All Stories

  1. Deep eutectic solvents: biorenewable reaction media for Au(i)-catalysed cycloisomerisations and one-pot tandem cycloisomerisation/Diels–Alder reactions

    Article • Green Chemistry, January 2015, Royal Society of Chemistry

    Joaquín García-Álvarez

  2. Chemoenzymatic one-pot synthesis in an aqueous medium: combination of metal-catalysed allylic alcohol isomerisation–asymmetric bioamination

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Joaquín García-Álvarez, Javier González Sabín

  3. ChemInform Abstract: Iminophosphorane—Phosphines: Versatile Ligands for Homogeneous Catalysis

    Article • ChemInform, May 2014, Wiley

    Joaquín García-Álvarez

  4. Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air

    Article • Angewandte Chemie, April 2014, Wiley

    Joaquín García-Álvarez

  5. Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air

    Article • Angewandte Chemie, April 2014, Wiley

    Joaquín García-Álvarez

  6. Iminophosphorane–phosphines: Versatile ligands for homogeneous catalysis

    Article • Journal of Organometallic Chemistry, February 2014, Elsevier

    Joaquín García-Álvarez

  7. Glycerol: a biorenewable solvent for base-free Cu(i)-catalyzed 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes. Highly efficient transformations and catalyst recycling

    Article • Green Chemistry, January 2014, Royal Society of Chemistry

    Joaquín García-Álvarez

  8. Deep eutectic solvents (DES) as green reaction media for the redox isomerization of allylic alcohols into carbonyl compounds catalyzed by the ruthenium complex [Ru(η3:η3-C10H16)Cl2(benzimidazole)]

    Article • Catalysis Communications, January 2014, Elsevier

    Joaquín García-Álvarez

  9. Introducing deep eutectic solvents as biorenewable media for Au(i)-catalysed cycloisomerisation of γ-alkynoic acids: an unprecedented catalytic system

    Article • Chemical Communications, January 2014, Royal Society of Chemistry

    Joaquín García-Álvarez

  10. ChemInform Abstract: Catalytic Rearrangements and Allylation Reactions in Water

    Article • ChemInform, December 2013, Wiley

    Joaquín García-Álvarez

  11. “Click” Copper Catalyzed Azide–Alkyne Cycloaddition (CUAAC) in Aqueous Medium

    Article • October 2013, Wiley

    Joaquín García-Álvarez

  12. Donor-Activated Lithiation and Sodiation of Trifluoromethylbenzene: Structural, Spectroscopic, and Theoretical Insights

    Article • Organometallics, September 2013, American Chemical Society (ACS)

    Joaquín García-Álvarez, William Clegg

  13. Nanocatalysts for Rearrangement Reactions

    Article • August 2013, Wiley

    Joaquín García-Álvarez

  14. ChemInform Abstract: Metal‐Catalyzed Isomerization of Allylic and Propargylic Alcohols in Aqueous Media

    Article • ChemInform, August 2013, Wiley

    Joaquín García-Álvarez

  15. New Ag(I)–Iminophosphorane Coordination Polymers as Efficient Catalysts Precursors for the MW-Assisted Meyer–Schuster Rearrangement of Propargylic Alcohols in Water

    Article • Inorganic Chemistry, May 2013, American Chemical Society (ACS)

    Joaquín García-Álvarez

  16. ChemInform Abstract: (Iminophosphorane)copper(I) Complexes as Highly Efficient Catalysts for 1,3‐Dipolar Cycloaddition of Azides with Terminal and 1‐Iodoalkynes in Water: One‐Pot Multi‐Component Reaction from Alkynes and in situ Generated Azides.

    Article • ChemInform, April 2013, Wiley

    Joaquín García-Álvarez

  17. Synthesis and Reactivity of New Rhenium(I) Complexes Containing Iminophosphorane-Phosphine Ligands: Application to the Catalytic Isomerization of Propargylic Alcohols in Ionic Liquids

    Article • Inorganic Chemistry, April 2013, American Chemical Society (ACS)

    Joaquín García-Álvarez

  18. ChemInform Abstract: Pd(II)‐Catalyzed Cycloisomerization of γ‐Alkynoic Acids and One‐Pot Tandem Cycloisomerization/CuAAC Reactions in Water.

    Article • ChemInform, March 2013, Wiley

    Joaquín García-Álvarez

  19. Catalytic Rearrangements and Allylation Reactions in Water

    Article • January 2013, Wiley

    Joaquín García-Álvarez

  20. Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(i) complex with a NHC anion

    Article • Chemical Science, January 2013, Royal Society of Chemistry

    Joaquín García-Álvarez

  21. (Iminophosphorane)copper(I) Complexes as Highly Efficient Catalysts for 1,3‐Dipolar Cycloaddition of Azides with Terminal and 1‐Iodoalkynes in Water: One‐Pot Multi‐Component Reaction from Alkynes and in situ Generated Azides

    Article • European Journal of Inorganic Chemistry, October 2012, Wiley

    Joaquín García-Álvarez

  22. ChemInform Abstract: Microwave‐Assisted Meyer—Schuster Rearrangement of Propargylic Alcohols Catalyzed by the Oxovanadate Complex [V(O)Cl(OEt)2].

    Article • ChemInform, April 2012, Wiley

    Joaquín García-Álvarez

  23. Pd(ii)-catalyzed cycloisomerisation of γ-alkynoic acids and one-pot tandem cycloisomerisation/CuAAC reactions in water

    Article • Green Chemistry, January 2012, Royal Society of Chemistry

    Joaquín García-Álvarez

  24. Microwave‐Assisted Meyer–Schuster Rearrangement of Propargylic Alcohols Catalyzed by the Oxovanadate Complex [V(O)Cl(OEt)2]

    Article • ChemCatChem, October 2011, Wiley

    Joaquín García-Álvarez

  25. ChemInform Abstract: Ruthenium Complexes Containing Iminophosphorane Ligands: Synthesis, Structure, Reactivity and Applications

    Article • ChemInform, September 2011, Wiley

    Joaquín García-Álvarez

  26. ChemInform Abstract: Novel Rhenium(I) Catalysts for the Isomerization of Propargylic Alcohols into α,β‐Unsaturated Carbonyl Compounds: An Unprecedented Recyclable Catalytic System in Ionic Liquids.

    Article • ChemInform, August 2011, Wiley

    Joaquín García-Álvarez

  27. ChemInform Abstract: A Highly Efficient Copper(I) Catalyst for the 1,3‐Dipolar Cycloaddition of Azides with Terminal and 1‐Iodoalkynes in Water: Regioselective Synthesis of 1,4‐Disubstituted and 1,4,5‐Trisubstituted 1,2,3‐Triazoles.

    Article • ChemInform, March 2011, Wiley

    Joaquín García-Álvarez

  28. Novel rhenium(i) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Joaquín García-Álvarez

  29. Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

    Article • Journal of the American Chemical Society, June 2010, American Chemical Society (ACS)

    Joaquín García-Álvarez, William Clegg

  30. Structurally Stimulated Deprotonation/Alumination of the TMP Anion

    Article • Angewandte Chemie, April 2010, Wiley

    Joaquín García-Álvarez

  31. Structurally Stimulated Deprotonation/Alumination of the TMP Anion

    Article • Angewandte Chemie, April 2010, Wiley

    Joaquín García-Álvarez

  32. Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph2P(Se)CH2P(NR)Ph2: coordination of their methanide and methandiide anions to ruthenium

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Joaquín García-Álvarez

  33. A highly efficient copper(i) catalyst for the 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes in water: regioselective synthesis of 1,4-disubstituted and 1,4,5-trisubstituted 1,2,3-triazoles

    Article • Green Chemistry, January 2010, Royal Society of Chemistry

    Joaquín García-Álvarez

  34. Synthetic and Structural Insights into the Zincation of Toluene: Direct Synergic Ring Metallation versus Indirect Nonsynergic Lateral Metallation

    Article • Chemistry - A European Journal, March 2009, Wiley

    Joaquín García-Álvarez

  35. (η6-Arene)−Ruthenium(II) Complexes Containing Methanide and Methandiide Anions of Ph2P(═S)CH2P(═NR)Ph2: Unprecedented Insertion of Isocyanide into a Ruthenium−Carbene Bond

    Article • Organometallics, March 2008, American Chemical Society (ACS)

    Joaquín García-Álvarez

  36. Novel ruthenium(ii) complexes containing the N-phosphorylated iminophosphorane-phosphine ligand Ph2PCH2P{NP(O)(OEt)2}Ph2: a new coordination mode of its methanide anion

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Joaquín García-Álvarez

  37. Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Joaquín García-Álvarez, Dr Charles O'Hara, William Clegg

  38. Synthesis and characterisation of new bimetallic alkali metal–magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Joaquín García-Álvarez

  39. Alkali‐Metal‐Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

    Article • Angewandte Chemie, January 2007, Wiley

    Joaquín García-Álvarez

  40. Alkali‐Metal‐Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

    Article • Angewandte Chemie, January 2007, Wiley

    Joaquín García-Álvarez

  41. Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry

    Article • Chemical Communications, January 2007, Royal Society of Chemistry

    Joaquín García-Álvarez

  42. Reaction of isocyanides with iminophosphorane-based carbene ligands: Synthesis of unprecedented ketenimine–ruthenium complexes

    Article • Journal of Organometallic Chemistry, December 2005, Elsevier

    Joaquín García-Álvarez

  43. Iminophosphorane-Based Nucleophilic Ruthenium(II) Carbene Complexes:  Unusual C−C Coupling and C−H Activation Promoted by the Addition of Alkynes to the RuC Bond

    Article • Organometallics, April 2005, American Chemical Society (ACS)

    Joaquín García-Álvarez

  44. Base-Assisted Cyclometalation and Phosphorus−Carbon Bond Cleavage in (Arene)ruthenium(II) Complexes Containing Functionalized Iminophosphorane-Phosphine Ligands Ph2PCH2P{NP(X)(OR)2}Ph2 (X = O, S; R = Et, Ph)

    Article • Organometallics, June 2004, American Chemical Society (ACS)

    Joaquín García-Álvarez

  45. Bis(iminophosphorano)methane Derivatives as Precursors of Unusual Ruthenium Carbene Complexes:  A Synthetic and DFT Study

    Article • Organometallics, April 2004, American Chemical Society (ACS)

    Joaquín García-Álvarez

  46. Ruthenium(II) and Ruthenium(IV) Complexes Containing κ1-P-, κ2-P,O-, and κ3-P,N,O-Iminophosphorane-Phosphine Ligands Ph2PCH2P{NP(O)(OR)2}Ph2...

    Article • Inorganic Chemistry, April 2003, American Chemical Society (ACS)

    Joaquín García-Álvarez, Santiago Garcia-Granda