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  1. Rhodium(i) complexes with proton-responsive anionic tethered N-heterocyclic carbene ligands: synthesis and application in alkyne dimerization

    Article • Dalton Transactions, January 2025, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  2. Tuning the Pyridone Scaffold within a Rhodium-NHC Platform for gem-Specific Alkyne Dimerization via a Ligand-Assisted Proton Shuttle Mechanism

    Article • Organometallics, November 2024, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  3. Stereoregular polymerization of phenylacetylene using alkynyl and methyl rhodium(i) complexes with functionalized phosphine ligands: linear vs. branched poly(phenylacetylene)s

    Article • Polymer Chemistry, January 2024, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  4. Synthesis of megadalton stereoregular ring-substituted poly(phenylacetylene)s by a rhodium(i) catalyst with a N-functionalized hemilabile phosphine ligand

    Article • Polymer Chemistry, January 2024, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  5. Rhodium and Iridium Complexes of Lutidine-Based NHC/Amino Pincer Ligands: From Monodentate to Tetradentate Coordination Enabled by C–H Activation

    Article • Organometallics, November 2023, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  6. Tailor-made poly(vinylidene sulfide)s by Rh(I)–NHC catalyzed regioselective thiol-yne click polymerization

    Article • European Polymer Journal, July 2023, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  7. Reactivity of Ir(i)-aminophosphane platforms towards oxidants

    Article • Dalton Transactions, January 2023, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  8. β-(Z)-Selective alkyne hydrosilylation by a N,O-functionalized NHC-based rhodium(i) catalyst

    Article • Dalton Transactions, January 2023, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  9. Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts

    Article • Molecules, November 2022, MDPI AG

    Prof. Dr. Jesús J. Pérez-Torrente

  10. Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes

    Article • Molecules, October 2022, MDPI AG

    Prof. Dr. Jesús J. Pérez-Torrente

  11. Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights

    Article • Organometallics, July 2022, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  12. N-Methylation of Amines with Methanol Catalyzed by Iridium(I) Complexes Bearing an N,O-Functionalized NHC Ligand

    Article • Organometallics, May 2022, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  13. Photocatalytic Activity in the In-Flow Degradation of NO on Porous TiO2–Coated Glasses from Hybrid Inorganic–Organic Thin Films Prepared by a Combined ALD/MLD Deposition Strategy

    Article • Coatings, April 2022, MDPI AG

    Prof. Dr. Jesús J. Pérez-Torrente

  14. Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes

    Article • Angewandte Chemie, March 2022, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  15. Rhodium‐NHC‐Catalyzed gem‐Specific O‐Selective Hydropyridonation of Terminal Alkynes

    Article • Angewandte Chemie, March 2022, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  16. Catalytic applications of zwitterionic transition metal compounds

    Article • Dalton Transactions, January 2022, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  17. Cyclometalated iridium complexes based on monodentate aminophosphanes

    Article • Dalton Transactions, January 2022, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  18. Polymerization of phenylacetylene catalyzed by rhodium(i) complexes with N-functionalized N-heterocyclic carbene ligands

    Article • Polymer Chemistry, January 2022, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  19. Synthesis and reactivity of an iridium complex based on a tridentate aminophosphano ligand

    Article • Dalton Transactions, January 2022, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  20. Variation on the π‐Acceptor Ligand within a RhI−N‐Heterocyclic Carbene Framework: Divergent Catalytic Outcomes for Phenylacetylene‐Methanol Transformations

    Article • European Journal of Inorganic Chemistry, July 2021, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  21. Preparation of Butadienylpyridines by Iridium‐NHC‐Catalyzed Alkyne Hydroalkenylation and Quinolizine Rearrangement

    Article • Chemistry - A European Journal, June 2021, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  22. Metal–Ligand Cooperative Proton Transfer as an Efficient Trigger for Rhodium-NHC-Pyridonato Catalyzed gem-Specific Alkyne Dimerization

