All Stories

  1. Coordination and Dehydrogenation of Diphosphine–Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative
  2. Hydride, alkyl and carbyne derivatives of the unsaturated heterometallic anion [MoWCp2(μ-PCy2)(μ-CO)2]−
  3. Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds
  4. 9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides
  5. One-step synthesis and P–H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives
  6. Trapping of an Heterometallic Unsaturated Hydride: Structure and Properties of the Ammonia Complex [MoMnCp(μ-H)(μ-PPh2)(CO)5(NH3)]
  7. N–O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)
  8. Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds
  9. Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]
  10. Acceptor Behavior and E–H Bond Activation Processes of the Unsaturated Heterometallic Anion [MoReCp(μ-PCy2)(CO)5]−(Mo═Re)
  11. E–H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]
  12. Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes*)(CO)2] (Mes* = 2,4,6-C6H2tBu3)
  13. Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex
  14. Carbodiimides as catalysts for the reduction of CO2 with boranes
  15. Reply to the ‘Comment on “Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−”’ by M. Green, Dalton Transactions, 2018, 47,...
  16. C−C and C−N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives
  17. Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands
  18. Divergent Reactivity of a Phosphinidene-Bridged Dimolybdenum Complex Toward 1-Alkynes: P–C, P–H, C–C, and C–H Couplings
  19. Synthesis of the Unsaturated [MMoCp(µ-PR2)(CO)5]-Anions (M = Mn, R = Ph; M = Re, R = Cy): Versatile Precursors of Heterometallic Complexes
  20. Phosphinidene-bridged binuclear complexes
  21. Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ–κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)]
  22. Sn–H bond additions to asymmetric trigonal phosphinidene-bridged dimolybdenum complexes
  23. Insertion reactions of small unsaturated molecules in the N–B bonds of boron guanidinates
  24. Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study
  25. Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]
  26. C–C and C–N Couplings in Reactions of the Benzylidyne-Bridged Complex [Mo2Cp2(μ-CPh)(μ-PCy2)(CO)2] with Small Unsaturated Organics
  27. Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex
  28. The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2]−: an entry to the chemistry of unsaturated nitrosyl complexes
  29. Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes
  30. Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center
  31. Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]
  32. Thermally Stable Diazoalkane Derivatives of the Unsaturated Ditungsten Hydride [W2Cp2(H)(μ-PCy2)(CO)2]
  33. Reactions of the Unsaturated Ditungsten Anion [W2Cp2(μ-PCy2)(μ-CO)2]−with C- and P-Based Electrophiles
  34. Activity of Mo–Mo and Mo–P multiple bonds at the phosphinidene complex [Mo2Cp2{μ-P(2,4,6-C6H2Bu3)}(μ-CO)2] in reactions with isocyanides and phosphine ligands
  35. Mild P–P Bond Cleavage in the Methyldiphosphenyl Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2Me)(CO)2] To Give Novel Phosphide-Bridged Trinuclear Derivatives
  36. Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)
  37. Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite ...
  38. Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo2(η5-C5H5)2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph) with isocyanides and secondary phosphines
  39. Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−
  40. Site-Selectivity in the Protonation and Related Reactions of Chalcogenophosphinidene-Bridged Dimolybdenum Cyclopentadienyl Complexes
  41. Novel Dimerization of Maleic Anhydride at a Mo2Complex: Phase-Driven Keto/Enol Tautomerism in a Phosphinidenium–Ylide Complex
  42. Monomerizing Alkali-Metal 3,5-Dimethylbenzyl Salts with Tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): Structural and Bonding Implications
  43. Insertion, Rearrangement, and Coupling Processes in the Reactions of the Unsaturated Hydride Complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with Isocyanides
  44. Thermally Induced Dehydrogenation of Amine–Borane Adducts and Ammonia–Borane by Group 6 Cyclopentadienyl Complexes Having Single and Triple ­Metal–Metal Bonds
  45. Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4
  46. Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity
  47. Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− toward Phosphorus- and Transition Metal-Based Electrophiles
  48. Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates
  49. Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions
  50. Electronic Structure and Reactivity of the Carbyne-Bridged Dimolybdenum Radical [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(μ-CO)]+
  51. Reversible P–C Coupling Reactions at the Unsaturated Dimolybdenum Carbyne Complex [Mo2(η5-C5H5)2(CPh)(μ-PCy2)(μ-SPh)(CO)]+
  52. Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Do...
