All Stories

  1. Preface
  2. Carbohydrate Chemistry II
  3. (1R)-2,3,4,6-Tetra-O-benzyl-1-C-allyl-1-deoxy-1-C-(2-thiazolyl)-d-galactopyranose
  4. Thiazolylketol Acetates as Glycosyl Donors: Stereoselective Synthesis of a C-Ketoside
  5. Recent Advances in Synthesis and Applications of Calixarene Derivatives Endowed with Anticancer Activity
  6. New Analogues of the Nicotinamide Phosphoribosyltransferase Inhibitor FK866 as Potential Anti-Pancreatic Cancer Agents
  7. Recent Advances in the Synthesis and Applications of Ionic Liquids Derived from Natural Products
  8. Iminosugar-Based Nicotinamide Phosphoribosyltransferase (NAMPT) Inhibitors as Potential Anti-Pancreatic Cancer Agents
  9. Synthesis of Chiral Ionic Liquids from Natural Monosaccharides
  10. Synthesis and Applications of Carbohydrate-Based Organocatalysts
  11. Iminosugars as glycosyltransferase inhibitors
  12. Modified Galacto‐ or Fuco‐Clusters Exploiting the Siderophore Pathway to Inhibit the LecA‐ or LecB‐Associated Virulence of Pseudomonas aeruginosa
  13. Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)
  14. On the scope of SuFEx as a bioorthogonal click process
  15. Protein Glycosylation through Sulfur Fluoride Exchange (SuFEx) Chemistry: The Key Role of a Fluorosulfate Thiolactoside
  16. SuFEx: a metal-free click ligation for multivalent biomolecules
  17. Synthesis and biological properties of imino-disaccharides and -oligosaccharides
  18. A Click Ligation Based on SuFEx for the Metal‐Free Synthesis of Sugar and Iminosugar Clusters
  19. A metal-free synthetic approach to peptide-based iminosugar clusters as novel multivalent glycosidase inhibitors
  20. Role of a Preorganized Scaffold Presenting Four Residues of a GM-3 Lactone Mimetic on Melanoma Progression
  21. Validating the alkene and alkyne hydrophosphonylation as an entry to organophosphonates
  22. Metal-free synthesis of E-vinylphosphonates via photoinduced alkyne hydrophosphonylation and thiol promoted isomerization sequence
  23. Synthesis and biological properties of multivalent iminosugars
  24. Emerging trends in enzyme inhibition by multivalent nanoconstructs
  25. CHAPTER 4. Multivalent Glycocalixarenes: Synthesis and Molecular Recognition
  26. Synthesis and glycosidase inhibition properties of triazole-linked calixarene–iminosugar clusters
  27. Synthesis of Galactoclusters by Metal-Free Thiol “Click Chemistry” and Their Binding Affinities forPseudomonas aeruginosaLectin LecA
  28. Thiol-ene and thiol-yne-based synthesis of glycodendrimers as nanomolar inhibitors of wheat germ agglutinin
  29. Metal-Catalyzed and Metal-Free Alkyne Hydrothiolation: Synthetic Aspects and Application Trends
  30. Discussion Addendum for: Diastereoselective Homologation of D-(R)-Glyceraldehyde Acetonide Using 2-(Trimethylsilyl)thiazole: 2-O-Benzyl-3,4-isopropylidene-D-erythrose
  31. Chapter 9. Electrochemical glycosylation
  32. Oxime Ligation: A Chemoselective Click-Type Reaction for Accessing Multifunctional Biomolecular Constructs
  33. Synthesis of rapamycin glycoconjugates via a CuAAC-based approach
  34. Efficiency of the Free-Radical Hydrophosphonylation of Alkenes: The Photoinduced Reaction of DimethylH-Phosphonate with Enopyranoses as an Exemplary Case
  35. Multivalent presentation of a hydrolytically stable GM3 lactone mimetic as modulator of melanoma cells motility and adhesion
  36. Free-Radical Thiol-Ene and Thiol-Yne Couplings as Click Processes for Glycoconjugation
  37. Thiyl Glycosylation of Propargylated Octasilsesquioxane: Synthesis and Lectin-Binding Properties of Densely Glycosylated Clusters on a Cubic Platform
  38. Tetravalent glycocyclopeptide with nanomolar affinity to wheat germ agglutinin
  39. Conformational Constraints: Nature Does It Best with Sialyl Lewisx
  40. Free-radical hydrothiolation of glycals: a thiol-ene-based synthesis of S-disaccharides
  41. Recent applications of thiol–ene coupling as a click process for glycoconjugation
  42. Glycoside and peptide clustering around the octasilsesquioxane scaffold via photoinduced free-radical thiol–ene coupling. The observation of a striking glycoside cluster effect
  43. Exhaustive glycosylation, pegylation, and glutathionylation of a [G4]-ene48 dendrimer via photoinduced thiol-ene coupling
  44. Sugar-Derived Ionic Liquids
  45. Multi-molecule reaction of serum albumin can occur through thiol-yne coupling
  46. Convergent synthesis and inclusion properties of novel Cn-symmetric triazole-linked cycloglucopyranosides
  47. Synthesis of S-glycosyl amino acids and S-glycopeptides via photoinduced click thiol–ene coupling
