All Stories

  1. Structure–Activity Relationships of Photoswitchable Diarylethene-Based β-Hairpin Peptides as Membranolytic Antimicrobial and Anticancer Agents
  2. Prospects of photopharmacology of diarylethenes
  3. Efficiently Photocontrollable or Not? Biological Activity of Photoisomerizable Diarylethenes
  4. Highly reactive bis-cyclooctyne-modified diarylethene for SPAAC-mediated cross-linking
  5. Bicyclo[1.1.1]pentane-Derived Building Blocks for Click Chemistry
  6. Conformational Plasticity of the Cell-Penetrating Peptide SAP As Revealed by Solid-State 19F-NMR and Circular Dichroism Spectroscopies
  7. Delivering Structural Information on the Polar Face of Membrane-Active Peptides: 19 F-NMR Labels with a Cationic Side Chain
  8. Delivering Structural Information on the Polar Face of Membrane-Active Peptides: 19 F-NMR Labels with a Cationic Side Chain
  9. Design, Synthesis, and Application of an Optimized Monofluorinated Aliphatic Label for Peptide Studies by Solid-State 19 F NMR Spectroscopy
  10. Design, Synthesis, and Application of an Optimized Monofluorinated Aliphatic Label for Peptide Studies by Solid-State 19 F NMR Spectroscopy
  11. Silica with immobilized phosphinic acid-derivative for uranium extraction
  12. Direct Photocontrol of Peptidomimetics: An Alternative to Oxygen-Dependent Photodynamic Cancer Therapy
  13. Following Ramachandran: exit vector plots (EVP) as a tool to navigate chemical space covered by 3D bifunctional scaffolds. The case of cycloalkanes
  14. Intramolecular functional group differentiation as a strategy for the synthesis of bridged bicyclic β-amino acids
  15. Synthesis of racemic and enantiopure 3,4-methanonipecotic acid
  16. Synthesis and Structural Analysis of Angular Monoprotected Diamines Based on Spiro[3.3]heptane Scaffold
  17. Synthesis of a 2,5-Diazabicyclo[2.2.1]heptane-Derived α,β-Diamino Acid
  18. The Most Reactive Amide As a Transition-State Mimic For cis–trans Interconversion
  19. Delivery of SiC-based nanoparticles into live cells driven by cell-penetrating peptides SAP and SAP-E
  20. Design and Synthesis of Novel 19F-Amino Acid: A Promising 19F NMR Label for Peptide Studies
  21. An Expedient and Practical Approach to Functionalized 3-Aza-, 3-Oxa-, and 3-Thiabicyclo[3.3.1]nonane Systems
  22. ChemInform Abstract: The Catalytic Asymmetric α-Benzylation of Aldehydes.
  23. Structure Analysis and Conformational Transitions of the Cell Penetrating Peptide Transportan 10 in the Membrane-Bound State
  24. Synthesis of Boc-protected 4,5-methano-β-proline
  25. Design and Synthesis of a Monofluoro-Substituted Aromatic Amino Acid as a Conformationally Restricted19F NMR ­Label for Membrane-Bound Peptides
  26. Synthesis of Trifluoromethyl-Substituted 3-Azabicyclo[n.1.0]alkanes: Advanced Building Blocks for Drug Discovery
  27. Innenrücktitelbild: Controlling Biological Activity with Light: Diarylethene-Containing Cyclic Peptidomimetics (Angew. Chem. 13/2014)
  28. Inside Back Cover: Controlling Biological Activity with Light: Diarylethene-Containing Cyclic Peptidomimetics (Angew. Chem. Int. Ed. 13/2014)
  29. Photoswitchable peptidomimetics
  30. Controlling Biological Activity with Light: Diarylethene-Containing Cyclic Peptidomimetics
  31. Stereolibrary of spirocyclic building blocks
  32. Gram-Scale Synthesis of 3,5-Methanonipecotic Acid, a Nonchiral Bicyclic β-Amino Acid
  33. Die katalytische asymmetrische α-Benzylierung von Aldehyden