    Article • ACS Catalysis, June 2021, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  23. Iridium(i) complexes bearing hemilabile coumarin-functionalised N-heterocyclic carbene ligands with application as alkyne hydrosilylation catalysts

    Article • Dalton Transactions, January 2021, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  24. β-(Z) Selectivity Control by Cyclometalated Rhodium(III)–Triazolylidene Homogeneous and Heterogeneous Terminal Alkyne Hydrosilylation Catalysts

    Article • ACS Catalysis, November 2020, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  25. Rhodium(I)‐NHC Complexes Bearing Bidentate Bis‐Heteroatomic Acidato Ligands as gem ‐Selective Catalysts for Alkyne Dimerization

    Article • Chemistry - A European Journal, July 2020, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  26. Carboxylate-Assisted β-(Z) Stereoselective Hydrosilylation of Terminal Alkynes Catalyzed by a Zwitterionic Bis-NHC Rhodium(III) Complex

    Article • ACS Catalysis, June 2020, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  27. Hybrid Catalysts Comprised of Graphene Modified with Rhodium-Based N-Heterocyclic Carbenes for Alkyne Hydrosilylation

    Article • ACS Applied Nano Materials, January 2020, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  28. Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines

    Article • Catalysis Science & Technology, January 2020, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  29. Mechanistic Insights on the Functionalization of CO 2 with Amines and Hydrosilanes Catalyzed by a Zwitterionic Iridium Carboxylate‐Functionalized Bis‐NHC Catalyst

    Article • ChemCatChem, October 2019, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  30. Hydride–Rhodium(III)-N-Heterocyclic Carbene Catalyst for Tandem Alkylation/Alkenylation via C–H Activation

    Article • ACS Catalysis, September 2019, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  31. Enhanced Chemical and Electrochemical Water Oxidation Catalytic Activity by Hybrid Carbon Nanotube-Based Iridium Catalysts Having Sulfonate-Functionalized NHC ligands

    Article • ACS Applied Energy Materials, April 2019, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  32. Dinuclear Phosphine-Amido [Rh2(diene){μ-NH(CH2)3PPh2}2] Complexes as Efficient Catalyst Precursors for Phenylacetylene Polymerization

    Article • Organometallics, April 2019, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  33. Molecular water oxidation catalysis by zwitterionic carboxylate bridge-functionalized bis-NHC iridium complexes

    Article • Catalysis Science & Technology, January 2019, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  34. Synthesis and reactivity at the Ir-MeTpm platform: from κ1-N coordination to κ3-N-based organometallic chemistry

    Article • Dalton Transactions, January 2019, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  35. Impact of Protic Ligands in the Ir-Catalyzed Dehydrogenation of Formic Acid in Water

    Article • Organometallics, August 2018, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  36. Mechanistic Investigation on the Polymerization of Phenylacetylene by 2-Diphenylphosphinopyridine Rhodium(I) Catalysts: Understanding the Role of the Cocatalyst and Alkynyl Intermediates

    Article • Organometallics, August 2018, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  37. Rhodium–N-Heterocyclic Carbene Catalyzed Hydroalkenylation Reactions with 2-Vinylpyridine and 2-Vinylpyrazine: Preparation of Nitrogen-Bridgehead Heterocycles

    Article • Organometallics, May 2018, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  38. Zwitterionic Rhodium and Iridium Complexes Based on a Carboxylate Bridge-Functionalized Bis-N-heterocyclic Carbene Ligand: Synthesis, Structure, Dynamic Behavior, and Reactivity

    Article • Inorganic Chemistry, April 2018, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  39. Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands

    Article • Organometallics, January 2018, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  40. A highly efficient Ir-catalyst for the solventless dehydrogenation of formic acid: the key role of an N-heterocyclic olefin

    Article • Green Chemistry, January 2018, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  41. Mechanistic insights into the tropo-inversion of the biphenyl moiety in chiral bis-amido phosphites and in their palladium(ii) complexes

