2-pyridone)
  222. Extensive substitution, protonation, and methoxidation reactions of triruthenium carbonyl clusters containing 2-amino-6-methylpyridinato (.mu.3-ampy) as a face-bridging ligand. X-ray structures of [Ru3(.mu.-H)(.mu.3-ampy)(CO)7(PPh3)2] and [Ru3(.mu.-H)2...
  223. Synthesis and reactivity of diphenylphosphine derivatives of [Ru3(μ-H)(μ3-ampy)(CO)9] and [Ru3(μ-H)2(μ3-ampy)(CO)9][BF4] (Hampy=2-amino-6-methylpyridine)
  224. The addition of protons and metallic electrophiles to the electron-rich RuRu bond of [Ru2(μ,-dan)(CO)4(PiPr3)2]. X-ray structure of [Ru2(μ-AgPPh3)(μ-dan)(CO)4(PiPr3)2][BF4]·CH2Cl2 (dan=1,8-diamidonaphthalene)
  225. Mercury—ruthenium mixed-metal carbonyl clusters containing 2-amido-6-methylpyridine (ampy) as a μ3,η2-ligand. Crystal structures of [Ru6(μ4-Hg)(μ3-ampy)2(CO)18]·2C4H8O and [Ru3(μ-HgBr)(μ3-ampy)(CO)9]
  226. Synthesis and reactions with electrophiles and nucleophiles of the ruthenium(I) complex [Ru2(µ-C10H8N2)(CO)6]. Crystal structure of [Ru2(µ-C10H8N2...
  227. Improved synthesis, solution and solid-state structure, and reactivity of [Ru2(µ-SePh)2(CO)6]
  228. Selective insertion of mercury(II) halides into the ruthenium–mercury bonds of trinuclear Ru2Hg clusters
  229. Reactions of [Ru2{μ-1,2-(NH)2C6H4}(CO)4(PPh3)2] with H+, NO+ and group 11 metal fragments. Syntheses of trinuclear Ru2M (M = Cu, Ag, Au) and pentanuclear Ru4Au clusters
  230. Diphenylphosphine and diphenylphosphido derivatives of [Ru3(μ-H)(μ3-ampy)(CO)9] (Hampy = 2-amino-6-methylpyridine)
  231. Selective carbonyl substitution reactions on [Ru3(μ-H)(μ3-ampy)(CO)9] and on its protonated derivative. Crystal structure of [Ru3(μ-H)2(μ3-ampy)(CO)9][BF4] (Hampy = 2-amino-6-methylpyridine)
  232. The thermal and photochemical reactions of [Ru3(CO)12] with tetraethyldiphosphite. X-ray structure of [Ru3(CO)10{μ-(EtO)2POP(OEt)2}]
  233. Notes. Nuclear magnetic resonance evidence for three different isomers of [Ru3(µ-H)(µ-bzim)(CO)9(PPh3)](bzim = benzimidazolate). Crystal structure of [Ru3(µ-H)(µ-bzim)(CO)10]·Me2CO
  234. The different reactivity of 2-aminopyridines and 2-pyridone with [Ru3(CO)12]. X-Ray crystal structure of [Ru3(µ-H)(µ3-anpy)(CO)9](hanpy = 2-anilinopyridine)
  235. Synthesis and reactivity of mono-, tri-, and poly-nuclear ruthenium carbonyl complexes containing the pyridine-2-thiolate ligand (pyS). Stepwise preparation of [Ru(pyS)2(CO)2] by reaction of [Ru3(CO)12] with ...
  236. Protonation and deprotonation reactions of triruthenium nona- and octa-carbonyl clusters containing a µ3-2-amido-6-methylpyridine (µ3-ampy) ligand. X-Ray structures of [Ru3(µ-H)2(µ3-ampy)(CO)9...
