All Stories

  1. Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles
  2. Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates
  3. Use of ion-mobility mass spectrometry (IMS-MS) to map polyoxometalate Keplerate clusters and their supramolecular assemblies
  4. A collection of robust methodologies for the preparation of asymmetric hybrid Mn–Anderson polyoxometalates for multifunctional materials
  5. A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage
  6. Directed assembly of nanoscale Co(ii)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates
  7. An unprecedented silver-decavanadate dimer investigated using ion-mobility mass spectrometry
  8. Engineering polyoxometalates with emergent properties
  9. Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv)
  10. [CoxCu1−x(DDOP)(OH2)(NO3)](NO3): hydrogen bond-driven distortion of cobalt(ii) by solid solution ‘network mismatch’
  11. Exploring the rotational isomerism in non-classical Wells–Dawson anions {W18X}: a combined theoretical and mass spectrometry study
  12. Pushing the frontiers in polyoxometalate and metal oxide cluster science
  13. Mapping the synthesis of low nuclearity polyoxometalates from octamolybdates to Mn-Anderson clusters
  14. Organic-soluble lacunary {M2(P2W15)2} polyoxometalate sandwiches showing a previously unseen αββα isomerism
  15. Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32−: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}
  16. Connecting theory with experiment to understand the initial nucleation steps of heteropolyoxometalate clusters
  17. Exploring the thermochromism of sulfite-embedded polyoxometalate capsules
  18. Electronic and photophysical properties of adducts of [Ru(bpy)3]2+ and Dawson-type sulfite polyoxomolybdates α/β-[Mo18O54(SO3)2]4−
  19. Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties
  20. Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly
  21. Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}
  22. Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry
  23. Understanding and mapping the assembly of a family of trimeric polyoxometalates: transition metal mediated Wells-Dawson (M18)-trimers
  24. Voltammetry of [R4N]4[M18O54(SO3)2] and [Ru(bpy)3]2[M18O54(SO3)2] (M = Mo, W) as microcrystals adhered to a glassy carbon electrode surface in contact with ionic liquid media
  25. A new C–C bond forming annulation reaction leading to pH switchable heterocycles