    Article • Dalton Transactions, January 2018, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  42. Mechanistic studies on the N-alkylation of amines with alcohols catalysed by iridium(i) complexes with functionalised N-heterocyclic carbene ligands

    Article • Catalysis Science & Technology, January 2018, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  43. Vinylidene-based polymers by Rh(i)-NHC catalyzed thiol–yne click polymerization: synthesis, characterization and post-polymerization modification

    Article • Polymer Chemistry, January 2018, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  44. Experimental and Theoretical Mechanistic Investigation on the Catalytic CO2 Hydrogenation to Formate by a Carboxylate-Functionalized Bis(N-heterocyclic carbene) Zwitterionic Iridium(I) Compound

    Article • Organometallics, August 2017, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  45. Design of Highly Selective Alkyne Hydrothiolation RhI-NHC Catalysts: Carbonyl-Triggered Nonoxidative Mechanism

    Article • Organometallics, May 2017, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  46. A well-defined NHC–Ir(iii) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights

    Article • Chemical Science, January 2017, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  47. Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

    Article • Chemical Communications, January 2017, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  48. Rhodium-Catalyzed Dehydrogenative Silylation of Acetophenone Derivatives: Formation of Silyl Enol Ethers versus Silyl Ethers

    Article • Chemistry - A European Journal, August 2016, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  49. Hydrosilylation of Terminal Alkynes Catalyzed by a ONO-Pincer Iridium(III) Hydride Compound: Mechanistic Insights into the Hydrosilylation and Dehydrogenative Silylation Catalysis

    Article • Organometallics, July 2016, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  50. Reactivity of [TiM2] (M = Rh, Ir) and [TiIr3] early-late heterobimetallic sulfido-bridged clusters

    Article • Journal of Organometallic Chemistry, June 2016, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  51. Local structure of Iridium organometallic catalysts covalently bonded to carbon nanotubes.

    Article • Journal of Physics Conference Series, May 2016, Institute of Physics Publishing

    Prof. Dr. Jesús J. Pérez-Torrente

  52. Pyridinethiolate Titanocene Metalloligands and Their Self-Assembly Reactions To Yield Early–Late Metallamacrocycles

    Article • Organometallics, February 2016, American Chemical Society (ACS)

    Professor Eliseo Ruiz Sabín, Prof. Dr. Jesús J. Pérez-Torrente

  53. En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond

    Article • Dalton Transactions, January 2016, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  54. Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand

    Article • Chemical Communications, January 2016, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  55. Effect of structural differences of carbon nanotubes and graphene based iridium-NHC materials on the hydrogen transfer catalytic activity

    Article • Carbon, January 2016, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  56. Enhancing the hydrogen transfer catalytic activity of hybrid carbon nanotube-based NHC–iridium catalysts by increasing the oxidation degree of the nanosupport

    Article • Catalysis Science & Technology, January 2016, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  57. Mechanistic insight into the pyridine enhanced α-selectivity in alkyne hydrothiolation catalysed by quinolinolate–rhodium(i)–N-heterocyclic carbene complexes

    Article • Catalysis Science & Technology, January 2016, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  58. Oxidation and β-Alkylation of Alcohols Catalysed by Iridium(I) Complexes with Functionalised N-Heterocyclic Carbene Ligands

    Article • Chemistry - A European Journal, October 2015, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  59. Efficient Rhodium-Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines

    Article • Chemistry - A European Journal, October 2015, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  60. Synthesis of Titanium and Zirconium Complexes with 2-­Pyridonate and 2, 6-Pyridinedithiolate Ligands

    Article • Zeitschrift für anorganische und allgemeine Chemie, August 2015, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  61. Grafting of Copper(I)-NHC Species on MCM-41: Homogeneous versus Heterogeneous Catalysis

    Article • ChemCatChem, July 2015, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  62. In Honour of the 70th Birthday of Professor Luis A. Oro