  48. Modular Approach to Triazole-Linked 1,6-α- d -Oligomannosides to the Discovery of Inhibitors of Mycobacterium tuberculosis Cell Wall Synthetase
  49. Calixarene and Calixresorcarene Glycosides: Their Synthesis and Biological Applications
  50. Photoinduced Addition of Glycosyl Thiols to Alkynyl Peptides: Use of Free-Radical Thiol−Yne Coupling for Post-Translational Double-Glycosylation of Peptides
  51. Copper(I)-Catalyzed Azide-Alkyne Cycloadditions in Ionic Liquids under Amine-Free Conditions
  52. Synthesis of Sugar-Based Silica Gels by Copper-Catalysed Azide-Alkyne Cycloaddition via a Single-Step Azido-Activated Silica Intermediate and the Use of the Gels in Hydrophilic Interaction Chromatography
  53. Immobilization of calix[4]arene-based glycoclusters on TiO2nanoparticlesvia click Cu(i)-catalyzed azide–alkyne coupling
  54. A theoretical study of the copper(i)-catalyzed 1,3-dipolar cycloaddition reaction in dabco-based ionic liquids: the anion effect on regioselectivity
  55. Synthesis and Applications of Ionic Liquids Derived from Natural Sugars
  56. Studies Toward the Synthesis of Inhibitors of Mycobacterium tuberculosis Cell-Wall Biosynthesis: The Assembly of Triazole-Linked 1,6-α-d-Oligomannosides via Click CuAAC
  57. Transformation of linear oligoketosides into macrocyclic neoglycoconjugates
  58. Photoinduced Thiol−Ene Coupling as a Click Ligation Tool for Thiodisaccharide Synthesis
  59. Design of Triazole-Tethered Glycoclusters Exhibiting Three Different Spatial Arrangements and Comparative Study of their Affinities towards PA-IL and RCA 120 by Using a DNA-Based Glycoarray
  60. Single and dual glycoside clustering around calix[4]arene scaffolds via click thiol–ene coupling and azide–alkyne cycloaddition
  61. Microwave-Enhanced Ionothermal CuAAC for the Synthesis of Glycoclusters on a Calix[4]arene Platform
  62. Validation of the Copper(I)-Catalyzed Azide−Alkyne Coupling in Ionic Liquids. Synthesis of a Triazole-Linked C-Disaccharide as a Case Study
  63. Synthesis of sialoclusters appended to calix[4]arene platforms via multiple azide-alkyne cycloaddition. New inhibitors of hemagglutination and cytopathic effect mediated by BK and influenza A viruses
  64. Addressing the scope of the azide–nitrile cycloaddition in glycoconjugate chemistry. The assembly of C-glycoclusters on a calix[4]arene scaffold through tetrazole spacers
  65. Direct epoxidation of d-glucal and d-galactal derivatives with in situ generated DMDO
  66. C -Glycoside Clustering on Calix[4]arene, Adamantane, and Benzene Scaffolds through 1,2,3-Triazole Linkers
  67. First synthesis of 1,2,3-triazolo-linked (1,6)-α-d-oligomannoses (triazolomannoses) by iterative Cu(i)-catalyzed alkyne–azide cycloaddition
  68. Concise and Practical Synthesis of C -Glycosyl Ketones from Sugar Benzothiazoles and Their Transformation into Chiral Tertiary Alcohols
  69. Hybrid Solution/Solid-Phase Synthesis of Oligosaccharides by Using Trichloroacetyl Isocyanate as Sequestration-Enabling Reagent of Sugar Alcohols
  70. Hybrid Solution/Solid-Phase Synthesis of Oligosaccharides by Using Trichloroacetyl Isocyanate as Sequestration-Enabling Reagent of Sugar Alcohols
  71. Synthesis and characterization of calix[4]arene-based copolyethers and polyurethanes. Ionophoric properties and extraction abilities towards metal cations of polymeric calix[4]arene urethanes
  72. Stereoselective Synthesis of α- and β- l - C -Fucosyl Aldehydes and Their Utility in the Assembly of C -Fucosides of Biological Relevance
  73. Thiazole-Mediated Synthetic Methodology
  74. Ring Enlargement of Polyhydroxylated Pyrrolidines to Piperidines by ­Mitsunobu Reaction: A Fortuitous Synthesis of 1-Deoxy- l -allonojirimycin
  75. A new synthetic approach to mycobacterial cell wall α-(1→5)-d-arabinofuranosyl C-oligosaccharides
  76. Novel Carboranyl C-Glycosides for the Treatment of Cancer by Boron Neutron Capture Therapy
  77. A Model Route Toward the Synthesis of Conformationally Constrained Polyhydroxylated Dipeptides from Natural Carbohydrates
  78. Multigram scale synthesis of formyl tetra-O-benzyl-β-d-C-glucopyranoside using benzothiazole as a formyl group equivalent
  79. Glycoside-Clustering Round Calixarenes toward the Development of Multivalent Carbohydrate Ligands. Synthesis and Conformational Analysis of Calix[4]arene O - and C -Glycoconjugates
  80. Linear Total Synthetic Routes to β- d - C -(1,6)-Linked Oligoglucoses and Oligogalactoses up to Pentaoses by Iterative Wittig Olefination Assembly.