  34. The Catalytic Asymmetric α-Benzylation of Aldehydes
  35. What Goes around Comes around-A Comparative Study of the Influence of Chemical Modifications on the Antimicrobial Properties of Small Cyclic Peptides
  36. Incorporation of labile trans-4,5-difluoromethanoproline into a peptide as a stable label for 19F NMR structure analysis
  37. Synthesis of 5-amino-2-aminoalkyl-1,3-oxazol-4-ylphosphonic acid derivatives and their use in the preparation of phosphorylated peptidomimetics
  38. Design, Synthesis, and Application of a Trifluoromethylated Phenylalanine Analogue as a Label to Study Peptides by Solid-State19F NMR Spectroscopy
  39. Design, Synthesis, and Application of a Trifluoromethylated Phenylalanine Analogue as a Label to Study Peptides by Solid-State19F NMR Spectroscopy
  40. Synthesis and Characterization of β-Trifluoromethyl-Substituted Pyrrolidines
  41. Stereochemical effects on the aggregation and biological properties of the fibril-forming peptide [KIGAKI]3 in membranes
  42. Confining the χ space of basic natural amino acids: cyclobutane-derived χ1,χ2-constrained analogues of arginine, lysine and ornithine
  43. Synthesis of Isomeric 6-Trifluoromethyl-3-azabicyclo[3.1.0]hexanes: Conformationally Restricted Analogues of 4-Trifluoromethylpiperidine
  44. A19F NMR Label to Substitute Polar Amino Acids in Peptides: A CF3-Substituted Analogue of Serine and Threonine
  45. A19F NMR Label to Substitute Polar Amino Acids in Peptides: A CF3-Substituted Analogue of Serine and Threonine
  46. Incorporation of cis- and trans-4,5-Difluoromethanoprolines into Polypeptides
  47. Incorporation of cis- and trans-4,5-Difluoromethanoprolines into Polypeptides
  48. Focused enumeration and assessing the structural diversity of scaffold libraries: conformationally restricted bicyclic secondary diamines
  49. Synthesis of a novel Boc-protected cyclopropane-modified proline analogue
  50. Trifluoromethyl-Substituted α-Amino Acids as Solid-State 19 F NMR Labels for Structural Studies of Membrane-Bound Peptides
  51. Exploiting the Addition of Trimethyl(trifluoromethyl)silane to Functionalized N-Benzylimines for the Preparation of Two Novel x-Trifluoromethyl x-Amino Acids
  52. 1-Alkyl-5-((di)alkylamino) Tetrazoles: Building Blocks for Peptide Surrogates
  53. ChemInform Abstract: Bicyclic Conformationally Restricted Diamines
  54. ChemInform Abstract: Expedient Synthesis of cis- and trans-3-Aminocyclobutanecarboxylic Acids.
  55. An Entry into Hexahydro-2H-thieno[2,3-c]pyrrole 1,1-Dioxide Derivatives
  56. Bicyclic Conformationally Restricted Diamines
  57. ChemInform Abstract: Trifluoromethyl-Substituted Cyclopropanes
  58. Expedient Synthesis of cis- and trans-3-Aminocyclobutanecarboxylic Acids
  59. Exploiting morph-DAST mediated ring-expansion of substituted cyclic β-amino alcohols for the preparation of cyclic fluorinated amino acids. Synthesis of 5-fluoromethylproline and 5-fluoropipecolic acid
  60. Synthesis of β-fluoro-β-proline
  61. Trifluoromethyl-substituted cyclopropanes
  62. Synthesis of enantiopure (R,R)- and (S,S)-cis-2,3-propanoprolines
  63. Cyclobutane-Derived Diamines: Synthesis and Molecular Structure
  64. ChemInform Abstract: 1-Amino-3,3-difluorocyclobutanecarboxylic Acid.
  65. ChemInform Abstract: Synthesis, Structure and Reactions of the Most Twisted Amide.
  66. ChemInform Abstract: Highly Enantioselective or Not? - Chiral Monodentate Monophosphorus Ligands in the Asymmetric Hydrogenation.