    Article • ChemCatChem, June 2015, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  63. Graphene–NHC–iridium hybrid catalysts built through –OH covalent linkage

    Article • Carbon, March 2015, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  64. Mechanistic Insights into Transfer Hydrogenation Catalysis by [Ir(cod)(NHC)2]+ Complexes with Functionalized N-Heterocyclic Carbene Ligands

    Article • Organometallics, February 2015, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  65. Preferential α-Hydrosilylation of Terminal Alkynes by Bis-N-Heterocyclic Carbene Rhodium(III) Catalysts

    Article • Advanced Synthesis & Catalysis, January 2015, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  66. Orthometallation of N-substituents at the NHC ligand of [Rh(Cl)(COD)(NHC)] complexes: its role in the catalytic hydrosilylation of ketones

    Article • Catalysis Science & Technology, January 2015, Royal Society of Chemistry

    Dr Francisco J Fernández-Alvarez, Prof. Dr. Jesús J. Pérez-Torrente

  67. Pyridine versus acetonitrile coordination in rhodium–N-heterocyclic carbene square-planar complexes

    Article • Dalton Transactions, January 2015, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  68. A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  69. Tuning PCP–Ir complexes: the impact of an N-heterocyclic olefin

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  70. Intramolecular C–H oxidative addition to iridium(i) triggered by trimethyl phosphite in N,N′-diphosphanesilanediamine complexes

    Article • Dalton Transactions, January 2015, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  71. Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups

    Article • Organometallics, December 2014, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  72. Catalytic Hydrodechlorination of Benzyl Chloride Promoted by Rh-N-heterocyclic Carbene Catalysts

    Article • ChemSusChem, December 2014, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  73. Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling ofN-Vinylpyrazoles with Alkynes via C–H Activation

    Article • ACS Catalysis, October 2014, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  74. Selective CH Bond Functionalization of 2-(2-Thienyl)pyridine by a Rhodium N-Heterocyclic Carbene Catalyst

    Article • ChemCatChem, September 2014, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  75. gem-Selective Cross-Dimerization and Cross-Trimerization of Alkynes with Silylacetylenes Promoted by a Rhodium-Pyridine-N-Heterocyclic Carbene Catalyst

    Article • ChemCatChem, July 2014, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  76. Hydride-Rhodium(III)-N-Heterocyclic Carbene Catalysts for Vinyl-Selective H/D Exchange: A Structure-Activity Study

    Article • Chemistry - A European Journal, June 2014, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  77. Iridium-Catalyzed Hydrogen Production from Hydrosilanes and Water

    Article • ChemCatChem, April 2014, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  78. Dinuclear Pyridine-4-thiolate-Bridged Rhodium and Iridium Complexes as Ditopic Building Blocks in Molecular Architecture

    Article • Inorganic Chemistry, January 2014, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  79. Intramolecular C–H Oxidative Addition to Iridium(I) in Complexes Containing a N,N′-Diphosphanosilanediamine Ligand

    Article • Inorganic Chemistry, January 2014, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  80. Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation

    Article • Catalysis Science & Technology, January 2014, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  81. Synthesis and dynamic behaviour of zwitterionic [M(η6-C6H5-BPh3)(coe)2] (M = Rh, Ir) cyclooctene complexes

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  82. An Alternative Mechanistic Paradigm for the β‐ Z Hydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle

    Article • Chemistry - A European Journal, November 2013, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  83. Hydroxo–Rhodium–N-Heterocyclic Carbene Complexes as Efficient Catalyst Precursors for Alkyne Hydrothiolation

    Article • ACS Catalysis, November 2013, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  84. ONO Dianionic Pincer-Type Ligand Precursors for the Synthesis of σ,π-Cyclooctenyl Iridium(III) Complexes: Formation Mechanism and Coordination Chemistry

    Article • Organometallics, November 2013, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  85. Unsaturated Iridium(III) Complexes Supported by a Quinolato–Carboxylato ONO Pincer-Type Ligand: Synthesis, Reactivity, and Catalytic C–H Functionalization