  53. Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)
  54. Dimolybdenum Cyclopentadienyl Complexes with Bridging Chalcogenophosphinidene Ligands
  55. Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)
  56. Activation of H–H and H–O Bonds at Phosphorus with Diiron Complexes Bearing Pyramidal Phosphinidene Ligands
  57. Protonation reactions of the oxo complex cis-[Mo2(η5-C5H5)2(O)(μ-PPh2)2(CO)]. Hydroxo and tetrafluoroborate derivatives
  58. Reactivity of the Phosphinidene-Bridged Complexes [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(η6-1,3,5-C6H3tBu3)(CO)2] and [Mo2...
  59. Well-controlled synthesis of boronic-acid functionalised poly(lactide)s: a versatile platform for biocompatible polymer conjugates and sensors
  60. Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity
  61. Binuclear Carbyne and Ketenyl Derivatives of the Alkyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph)
  62. Polyamine-Stabilized Sodium Aryloxides: Simple Initiators for the Ring-Opening Polymerization ofrac-Lactide
  63. Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site
  64. Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets
  65. Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide
  66. Structure, Bonding, and Reactivity of Binuclear Complexes Having Asymmetric Trigonal Phosphinidene Bridges: Addition of 16-Electron Metal Carbonyl Fragments to the Dimolybdenum Compounds [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2L] and [Mo2Cp2(μ-PH)(CO)2L] (L = η6-...
  67. Chemistry of the Oxophosphinidene Ligand. 1. Electronic Structure of the Anionic Complexes [MCp{P(O)R*}(CO)2]−(M = Mo, W; R* = 2,4,6-C6H2tBu3) and Their Reactions with H+and C-Based Electrophiles.
  68. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C−E Bond Formation and C−O Bond Cleavage Processes in the Reactions of [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)] with Severalp-Block Elements (E) and Thei...
  69. Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(CO)2]
  70. Synthesis and Reactivity of the Triply Bonded Binuclear Anion [W2(η5-C5H5)2(μ-PCy2)(μ-CO)2]−: Tungsten Makes a Difference
  71. Structural diversity in polyamine Lewis base stabilised lithium aryloxides
  72. Tris(2-dimethylaminoethyl)amine: a simple new tripodal polyamine ligand for Group 1 metals
  73. Reactions of the Unsaturated Complex [Mo2(η5-C5H5)2(μ-PEt2)2(CO)2] with [Au(PR3)]+Cations: Kinetic Preference of the Mo−P Bonds as the Site of Attack of the Gold(I) Electrophile
  74. Low-Temperature N−O Bond Cleavage in Nitrosyl Ligands Induced by the Unsaturated Dimolybdenum Anion [Mo 2 (η 5 -C 5 H 5 ) 2 (μ-PPh 2 )(μ-CO) 2 ] −
  75. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 5. Heterometallic Clusters Derived from the Neutral Complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)]
  76. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 4. Carbonyl, Isocyanide, and Diphosphine Derivatives of the Complexes [M2(η5-C5H5)2(μ-COMe)(μ-PR2)2]BF4(M = W, R = Ph; M = Mo, R = Et)
  77. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 3. Formation and Cleavage of C−C and C−O Bonds in the Reactions of the Complexes [Mo2Cp2(µ-COMe)(µ-COR)(µ-PCy2)]BF4...
  78. Multisite Reactivity of the Unsaturated Methoxycarbyne Complex [Mo2(η5-C5H5)2(µ-COMe)(µ-PCy2)(µ-CO)]
  79. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy- and Methoxycarbyne Ligands. 2. Synthesis, Structure, and Bonding of 32- and 34-Electron Complexes
  80. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 1. Synthesis, Structure, and Bonding of 30-Electron Complexes
  81. Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand
  82. Formation of P−H, P−C, and C−H Bonds by Hydride Attack on a Electrophilic Phosphide-Bridged Dimolybdenum Complex. Trapping the Phosphinidene Ligand with Borane
  83. Formation and Cleavage of C−C, C−O, and O−H Bonds Involving Methoxycarbyne and Hydroxycarbyne Ligands at Unsaturated Dimolybdenum Complexes
  84. Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)