  81. Synthesis of α- and β-Glycosyl Asparagine Ethylene Isosteres ( C -Glycosyl Asparagines) via Sugar Acetylenes and Garner Aldehyde Coupling †
  82. Linear Total Synthetic Routes to β- d - C -(1,6)-Linked Oligoglucoses and Oligogalactoses up to Pentaoses by Iterative Wittig Olefination Assembly †
  83. Synthesis of [60]fulleropyrrolidine glycoconjugates using 1,3-dipolar cycloaddition with C-glycosyl azomethine ylides
  84. Computational and experimental studies of di- and tetrasubstituted calix[4]arenes
  85. Synthesis of All Carbon Linked Glycoside Clusters Round Benzene Scaffold via Sonogashira-Heck-Cassar Cross-Coupling of Iodobenzenes with Ethynyl C-Glycosides
  86. Selectivity in the SmI2-induced deoxygenation of thiazolylketoses for formyl C-glycoside synthesis and revised structure of C-ribofuranosides
  87. First synthesis of bridged and double calixsugars
  88. Chemical Synthesis of Linear and Cyclic Unnatural Oligosaccharides by Iterative Glycosidation of Ketoses
  89. A concise C-glycosyl amino acid synthesis by alkenyl C-glycoside–vinyloxazolidine cross-metathesis. Synthesis of glycosyl serine, asparagine and hydroxynorvaline isosteres
  90. Expeditious Synthesis of β-Linked Glycosyl Serine Methylene Isosteres (β-C-Gly Ser) via Ethynylation of Sugar Lactones
  91. Methods for Anomeric Carbon-Linked and Fused Sugar Amino Acid Synthesis:  The Gateway to Artificial Glycopeptides
  92. Convergent synthesis of pyrrolidine-based (1→6)- and (1→5)-aza-C-disaccharides
  93. Improved iterative olefination approach to oligosaccharide mimics: stereoselective synthesis of β-(1→6)-d-galactopentaose methylene isostere
  94. General, stereoselective synthesis of ethylene isosteres of α- and β-glycosylasparagines
  95. Stereoselective synthesis of C-glycosylphosphonates from their ketols. Reconsideration of an abandoned route
  96. Stereoselective Conjugate Addition of Nitrogen and Carbon Nucleophiles to Sugar-Derived Enones: Synthesis of Sialic Acid Analogues
  97. Stereoselective Conjugate Addition of Nitrogen and Carbon Nucleophiles to Sugar-Derived Enones: Synthesis of Sialic Acid Analogues
  98. Design and Use of an Oxazolidine Silyl Enol Ether as a New Homoalanine Carbanion Equivalent for the Synthesis of Carbon-Linked Isosteres of O -Glycosyl Serine and N -Glycosyl Asparagine †
  99. Thiazolylketoses: a new class of versatile intermediates for glycoside synthesis
  100. Thiazole as Leaving Group. Thermal Elimination from Thiazolylketoses
  101. Synthesis and characterization of bisphenol-A copolyethers and copolyesters carrying calix[4]arene units in the main chains and their binding properties towards silver cations
  102. Synthesis of Calix[4]arenylvinylene and Calix[4]arenylphenylene Oligomers by Stille and Suzuki Cross-Coupling Reactions
  103. Synthesis of (1→6)-C-oligogalactosides by iterative Wittig olefination
  104. Synthesis of ethylene isosteres of β-d-galactosyl- and β-d-glucosyl-l-asparagine
  105. Synthesis of ketosyl and ulosonyl phosphonates by Arbuzov-type glycosidation of thiazolylketol acetates
  106. Stereoselective synthesis of the C-linked analogue of β-d-galactopyranosyl-l-serine
  107. Synthesis of methylene isosteres of α- and β-d-galactopyranosyl-l-serine
  108. Synthesis and Properties of O‐Glycosyl Calix[4]Arenes (Calixsugars)
  109. The assembly of carbon-linked calixarene-carbohydrate structures (C-calixsugars) by multiple wittig olefination
  110. Carbohydrate Homologation by the Use of 2-(Trimethylsilyl)thiazole. Preparative Scale Synthesis of Rare Sugars:  l -Gulose, l -Idose, and the Disaccharide Subunit of Bleomycin A 2
  111. Synthesis and receptor properties of calix[4]arene–bisphenol-A copolymers
  112. Thiazolylketol acetates as glycosyl donors. Stereoselective synthesis of α-linked ketodisaccharides
  113. Calixsugars: † Preparation of Upper Rim O -Ketopyranosyl Calix[4]arenes †
  114. Sugar Calixarenes: Preparation of Calix[4]arenes Substituted at the Lower and Upper Rims with O ‐Glycosyl Groups
  115. Zuckercalixarene: Synthese von Calix[4]arenen mitO-Glycosylsubstituenten am oberen oder unteren Rand
  116. A General Synthetic Route to Anomeric .alpha.-Azido and .alpha.-Amino Acids and Formal Synthesis of (+)-Hidantocidin
  117. Synthesis of a sialic acid analog with the acetamido group at C-4
  118. Installation of the Pyruvate Unit in Glycidic Aldehydes via a Wittig Olefination-Michael Addition Sequence Utilizing a Thiazole-Armed Carbonyl Ylide. A New Stereoselective Route to 3-Deoxy-2-Ulosonic Acids and the Total Synthesis of DAH, KDN, and 4-epi...
  119. Furan-based synthesis of C-glycosyl carboxylates
  120. C-glycofuranosides via tandem Wittig-Michael sequence using a thiazole-armed phosphorane. A route to C-furanosyl α-hydroxy propanals and propionic acids
  121. Selective Conjugate Addition of Benzylamine to 2-Thiazolyl α,β-Enone Derived from D-Glyceraldehyde Acetonide. An Exploratory Study Toward the Synthesis of Aminated Ulosonic Acids
  122. Efficacious modification of the procedure for the aldehyde release from 2-substituted thiazoles
  123. Isopropenyl glycosides and congeners as novel classes of glycosyl donors: theme and variations
  124. A novel and convenient method for the removal of a nitrate group at the anomeric position
  125. A novel class of glycosyl donors: Anomeric S-xanthates of 2-azido-2-deoxy-D-galactopyranosyl derivatives
  126. N-p-methoxybenzylidene derivatives of 2-amino-2-deoxy-d-glucose as glycosyl donors: a reinvestigation
  127. A novel stereoselective synthesis of N-acetyl-α-neuraminosyl-galactose di-saccharide derivatives, using anomeric S-glycosyl xanthates
  128. Glycosylation Using a One-Electron-Transfer Homogeneous Reagent: A Novel and Efficient Synthesis of β-Linked Disaccharides
  129. Anomeric S -Xanthates of 2-Azido-2-deoxy- D -galactopyranosyl Derivatives as Efficient Glycosyl Donors 1
  130. Synthesis of disaccharide fragments of dermatan sulfate
  131. Acetylation of N-acetylneuraminic acid and its methyl ester
  132. Preparation of pyranoid glycal derivatives from phenyl thioglycosides and glycosyl phenyl sulphones
  133. Stereoselective synthesis of 2-thioglycosides of N-acetylneuraminic acid
  134. Convenient syntheses of substituted pyranoid glycals from thiophenyl glycosides and glycosyl phenylsulfones
  135. An improved preparation of 3,4-O-isopropylidene derivatives of α- and β-d-galactopyranosides
  136. Synthesis of 2,3:4,6-di-O-isopropylidene derivatives of alkyl α- and β-d-galactopyranosides, and elucidation of structure by n.m.r. and x-ray analysis
  137. Chemical synthesis of the desialylated human Cad-antigenic determinant
  138. New results in the isopropylidenation of galactopyranosides. Useful intermediates for the synthesis of galactose derivatives.