    Article • Organometallics, November 2013, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  86. Pyridine-Enhanced Head-to-Tail Dimerization of Terminal Alkynes by a Rhodium-N-Heterocyclic-Carbene Catalyst

    Article • Chemistry - A European Journal, September 2013, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  87. Enhanced Hydrogen-Transfer Catalytic Activity of Iridium N-Heterocyclic Carbenes by Covalent Attachment on Carbon Nanotubes

    Article • ACS Catalysis, May 2013, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  88. Labile Rhodium(I)–N-Heterocyclic Carbene Complexes

    Article • Organometallics, April 2013, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  89. A New Access to 4 H-Quinolizines from 2-Vinylpyridine and Alkynes Promoted by Rhodium-N-Heterocyclic-Carbene Catalysts

    Article • Chemistry - A European Journal, February 2013, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  90. Bis(hydrosulfido)-bridged dinuclear rhodium(i) complexes as a platform for the synthesis of trinuclear sulfido aggregates with the core [MRh2(μ3-S2)] (M = Rh, Ir, Pd, Pt, Ru)

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  91. The Emergence of Transition-Metal-Mediated Hydrothiolation of Unsaturated Carbon-Carbon Bonds: A Mechanistic Outlook

    Article • Angewandte Chemie, December 2012, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  92. Mechanistic Studies on the Catalytic Oxidative Amination of Alkenes by Rhodium(I) Complexes with Hemilabile Phosphines

    Article • ChemCatChem, October 2012, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  93. Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation

    Article • Angewandte Chemie, September 2012, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  94. Synthesis of Poly(silyl ether)s by Rhodium(I)-NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis

    Article • ChemCatChem, September 2012, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  95. Steric Effects in the Oxidative Addition of MeI to a Sulfido-Bridged ZrRh2 Early–Late Heterobimetallic Compound

    Article • Organometallics, August 2012, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  96. Synthesis, structure, and kinetic studies on [RuCl2(NCCH3)2(cod)]

    Article • Journal of Coordination Chemistry, July 2012, Taylor & Francis

    Prof. Dr. Jesús J. Pérez-Torrente

  97. Rhodium(I) Complexes with Hemilabile Phosphines: Rational Design for Efficient Oxidative Amination Catalysts

    Article • ChemCatChem, May 2012, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  98. Ligand-Controlled Regioselectivity in the Hydrothiolation of Alkynes by Rhodium N-Heterocyclic Carbene Catalysts

    Article • Journal of the American Chemical Society, May 2012, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  99. A synthon for a 14-electron Ir(iii) species: catalyst for highly selective β-(Z) hydrosilylation of terminal alkynes

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  100. Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts

    Article • Organometallics, October 2011, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  101. Synthesis of a Square-Planar Rhodium Alkylidene N-Heterocyclic Carbene Complex and Its Reactivity Toward Alkenes

    Article • Organometallics, October 2011, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  102. Hydride Mobility in Trinuclear Sulfido Clusters with the Core [Rh3(μ-H)(μ3-S)2]: Molecular Models for Hydrogen Migration on Metal Sulfide Hydrotreating Catalysts

    Article • Chemistry - A European Journal, June 2011, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  103. Mild and Selective H/D Exchange at the β Position of Aromatic α-Olefins by N-Heterocyclic Carbene-Hydride-Rhodium Catalysts

    Article • Angewandte Chemie, March 2011, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  104. Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes

    Article • Dalton Transactions, January 2011, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  105. Branched Poly(phenylacetylene)

    Article • Macromolecules, August 2010, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  106. Hydroformylation of Synthetic Naphtha Catalyzed by a Dinuclear gem-Dithiolato-Bridged Rhodium(I) Complex~!2009-09-28~!2009-12-18~!2010-04-23~!

