All Stories

  1. Dinuclear Rhodium(I)– N ‐Heterocyclic Carbene Complexes as Alkyne Hydropyridonation Catalysts
  2. Mechanistic Insights on the β-(Z) alkyne hydrosilylation by a NHC-based Cp*Rh(III) catalyst: from catalyst design to an alternative model for H-Si activation
  3. Rhodium(i) complexes with proton-responsive anionic tethered N-heterocyclic carbene ligands: synthesis and application in alkyne dimerization
  4. Tuning the Pyridone Scaffold within a Rhodium-NHC Platform for gem-Specific Alkyne Dimerization via a Ligand-Assisted Proton Shuttle Mechanism
  5. Stereoregular polymerization of phenylacetylene using alkynyl and methyl rhodium(i) complexes with functionalized phosphine ligands: linear vs. branched poly(phenylacetylene)s
  6. Synthesis of megadalton stereoregular ring-substituted poly(phenylacetylene)s by a rhodium(i) catalyst with a N-functionalized hemilabile phosphine ligand
  7. Rhodium and Iridium Complexes of Lutidine-Based NHC/Amino Pincer Ligands: From Monodentate to Tetradentate Coordination Enabled by C–H Activation
  8. Tailor-made poly(vinylidene sulfide)s by Rh(I)–NHC catalyzed regioselective thiol-yne click polymerization
  9. Reactivity of Ir(i)-aminophosphane platforms towards oxidants
  10. β-(Z)-Selective alkyne hydrosilylation by a N,O-functionalized NHC-based rhodium(i) catalyst
  11. Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts
  12. Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes
  13. Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights
  14. N-Methylation of Amines with Methanol Catalyzed by Iridium(I) Complexes Bearing an N,O-Functionalized NHC Ligand
  15. Photocatalytic Activity in the In-Flow Degradation of NO on Porous TiO2–Coated Glasses from Hybrid Inorganic–Organic Thin Films Prepared by a Combined ALD/MLD Deposition Strategy
  16. Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes
  17. Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes
  18. Catalytic applications of zwitterionic transition metal compounds
  19. Cyclometalated iridium complexes based on monodentate aminophosphanes
  20. Polymerization of phenylacetylene catalyzed by rhodium(i) complexes with N-functionalized N-heterocyclic carbene ligands
  21. Synthesis and reactivity of an iridium complex based on a tridentate aminophosphano ligand
  22. Variation on the π‐Acceptor Ligand within a RhI−N‐Heterocyclic Carbene Framework: Divergent Catalytic Outcomes for Phenylacetylene‐Methanol Transformations
  23. Preparation of Butadienylpyridines by Iridium‐NHC‐Catalyzed Alkyne Hydroalkenylation and Quinolizine Rearrangement
  24. Metal–Ligand Cooperative Proton Transfer as an Efficient Trigger for Rhodium-NHC-Pyridonato Catalyzed gem-Specific Alkyne Dimerization
  25. Iridium(i) complexes bearing hemilabile coumarin-functionalised N-heterocyclic carbene ligands with application as alkyne hydrosilylation catalysts
  26. β-(Z) Selectivity Control by Cyclometalated Rhodium(III)–Triazolylidene Homogeneous and Heterogeneous Terminal Alkyne Hydrosilylation Catalysts
  27. Rhodium(I)‐NHC Complexes Bearing Bidentate Bis‐Heteroatomic Acidato Ligands as gem ‐Selective Catalysts for Alkyne Dimerization
  28. Carboxylate-Assisted β-(Z) Stereoselective Hydrosilylation of Terminal Alkynes Catalyzed by a Zwitterionic Bis-NHC Rhodium(III) Complex
  29. Hybrid Catalysts Comprised of Graphene Modified with Rhodium-Based N-Heterocyclic Carbenes for Alkyne Hydrosilylation
  30. Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines
  31. Mechanistic Insights on the Functionalization of CO 2 with Amines and Hydrosilanes Catalyzed by a Zwitterionic Iridium Carboxylate‐Functionalized Bis‐NHC Catalyst
  32. Hydride–Rhodium(III)-N-Heterocyclic Carbene Catalyst for Tandem Alkylation/Alkenylation via C–H Activation
  33. Enhanced Chemical and Electrochemical Water Oxidation Catalytic Activity by Hybrid Carbon Nanotube-Based Iridium Catalysts Having Sulfonate-Functionalized NHC ligands
  34. Dinuclear Phosphine-Amido [Rh2(diene){μ-NH(CH2)3PPh2}2] Complexes as Efficient Catalyst Precursors for Phenylacetylene Polymerization
  35. Molecular water oxidation catalysis by zwitterionic carboxylate bridge-functionalized bis-NHC iridium complexes
  36. Synthesis and reactivity at the Ir-MeTpm platform: from κ1-N coordination to κ3-N-based organometallic chemistry
  37. Impact of Protic Ligands in the Ir-Catalyzed Dehydrogenation of Formic Acid in Water
  38. Mechanistic Investigation on the Polymerization of Phenylacetylene by 2-Diphenylphosphinopyridine Rhodium(I) Catalysts: Understanding the Role of the Cocatalyst and Alkynyl Intermediates
  39. Rhodium–N-Heterocyclic Carbene Catalyzed Hydroalkenylation Reactions with 2-Vinylpyridine and 2-Vinylpyrazine: Preparation of Nitrogen-Bridgehead Heterocycles
  40. Zwitterionic Rhodium and Iridium Complexes Based on a Carboxylate Bridge-Functionalized Bis-N-heterocyclic Carbene Ligand: Synthesis, Structure, Dynamic Behavior, and Reactivity
  41. Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands
  42. A highly efficient Ir-catalyst for the solventless dehydrogenation of formic acid: the key role of an N-heterocyclic olefin
  43. Mechanistic insights into the tropo-inversion of the biphenyl moiety in chiral bis-amido phosphites and in their palladium(ii) complexes
  44. Mechanistic studies on the N-alkylation of amines with alcohols catalysed by iridium(i) complexes with functionalised N-heterocyclic carbene ligands
  45. Vinylidene-based polymers by Rh(i)-NHC catalyzed thiol–yne click polymerization: synthesis, characterization and post-polymerization modification
  46. Experimental and Theoretical Mechanistic Investigation on the Catalytic CO2 Hydrogenation to Formate by a Carboxylate-Functionalized Bis(N-heterocyclic carbene) Zwitterionic Iridium(I) Compound
  47. Design of Highly Selective Alkyne Hydrothiolation RhI-NHC Catalysts: Carbonyl-Triggered Nonoxidative Mechanism
  48. A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights
  49. Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant
  50. Rhodium-Catalyzed Dehydrogenative Silylation of Acetophenone Derivatives: Formation of Silyl Enol Ethers versus Silyl Ethers
  51. Hydrosilylation of Terminal Alkynes Catalyzed by a ONO-Pincer Iridium(III) Hydride Compound: Mechanistic Insights into the Hydrosilylation and Dehydrogenative Silylation Catalysis
  52. Reactivity of [TiM2] (M = Rh, Ir) and [TiIr3] early-late heterobimetallic sulfido-bridged clusters
  53. Local structure of Iridium organometallic catalysts covalently bonded to carbon nanotubes.
  54. Pyridinethiolate Titanocene Metalloligands and Their Self-Assembly Reactions To Yield Early–Late Metallamacrocycles
  55. En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond
  56. Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand
  57. Effect of structural differences of carbon nanotubes and graphene based iridium-NHC materials on the hydrogen transfer catalytic activity
  58. Enhancing the hydrogen transfer catalytic activity of hybrid carbon nanotube-based NHC–iridium catalysts by increasing the oxidation degree of the nanosupport
  59. Mechanistic insight into the pyridine enhanced α-selectivity in alkyne hydrothiolation catalysed by quinolinolate–rhodium(i)–N-heterocyclic carbene complexes
  60. Oxidation and β-Alkylation of Alcohols Catalysed by Iridium(I) Complexes with Functionalised N-Heterocyclic Carbene Ligands
  61. Efficient Rhodium-Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines
  62. Synthesis of Titanium and Zirconium Complexes with 2-­Pyridonate and 2, 6-Pyridinedithiolate Ligands
  63. Grafting of Copper(I)-NHC Species on MCM-41: Homogeneous versus Heterogeneous Catalysis
  64. In Honour of the 70th Birthday of Professor Luis A. Oro
  65. Graphene–NHC–iridium hybrid catalysts built through –OH covalent linkage
  66. Mechanistic Insights into Transfer Hydrogenation Catalysis by [Ir(cod)(NHC)2]+ Complexes with Functionalized N-Heterocyclic Carbene Ligands
  67. Preferential α-Hydrosilylation of Terminal Alkynes by Bis-N-Heterocyclic Carbene Rhodium(III) Catalysts
  68. Orthometallation of N-substituents at the NHC ligand of [Rh(Cl)(COD)(NHC)] complexes: its role in the catalytic hydrosilylation of ketones
  69. Pyridine versus acetonitrile coordination in rhodium–N-heterocyclic carbene square-planar complexes
  70. A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))
  71. Tuning PCP–Ir complexes: the impact of an N-heterocyclic olefin
  72. Intramolecular C–H oxidative addition to iridium(i) triggered by trimethyl phosphite in N,N′-diphosphanesilanediamine complexes
  73. Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups
  74. Catalytic Hydrodechlorination of Benzyl Chloride Promoted by Rh-N-heterocyclic Carbene Catalysts
  75. Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling ofN-Vinylpyrazoles with Alkynes via C–H Activation
  76. Selective CH Bond Functionalization of 2-(2-Thienyl)pyridine by a Rhodium N-Heterocyclic Carbene Catalyst
  77. gem-Selective Cross-Dimerization and Cross-Trimerization of Alkynes with Silylacetylenes Promoted by a Rhodium-Pyridine-N-Heterocyclic Carbene Catalyst
  78. Hydride-Rhodium(III)-N-Heterocyclic Carbene Catalysts for Vinyl-Selective H/D Exchange: A Structure-Activity Study
  79. Iridium-Catalyzed Hydrogen Production from Hydrosilanes and Water
  80. Dinuclear Pyridine-4-thiolate-Bridged Rhodium and Iridium Complexes as Ditopic Building Blocks in Molecular Architecture
  81. Intramolecular C–H Oxidative Addition to Iridium(I) in Complexes Containing a N,N′-Diphosphanosilanediamine Ligand
  82. Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation
  83. Synthesis and dynamic behaviour of zwitterionic [M(η6-C6H5-BPh3)(coe)2] (M = Rh, Ir) cyclooctene complexes
  84. An Alternative Mechanistic Paradigm for the β‐ Z Hydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle
  85. Hydroxo–Rhodium–N-Heterocyclic Carbene Complexes as Efficient Catalyst Precursors for Alkyne Hydrothiolation
  86. ONO Dianionic Pincer-Type Ligand Precursors for the Synthesis of σ,π-Cyclooctenyl Iridium(III) Complexes: Formation Mechanism and Coordination Chemistry
  87. Unsaturated Iridium(III) Complexes Supported by a Quinolato–Carboxylato ONO Pincer-Type Ligand: Synthesis, Reactivity, and Catalytic C–H Functionalization
  88. Pyridine-Enhanced Head-to-Tail Dimerization of Terminal Alkynes by a Rhodium-N-Heterocyclic-Carbene Catalyst
  89. Enhanced Hydrogen-Transfer Catalytic Activity of Iridium N-Heterocyclic Carbenes by Covalent Attachment on Carbon Nanotubes
  90. Labile Rhodium(I)–N-Heterocyclic Carbene Complexes
  91. A New Access to 4 H-Quinolizines from 2-Vinylpyridine and Alkynes Promoted by Rhodium-N-Heterocyclic-Carbene Catalysts
  92. Bis(hydrosulfido)-bridged dinuclear rhodium(i) complexes as a platform for the synthesis of trinuclear sulfido aggregates with the core [MRh2(μ3-S2)] (M = Rh, Ir, Pd, Pt, Ru)
  93. The Emergence of Transition-Metal-Mediated Hydrothiolation of Unsaturated Carbon-Carbon Bonds: A Mechanistic Outlook
  94. Mechanistic Studies on the Catalytic Oxidative Amination of Alkenes by Rhodium(I) Complexes with Hemilabile Phosphines
  95. Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation
  96. Synthesis of Poly(silyl ether)s by Rhodium(I)-NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis
  97. Steric Effects in the Oxidative Addition of MeI to a Sulfido-Bridged ZrRh2 Early–Late Heterobimetallic Compound
  98. Synthesis, structure, and kinetic studies on [RuCl2(NCCH3)2(cod)]
  99. Rhodium(I) Complexes with Hemilabile Phosphines: Rational Design for Efficient Oxidative Amination Catalysts
  100. Ligand-Controlled Regioselectivity in the Hydrothiolation of Alkynes by Rhodium N-Heterocyclic Carbene Catalysts
  101. A synthon for a 14-electron Ir(iii) species: catalyst for highly selective β-(Z) hydrosilylation of terminal alkynes
  102. Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts
  103. Synthesis of a Square-Planar Rhodium Alkylidene N-Heterocyclic Carbene Complex and Its Reactivity Toward Alkenes
  104. Hydride Mobility in Trinuclear Sulfido Clusters with the Core [Rh3(μ-H)(μ3-S)2]: Molecular Models for Hydrogen Migration on Metal Sulfide Hydrotreating Catalysts
  105. Mild and Selective H/D Exchange at the β Position of Aromatic α-Olefins by N-Heterocyclic Carbene-Hydride-Rhodium Catalysts
  106. Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes
  107. Branched Poly(phenylacetylene)
  108. Hydroformylation of Synthetic Naphtha Catalyzed by a Dinuclear gem-Dithiolato-Bridged Rhodium(I) Complex~!2009-09-28~!2009-12-18~!2010-04-23~!
  109. Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene
  110. Cationic Rhodium Complexes with Hemilabile Phosphine Ligands as Polymerization Catalyst for High Molecular Weight Stereoregular Poly(phenylacetylene)
  111. On the Synthesis and Chemical Behaviour of the Elusive Bis(hydrosulfido)-Bridged Dinuclear Rhodium(I) Complexes [{Rh(μ-SH)(CO)(PR3)}2]
  112. Synthesis of Tetranuclear Rhodium and Iridium Complexes Directed by 6-Mercaptopyridin-2-ol: Electrochemical Behavior, Chemical Oxidation, and Coordination Chemistry
  113. Convenient Methods for the Synthesis of a Library of Hemilabile Phosphines
  114. Hydroformylation of Hex-1-ene by a Dinuclear gem-Dithiolato-bridged Rhodium Catalyst Under CO/H2O Conditions
  115. Hydroformylation of oct-1-ene catalyzed by dinuclear gem-dithiolato-bridged rhodium(I) complexes and phosphorus donor ligands
  116. Synthesis, Structural Characterization, and Ligand Replacement Reactions ofgem-Dithiolato-Bridged Rhodium and Iridium Complexes
  117. Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts
  118. Novelgem-Dithiolato-Bridged Rhodium Hydroformylation Catalysts: Bridging the Gap in Dinuclear Rhodium Thiolate Chemistry
  119. The Anions [Cptt2Zr(μ-S)2M(CO)2]-(M = Rh, Ir) as Versatile Precursors for the Synthesis of Sulfido-Bridged Early−Late Heterotrimetallic (ELHT) Compounds†
  120. Reversible Opening of the Triangular Structure of a Sulfido-Bridged ZrRh2Early−Late Heterobimetallic Complex Induced by Bis-(diphenylphosphino)methane
  121. Effects of the Heterocycle and Its Substituents on Structure and Fluxionality in Rhodium(I) and Iridium(I) Complexes with the Hindered Thiolates 6-tert-Butylpyridine-2-thiolate and 1-Alkyl-4-tert-butylimidazole-2-thiolate (alkyl = methyl andtert-butyl)
  122. Flexible Building Blocks for Transition Metal Early−Late Chemistry. Synthesis of Heterobimetallic Tetranuclear Metallomacrocycles
  123. Tetranuclear [Rh4(μ-PyS2)2(diolefin)4] Complexes as Building Blocks for New Inorganic Architectures:  Synthesis of Coordination Polymers and Heteropolynuclear Complexes with Electrophilic d8and d10Metal Fragments
  124. Stereoselective Oxidative Additions of Iodoalkanes and Activated Alkynes to a Sulfido-Bridged Heterotrinuclear Early−Late (TiIr2) Complex
  125. Synthesis, Reactivity, and Catalytic Activity of Triangular ZrM2(M = Rh, Ir) Early−Late Heterobimetallic Complexes
  126. Early (Ti, Zr)-late (Rh, Ir) heteronuclear complexes with bridging sulphido ligands
  127. Unexpected formation and structural characterisation of a novel rhodium B12analogue
  128. Synthesis of Paramagnetic Tetranuclear Rhodium and Iridium Complexes with the 2,6-Pyridinedithiolate Ligand. Redox-Induced Degradation to Diamagnetic Triiridium Compounds
  129. Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2= 2,6-dimercaptopyr...
  130. Controlling the molecular architecture of low nuclearity rhodium and iridium complexes using bridging NCX (X=N, O, S) ligands
  131. Controlled Synthesis of Early-Late Zr-Ir-Rh Heterotrimetallic Compounds by Metal Exchange Reactions
  132. Bimetallic reactivity: unusual change in the coordination mode of the bridging ligands arising from an oxidative addition process
  133. The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond
  134. Chemical evidence of polynuclear intermediates in a ligand redistribution equilibrium between dinuclear rhodium complexes. X-ray structure of [Rh2(μ-bzta)2(CO)3(PPh3)] (bzta = benzothiazole-2-thiolate)
  135. Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium
  136. Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium
  137. Trinuclear aggregates of rhodium and iridium supported by thiolate bridges: synthesis and crystal structure
  138. Atropisomerism in asymmetric cis-diphosphine arylplatinum complexes
  139. Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)]...
  140. Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3
  141. Rhodium complexes of the binucleating ligands pyridine-2-thiolate and benzothiazole-2-thiolate. Crystal structures of [{Rh(µ-SC5H4N)(CO)2}2] and [{Rh(µ-SC5H4N)(tfbb)}2]·Me
  142. Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H