  67. Compatibility of the conformationally rigid CF3-Bpg side chain with the hydrophobic coiled-coil interface
  68. 1-Amino-3,3-difluorocyclobutanecarboxylic acid
  69. An optimized protocol for the multigram synthesis of 3-(trifluoromethyl)bicyclo[1.1.1]pent-1-ylglycine (CF3-Bpg)
  70. Synthesis of 2-azaspiro[3.3]heptane-derived amino acids: ornitine and GABA analogues
  71. Role of Peptide Folding and Aggregation in Triggering Membrane Perturbation
  72. Simple and Efficient Procedure for a Multigram Synthesis of Both trans- and cis-1-Amino-2-(trifluoromethyl)cyclopropane-1-carboxylic Acid
  73. 4-Fluoro-2,4-methanoproline
  74. Synthesis of a Conformationally Rigid Analogue of 2-Aminoadipic Acid ­Containing an 8-Azabicyclo[3.2.1]octane Skeleton
  75. A novel approach to 2,4-ethanoproline
  76. Trifluoromethyl-Substituted Analogues of 1-Aminocyclobutane-1-carboxylic Acid
  77. Conformationally Restricted Nonchiral Pipecolic Acid Analogues
  78. The Alignment of Membrane-Active Peptides Depends on the Lipid Phase State as Viewed by solid state 19F-NMR
  79. Synthesis of conformationally restricted glutamic acid analogs based on the spiro[3.3]heptane scaffold
  80. ChemInform Abstract: A Convenient Route to Trifluoromethyl-Substituted Cyclopropane Derivatives.
  81. Synthesis of Trifluoromethyl‐Substituted Proline Analogues as19F NMR Labels for Peptides in the Polyproline II Conformation
  82. Synthesis of Trifluoromethyl‐Substituted Proline Analogues as19F NMR Labels for Peptides in the Polyproline II Conformation
  83. A Convenient Route to Trifluoromethyl-Substituted Cyclopropane Derivatives
  84. Solid state 19F NMR parameters of fluorine-labeled amino acids. Part II: Aliphatic substituents
  85. Synthesis of 7-azabicyclo[2.2.1]heptane-1,4-dicarboxylic acid, a rigid non-chiral analogue of 2-aminoadipic acid
  86. An approach to 2-cyanopyrrolidines bearing a chiral auxiliary
  87. A New Target for Highly Stereoselective Katsuki–Sharpless Epoxidation – One-Pot Synthesis ofC2-Symmetric 2,2′-Bioxiranes
  88. Evaluating the amino acid CF3-bicyclopentylglycine as a new label for solid-state19F-NMR structure analysis of membrane-bound peptides
  89. Conformationally Rigid Trifluoromethyl-Substituted α-Amino Acid Designed for Peptide Structure Analysis by Solid-State19F NMR Spectroscopy
  90. Conformationally Rigid Trifluoromethyl-Substituted α-Amino Acid Designed for Peptide Structure Analysis by Solid-State19F NMR Spectroscopy
  91. New chiral monodentate phospholane ligands by highly stereoselective hydrophosphination
  92. Stereoselective synthesis of 2,4-methanoproline homologues
  93. Direct Phosphorylation of Thiazoles and Naphtothiazoles by Phosphorus(V) Acid Chlorides
  94. Conformationally rigid cyclic α-amino acids in the design of peptidomimetics, peptide models and biologically active compounds
  95. Direct Phosphorylation of Thiazoles and Naphthothiazoles by Phosphorus(V) Acid Chlorides.
  96. Highly Enantioselective or Not? — Chiral Monodentate Monophosphorus Ligands in the Asymmetric Hydrogenation
  97. Synthesis of a New Chiral Bisphospholane Ligand for the Rh(I)-Catalyzed Enantioselective Hydrogenation of Isomeric β-Acylamido Acrylates.
  98. Chiral Oxo- and Oxy-Functionalized Diphosphane Ligands Derived from Camphor for Rhodium(I)-Catalyzed Enantioselective Hydrogenation.
  99. Enantioselective Hydrogenation of Isomeric β-Acylamido β-Alkylacrylates with Chiral Rh(I) Complexes—Comparison of Phosphine Ligands and Substrates.