  237. μ-Amido complexes of ruthenium carbonyl. Asymmetric versus symmetric bridging preference of the monodeprotonated derivatives of 1,2-arenediamines. Crystal structure of [Ru3(μ-H)(μ-H3N2-4,5-Me2-1,2-phenylene)]
  238. Ru3(CO)9(PPh3)3: a convenient starting material for the synthesis of binuclear ruthenium(I) complexes. Crystal structure of Ru2(μ-L2)(CO)4(PPh3)2 (H2L2 = 1,8-diaminonaphthalene)
  239. Liquid Crystal Derivatives of Transition Metals (I): Tetracoordinated Copper (II) Complexes Derived From Schiffs Bases
  240. Synthesis and reactivity of binuclear pyrazolate-bridged ruthenium(I) complexes. Crystal structures of bis[µ-(3,5-dimethylpyrazolato-NN′)-tricarbonylruthenium(I)](Ru–Ru) and bis[µ-(3,5-dimethylpyrazolato-NN′)]-µ-iodo-bis[tricarbon...
  241. Homogeneous hydrogenation of tetrasubstituted alkene moieties in prochiral didehydro amino acid derivatives catalysed by iridium complexes
  242. The reactions of [Ru3(CO)12] with nitrogen-containing heterocycles. Crystal structures of [Ru3(µ-H)(µ3-ppy)(CO)9] and [Ru3(µ-napy)(µ-CO)3(CO)7]
  243. The synthesis of di- and tetra-nuclear p-cymene–osmium hydride complexes; characterisation by1H(187Os) reverse INEPT two-dimensional nuclear magnetic resonance spectroscopy
  244. The reactions of dichloro-bis(μ-chloro)-bis(η6-p-cymene)diosmium(II) and -diruthenium(II) with hexamethyldialuminium
  245. Pyrazolate bridged ruthenium(I) complexes. A convenient synthesis of ruthenium(I) compounds. The X-ray structure of bis-μ-(3,5-dimethylpyrazolate)bis(tricarbonyl-ruthenium(I)) (RuRu)
  246. The cyclometallation of benzoic acid to give rhodium, iridium, and osmium C,O-benzoates. X-Ray structure determination of the dibenzoate [(C5Me5)Rh(OOCPh)2(H2O)]
  247. Dicationic tetranuclear tetrahydrides of iridium, ruthenium, and osmium
  248. The x-ray molecular structure of (η6-p-Cymene)(dimethylsulphoxide-S)dichloroosmium(II)
  249. The reactions of the tri-µ-hydroxo-bis[η6-p-cymeneosmium(II)] cation with aldehydes and acids and the homogeneously catalysed oxidation of acetaldehyde and propionaldehyde with water. X-Ray structure of [(p-MeC6H4<...
  250. Mononuclear η6-p-cymeneosmium(II) complexes and their reactions with Al2Me6and other methylating reagents
  251. The cyclometallation of benzoic acid and the X-ray crystal structure of [C5Me5Ir(O2CC6H4)(Me2SO)]
  252. Dinuclear p-cymeneosmium hydride complexes; the measurement of 187Os chemical shifts using 1H-{187Os} two-dimensional n.m.r. spectroscopy
  253. Rhodium(I) and rhodium(III) arene complexes with N-carbazolyltriphenylphosphinegold(I) and other polycyclic arene ligands
  254. Synthesis and reactivity of mono- and hetero-nuclear rhodium(I) or iridium(I) complexes with 2-(2′-pyridyl)benzimidazole
  255. Rhodium(I) and iridium(I) π-arene complexes of indole and of N-indolylgold(I) derivatives. X-ray structure of [(Me3TFB)Rh(η6-HIn)]ClO4 (TFB = tetrafluorobenzobarrelene)
  256. N-indolyltriarylphosphinegold(I) derivatives as η6-arene ligands in pentamethylcyclopentadienylrhodium(III) complexes. X-ray structure of [(C5Me5)Rh(μ-In)AuP(C6H5)3](ClO4)2·CH2Cl2
  257. 2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3
  258. Iridium-catalysed homogeneous hydrogenation of prochiral enamides containing tetrasubstituted alkene moieties
  259. New biimidazole and bibenzimidazole derivatives: mono and binuclear palladium(II) or platinum(II) complexes and heterobinuclear palladium(II)-rhodium(I) or platinum(II)-rhodium(I) complexes
  260. Bi-imidazole (H2bim) and bibenzimidazole η3-allylic complexes of palladium(II). Mono- and tetra-nuclear palladium(II) and heteronuclear palladium(II)–rhodium(I) complexes. Crystal struct...
  261. Indolylgold(I) derivatives and indole as π-arene ligands in cationic rhodium(I) complexes
  262. Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes