All Stories

  1. Solvent-Assisted N–O Bond Cleavage and Metal–Metal Bond Formation in the Reduction of Binuclear Nitrosyl Complexes [M2Cp2(μ-X)(μ-PtBu2)(NO)2] (MX = MoCl, WI): An Experimental and Theoretical...

    Article • Inorganic Chemistry, August 2025, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  2. C≡N and N≡O Bond Cleavages of Acetonitrile and Nitrosyl Ligands at a Dimolybdenum Center to Render Ethylidyne and Acetamidinate Ligands

    Article • Inorganic Chemistry, February 2024, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  3. Coordination of azol(in)ium dithiocarboxylate ligands to Au(iii): unexpected formation of a novel family of cyclometallated Au(iii) complexes, DFT calculations and catalytic studies

    Article • Dalton Transactions, January 2024, Royal Society of Chemistry

    Raquel Soengas, Dr Daniel Garcia Vivo

  4. Zinc amidinate-catalysed cyclization reaction of carbodiimides and alkynes. An insight into the mechanism

    Article • Dalton Transactions, January 2024, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  5. Isocyanide Cycloaddition and Coordination Processes at Trigonal Phosphinidene-Bridged MoRe and MoMn Complexes

    Article • Inorganics, September 2023, MDPI AG

    Dr Daniel Garcia Vivo

  6. E–H Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Hydrogen and p-Block Element Hydrides

    Article • Organometallics, August 2023, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  7. Cycloaddition and C–S Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Alkynes and Phenyl Isothiocyanate

    Article • Organometallics, July 2023, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  8. Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Sulfur and Selenium: From Chalcogenophosphinidene- to Trithiophosphonate-Bridged Derivatives

    Article • Inorganic Chemistry, March 2023, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  9. ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides

    Article • Organometallics, November 2022, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  10. Heterometallic phosphinidene-bridged complexes derived from the phosphanyl complexes syn-[MCp(PHR*)(CO)2] (M = Mo, W; R* = 2,4,6-C6H2Bu3)

    Article • Journal of Organometallic Chemistry, October 2022, Elsevier

    Dr Daniel Garcia Vivo

  11. Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N–O Bond Cleavage Reactions

    Article • Inorganic Chemistry, September 2022, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  12. Reactions of the unsaturated methyl-bridged complexes [Mo2Cp2(μ-CH3)(μ-P Bu2)(CO)x] (x = 1, 2) towards transition metal carbonyls: convenient dehydrogenative route to heterometallic methylidyne-bridged clusters

    Article • Journal of Organometallic Chemistry, February 2022, Elsevier

    Dr Daniel Garcia Vivo

  13. Electronic Structure and Donor Ability of an Unsaturated Triphosphorus-Bridged Dimolybdenum Complex

    Article • Inorganic Chemistry, July 2021, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  14. A glimpse into the chemical reactivity of the unsaturated hydride [MoWCp2(H)(μ-PCy2)(CO)2]

    Article • Journal of Organometallic Chemistry, March 2021, Elsevier

    Dr Daniel Garcia Vivo

  15. Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates

    Article • Inorganic Chemistry, October 2020, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  16. A Bridging Carbonyl of Unlikely Geometry: On the True Nature of the Technetium Complex [Tc2(μ-CO)2(CO)6(NC5H5)2]

    Article • September 2020, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  17. Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo–Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

    Article • Inorganic Chemistry, July 2020, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  18. P–N and N–Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

    Article • Inorganic Chemistry, May 2020, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  19. Coordination and Dehydrogenation of Diphosphine–Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

    Article • Inorganic Chemistry, November 2019, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  20. Hydride, alkyl and carbyne derivatives of the unsaturated heterometallic anion [MoWCp2(μ-PCy2)(μ-CO)2]−

    Article • Journal of Organometallic Chemistry, April 2019, Elsevier

    Dr Daniel Garcia Vivo

  21. Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds

    Article • Chemical Communications, January 2019, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  22. 9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides

    Article • Chemical Communications, January 2019, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  23. One-step synthesis and P–H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

    Article • Dalton Transactions, January 2019, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  24. Trapping of an Heterometallic Unsaturated Hydride: Structure and Properties of the Ammonia Complex [MoMnCp(μ-H)(μ-PPh2)(CO)5(NH3)]

    Article • Inorganics, November 2018, MDPI AG

    Dr Daniel Garcia Vivo

  25. N–O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)

    Article • Inorganic Chemistry, November 2018, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  26. Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds

    Article • Inorganic Chemistry, June 2018, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  27. Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]

    Article • Chemistry - A European Journal, May 2018, Wiley

    Dr Daniel Garcia Vivo

  28. Acceptor Behavior and E–H Bond Activation Processes of the Unsaturated Heterometallic Anion [MoReCp(μ-PCy2)(CO)5]−(Mo═Re)

    Article • Organometallics, May 2018, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  29. E–H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]

    Article • Inorganic Chemistry, February 2018, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  30. Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes*)(CO)2] (Mes* = 2,4,6-C6H2tBu3)

    Article • Inorganic Chemistry, January 2018, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  31. Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex

    Article • Inorganic Chemistry, January 2018, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  32. Carbodiimides as catalysts for the reduction of CO2 with boranes

    Article • Chemical Communications, January 2018, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  33. Reply to the ‘Comment on “Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−”’ by M. Green, Dalton Transactions, 2018, 47,...

    Article • Dalton Transactions, January 2018, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  34. C−C and C−N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives

    Article • Chemistry - A European Journal, September 2017, Wiley

    Dr Daniel Garcia Vivo

  35. Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands

    Article • Inorganic Chemistry, August 2017, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  36. Divergent Reactivity of a Phosphinidene-Bridged Dimolybdenum Complex Toward 1-Alkynes: P–C, P–H, C–C, and C–H Couplings

    Article • Organometallics, April 2017, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  37. Synthesis of the Unsaturated [MMoCp(µ-PR2)(CO)5]-Anions (M = Mn, R = Ph; M = Re, R = Cy): Versatile Precursors of Heterometallic Complexes

    Article • European Journal of Inorganic Chemistry, March 2017, Wiley

    Dr Daniel Garcia Vivo

  38. Phosphinidene-bridged binuclear complexes

    Article • Coordination Chemistry Reviews, January 2017, Elsevier

    Dr Daniel Garcia Vivo

  39. Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ–κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)]

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  40. Sn–H bond additions to asymmetric trigonal phosphinidene-bridged dimolybdenum complexes

    Article • RSC Advances, January 2017, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  41. Insertion reactions of small unsaturated molecules in the N–B bonds of boron guanidinates

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  42. Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  43. Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  44. C–C and C–N Couplings in Reactions of the Benzylidyne-Bridged Complex [Mo2Cp2(μ-CPh)(μ-PCy2)(CO)2] with Small Unsaturated Organics

    Article • Organometallics, October 2016, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  45. Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] with Diazoalkanes and Other Heterocumulenes

    Article • Inorganic Chemistry, October 2016, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  46. Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex

    Article • Chemistry - A European Journal, May 2016, Wiley

    Dr Daniel Garcia Vivo

  47. The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2]−: an entry to the chemistry of unsaturated nitrosyl complexes

    Article • Dalton Transactions, January 2016, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  48. Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

    Article • Dalton Transactions, January 2016, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  49. Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

    Article • Inorganic Chemistry, November 2015, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  50. Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]

    Article • Inorganic Chemistry, October 2015, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  51. Thermally Stable Diazoalkane Derivatives of the Unsaturated Ditungsten Hydride [W2Cp2(H)(μ-PCy2)(CO)2]

    Article • Organometallics, August 2015, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  52. Reactions of the Unsaturated Ditungsten Anion [W2Cp2(μ-PCy2)(μ-CO)2]−with C- and P-Based Electrophiles

    Article • Organometallics, March 2015, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  53. Activity of Mo–Mo and Mo–P multiple bonds at the phosphinidene complex [Mo2Cp2{μ-P(2,4,6-C6H2Bu3)}(μ-CO)2] in reactions with isocyanides and phosphine ligands

    Article • Inorganica Chimica Acta, January 2015, Elsevier

    Dr Daniel Garcia Vivo

  54. Mild P–P Bond Cleavage in the Methyldiphosphenyl Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2Me)(CO)2] To Give Novel Phosphide-Bridged Trinuclear Derivatives

    Article • Inorganic Chemistry, October 2014, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  55. Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)

    Article • Dalton Transactions, September 2014, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  56. Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite ...

    Article • Inorganic Chemistry, April 2014, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  57. Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo2(η5-C5H5)2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph) with isocyanides and secondary phosphines

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  58. Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  59. Site-Selectivity in the Protonation and Related Reactions of Chalcogenophosphinidene-Bridged Dimolybdenum Cyclopentadienyl Complexes

    Article • European Journal of Inorganic Chemistry, December 2013, Wiley

    Dr Daniel Garcia Vivo

  60. Novel Dimerization of Maleic Anhydride at a Mo2Complex: Phase-Driven Keto/Enol Tautomerism in a Phosphinidenium–Ylide Complex

    Article • Organometallics, November 2013, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  61. Monomerizing Alkali-Metal 3,5-Dimethylbenzyl Salts with Tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): Structural and Bonding Implications

    Article • Inorganic Chemistry, October 2013, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  62. Insertion, Rearrangement, and Coupling Processes in the Reactions of the Unsaturated Hydride Complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with Isocyanides

    Article • Organometallics, August 2013, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  63. Thermally Induced Dehydrogenation of Amine–Borane Adducts and Ammonia–Borane by Group 6 Cyclopentadienyl Complexes Having Single and Triple ­Metal–Metal Bonds

    Article • European Journal of Inorganic Chemistry, August 2013, Wiley

    Dr Daniel Garcia Vivo

  64. Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

    Article • Organometallics, August 2013, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  65. Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity

    Article • Coordination Chemistry Reviews, August 2013, Elsevier

    Dr Daniel Garcia Vivo

  66. Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]−toward Phosphorus- and Transition Metal-Based Electrophiles

    Article • Inorganic Chemistry, July 2013, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  67. Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates

    Article • Chemical Communications, January 2013, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  68. Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  69. Electronic Structure and Reactivity of the Carbyne-Bridged Dimolybdenum Radical [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(μ-CO)]+

    Article • Organometallics, December 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  70. Reversible P–C Coupling Reactions at the Unsaturated Dimolybdenum Carbyne Complex [Mo2(η5-C5H5)2(CPh)(μ-PCy2)(μ-SPh)(CO)]+

    Article • Organometallics, October 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  71. Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]−Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Don...

    Article • Inorganic Chemistry, September 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  72. Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

    Article • Inorganic Chemistry, September 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  73. Dimolybdenum Cyclopentadienyl Complexes with Bridging Chalcogenophosphinidene Ligands

    Article • Inorganic Chemistry, July 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  74. Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

    Article • Inorganic Chemistry, June 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  75. Activation of H–H and H–O Bonds at Phosphorus with Diiron Complexes Bearing Pyramidal Phosphinidene Ligands

    Article • Inorganic Chemistry, March 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  76. Protonation reactions of the oxo complex cis-[Mo2(η5-C5H5)2(O)(μ-PPh2)2(CO)]. Hydroxo and tetrafluoroborate derivatives

    Article • Journal of Organometallic Chemistry, February 2012, Elsevier

    Dr Daniel Garcia Vivo

  77. Reactivity of the Phosphinidene-Bridged Complexes [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(η6-1,3,5-C6H3tBu3)(CO)2] and [Mo2...

    Article • Organometallics, January 2012, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  78. Well-controlled synthesis of boronic-acid functionalised poly(lactide)s: a versatile platform for biocompatible polymer conjugates and sensors

    Article • RSC Advances, January 2012, Royal Society of Chemistry

    Dr Daniel Garcia Vivo, Tony D James

  79. Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

    Article • Inorganic Chemistry, December 2011, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  80. Binuclear Carbyne and Ketenyl Derivatives of the Alkyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph)

    Article • Organometallics, April 2011, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  81. Polyamine-Stabilized Sodium Aryloxides: Simple Initiators for the Ring-Opening Polymerization ofrac-Lactide

    Article • Inorganic Chemistry, April 2011, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  82. Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site

    Article • Inorganic Chemistry, March 2011, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  83. Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

    Article • Chemistry - A European Journal, February 2011, Wiley

    Dr Daniel Garcia Vivo

  84. Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  85. Structure, Bonding, and Reactivity of Binuclear Complexes Having Asymmetric Trigonal Phosphinidene Bridges: Addition of 16-Electron Metal Carbonyl Fragments to the Dimolybdenum Compounds [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2L] and [Mo2Cp2(μ-PH)(CO)2L] (L = η6-...