  100. Structural Correlations for Nucleophilic Addition to the CO Group: The Solvation Angle
  101. Synthesis of a New Chiral Bisphospholane Ligand for the Rh(I)-Catalyzed Enantioselective Hydrogenation of Isomeric β-Acylamido Acrylates
  102. A New Hydroxydiphosphine as a Ligand for Rh(I)-Catalyzed Enantioselective Hydrogenation.
  103. Highly Enantioselective or Not? ‐ Chiral Monodentate Monophosphorus Ligands in the Asymmetric Hydrogenation
  104. Highly stereoselective, thermodynamically controlled and reversible formation of a new P-chiral phosphine
  105. Chiral Oxo- and Oxy-Functionalized Diphosphane Ligands Derived from Camphor for Rhodium(I)-Catalyzed Enantioselective Hydrogenation
  106. A chiral tricyclic proline analogue obtained from camphor
  107. On the enantioselective hydrogenation of isomeric β-acylamido β-alkylacrylates with chiral Rh(I) complexes—comparison of phosphine ligands and substrates
  108. 3,5,7-Trimethyl-1-azatricyclo[3.3.1.13,7]decan-2-ylidene, an Aminocarbene without π Conjugation
  109. A new hydroxydiphosphine as a ligand for Rh(I)-catalyzed enantioselective hydrogenation
  110. Structure and chemistry of a zwitterionic amine–aldehyde adduct
  111. Organic molecules with abnormal geometric parameters
  112. Torsional effects on reactivity in glycosyl transfer
  113. Hochenantioselektiv oder nicht? – Chirale einzähnige Monophosphorliganden in der asymmetrischen Hydrierung
  114. Hochenantioselektiv oder nicht? - Chirale einzähnige Monophosphorliganden in der asymmetrischen Hydrierung
  115. Highly Enantioselective or Not?—Chiral Monodentate Monophosphorus Ligands in the Asymmetric Hydrogenation
  116. Synthesis, structure and reactions of the most twisted amide
  117. Direct Phosphorylation of Benzothiazoles and 4-Methyltthiazole
  118. Synthesis of strained Bi- and tricyclic systems by rearrangements of some bromosubstituted camphor derivatives
  119. Stereoelectronic interactions between hetero-atoms
  120. Distortion of the amide bond in amides and lactams. Photoelectron-spectrum and electronic structure of 3,5,7-trimethyl-1-azaadamantan-2-one, the most twisted amide
  121. Spontaneous, Millisecond Formation of a Twisted Amide from the Amino Acid, and the Crystal Structure of a Tetrahedral Intermediate
  122. Direct Phosphorylation ofN-Protected Imidazoles and Benzoimidazoles-A Route to 1H-Imidazol(benzoimidazol)-2-yl Phosphonic and Phosphinic Acids and Their Derivatives
  123. The Most Twisted Amide: Structure and Reactions
  124. Struktur und Reaktionen von 3,6,9-Trimethyl-1-aza-2-adamantanon, dem am stärksten verdrillten Amid
  125. A test for the reverse anomeric effect
  126. PHOSPHORYLATION OF ENAMINEHYDRAZONES AS AN EFFICIENT ROUTE TO DIAZAPHOSPHOLINES AND DIAZAPHOSPHOLES
  127. Synthesis of chiral functionalized phosphine ligands based on camphor skeleton
  128. Phosphorylation of 1,3-Di(N-alkyl)Azoles by Phosphorus(V) Acid Chlorides — a Route to Potential Haptens Derived from Phosphinic Acids
  129. Tungsten pentacarbonyl as a potential protecting group for soft lewis base centres in alkylation of multifunctional molecules
  130. Diamagnetic lanthanide tris-β-diketonates as ‘dissolving’ reagents
  131. Selective catalytic hydrogenation in the presence of lanthanide tris-β-diketonates as “protecting” reagents
  132. A new approach to the selective alkylation of difunctional compounds
  133. New selective shift reagents for primary alyphatic amines on the base of monophthalocyanine lanthanide complexes
  134. Plancher rearrangement in the reaction of 1,3,3-trimethyl-2-cyanomethyleneindoline with ortho-phenylenediamine
  135. Ring-chain isomerism of 1,3,3-trimethyl-2-formylmethylene-indoline (fischer aldehyde) oxime and associated reactions
  136. Investigation of the distribution of the negative charge in anionic cyanine dyes by means of lanthanide shift reagents
  137. Atropo-isomerism and abnormal temperature dependence of paramagnetic shifts in 1H NMR spectra of heterocyclic analogs of isoflavones in the presence of lanthanide chelates
  138. Interaction of lanthanide shift reagents with alkyltosylates of heterocyclic bases and tosylates of cyanine dyes
  139. Highly Enantioselective or Not? - Chiral Monodentate Monophosphorus Ligands in the Asymmetric Hydrogenation