    Article • Organometallics, October 2010, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  86. Chemistry of the Oxophosphinidene Ligand. 1. Electronic Structure of the Anionic Complexes [MCp{P(O)R*}(CO)2]−(M = Mo, W; R* = 2,4,6-C6H2tBu3) and Their Reactions with H+and C-Based Electrophiles.

    Article • Inorganic Chemistry, October 2010, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  87. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C−E Bond Formation and C−O Bond Cleavage Processes in the Reactions of [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)] with Severalp-Block Elements (E) and Thei...

    Article • Organometallics, May 2010, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  88. Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(CO)2]

    Article • Journal of Organometallic Chemistry, May 2010, Elsevier

    Dr Daniel Garcia Vivo

  89. Synthesis and Reactivity of the Triply Bonded Binuclear Anion [W2(η5-C5H5)2(μ-PCy2)(μ-CO)2]−: Tungsten Makes a Difference

    Article • Organometallics, February 2010, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  90. Structural diversity in polyamine Lewis base stabilised lithium aryloxides

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  91. Tris(2-dimethylaminoethyl)amine: a simple new tripodal polyamine ligand for Group 1 metals

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Dr Daniel Garcia Vivo

  92. Reactions of the Unsaturated Complex [Mo2(η5-C5H5)2(μ-PEt2)2(CO)2] with [Au(PR3)]+Cations: Kinetic Preference of the Mo−P Bonds as the Site of Attack of the Gold(I) Electrophile

    Article • Inorganic Chemistry, October 2009, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  93. Low-Temperature N−O Bond Cleavage in Nitrosyl Ligands Induced by the Unsaturated Dimolybdenum Anion [Mo 2 (η 5 -C 5 H 5 ) 2 (μ-PPh 2 )(μ-CO) 2 ] −

    Article • Inorganic Chemistry, October 2009, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  94. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 5. Heterometallic Clusters Derived from the Neutral Complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)]

    Article • Organometallics, August 2009, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  95. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 4. Carbonyl, Isocyanide, and Diphosphine Derivatives of the Complexes [M2(η5-C5H5)2(μ-COMe)(μ-PR2)2]BF4(M = W, R = Ph; M = Mo, R = Et)

    Article • Organometallics, August 2008, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  96. Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methyli...

    Article • Organometallics, April 2008, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  97. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 3. Formation and Cleavage of C−C and C−O Bonds in the Reactions of the Complexes [Mo2Cp2(µ-COMe)(µ-COR)(µ-PCy2)]BF4...

    Article • Organometallics, February 2008, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  98. Multisite Reactivity of the Unsaturated Methoxycarbyne Complex [Mo2(η5-C5H5)2(µ-COMe)(µ-PCy2)(µ-CO)]

    Article • Organometallics, January 2008, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  99. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy- and Methoxycarbyne Ligands. 2. Synthesis, Structure, and Bonding of 32- and 34-Electron Complexes

    Article • Organometallics, October 2007, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  100. Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 1. Synthesis, Structure, and Bonding of 30-Electron Complexes

    Article • Organometallics, August 2007, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  101. Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

    Article • Inorganic Chemistry, July 2007, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  102. Formation of P−H, P−C, and C−H Bonds by Hydride Attack on a Electrophilic Phosphide-Bridged Dimolybdenum Complex. Trapping the Phosphinidene Ligand with Borane

    Article • Organometallics, December 2006, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo

  103. Formation and Cleavage of C−C, C−O, and O−H Bonds Involving Methoxycarbyne and Hydroxycarbyne Ligands at Unsaturated Dimolybdenum Complexes

    Article • Organometallics, July 2005, American Chemical Society (ACS)

    Dr Daniel Garcia Vivo, Dr- Celedonio M. Alvarez

  104. Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)

    Article • Dalton Transactions, January 2004, Royal Society of Chemistry

    Dr Daniel Garcia Vivo, Dr- Celedonio M. Alvarez