    Article • The Open Catalysis Journal, May 2010, Bentham Science Publishers

    Prof. Dr. Jesús J. Pérez-Torrente

  107. Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene

    Article • Chemical Communications, January 2010, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  108. Cationic Rhodium Complexes with Hemilabile Phosphine Ligands as Polymerization Catalyst for High Molecular Weight Stereoregular Poly(phenylacetylene)

    Article • Macromolecules, November 2009, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  109. On the Synthesis and Chemical Behaviour of the Elusive Bis(hydrosulfido)-Bridged Dinuclear Rhodium(I) Complexes [{Rh(μ-SH)(CO)(PR3)}2]

    Article • Chemistry - A European Journal, October 2009, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  110. Synthesis of Tetranuclear Rhodium and Iridium Complexes Directed by 6-Mercaptopyridin-2-ol: Electrochemical Behavior, Chemical Oxidation, and Coordination Chemistry

    Article • Inorganic Chemistry, August 2009, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  111. Convenient Methods for the Synthesis of a Library of Hemilabile Phosphines

    Article • Synthesis, April 2009, Thieme Publishing Group

    Prof. Dr. Jesús J. Pérez-Torrente

  112. Hydroformylation of Hex-1-ene by a Dinuclear gem-Dithiolato-bridged Rhodium Catalyst Under CO/H2O Conditions

    Article • Catalysis Letters, March 2009, Springer Science + Business Media

    Prof. Dr. Jesús J. Pérez-Torrente

  113. Hydroformylation of oct-1-ene catalyzed by dinuclear gem-dithiolato-bridged rhodium(I) complexes and phosphorus donor ligands

    Article • Journal of Molecular Catalysis A Chemical, March 2009, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  114. Synthesis, Structural Characterization, and Ligand Replacement Reactions ofgem-Dithiolato-Bridged Rhodium and Iridium Complexes

    Article • Inorganic Chemistry, July 2008, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  115. Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts

    Article • Organometallics, January 2008, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  116. Novelgem-Dithiolato-Bridged Rhodium Hydroformylation Catalysts: Bridging the Gap in Dinuclear Rhodium Thiolate Chemistry

    Article • European Journal of Inorganic Chemistry, December 2007, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  117. The Anions [Cptt2Zr(μ-S)2M(CO)2]-(M = Rh, Ir) as Versatile Precursors for the Synthesis of Sulfido-Bridged Early−Late Heterotrimetallic (ELHT) Compounds†

    Article • Organometallics, December 2007, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  118. Reversible Opening of the Triangular Structure of a Sulfido-Bridged ZrRh2Early−Late Heterobimetallic Complex Induced by Bis-(diphenylphosphino)methane

    Article • Organometallics, May 2007, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  119. Effects of the Heterocycle and Its Substituents on Structure and Fluxionality in Rhodium(I) and Iridium(I) Complexes with the Hindered Thiolates 6-tert-Butylpyridine-2-thiolate and 1-Alkyl-4-tert-butylimidazole-2-thiolate (alkyl = methyl andtert-butyl)

    Article • Organometallics, August 2006, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  120. Flexible Building Blocks for Transition Metal Early−Late Chemistry. Synthesis of Heterobimetallic Tetranuclear Metallomacrocycles

    Article • Organometallics, November 2005, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  121. Tetranuclear [Rh4(μ-PyS2)2(diolefin)4] Complexes as Building Blocks for New Inorganic Architectures:  Synthesis of Coordination Polymers and Heteropolynuclear Complexes with Electrophilic d8and d10Metal Fragments

    Article • Inorganic Chemistry, February 2004, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  122. Stereoselective Oxidative Additions of Iodoalkanes and Activated Alkynes to a Sulfido-Bridged Heterotrinuclear Early−Late (TiIr2) Complex

    Article • Inorganic Chemistry, June 2003, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  123. Synthesis, Reactivity, and Catalytic Activity of Triangular ZrM2(M = Rh, Ir) Early−Late Heterobimetallic Complexes

    Article • Organometallics, March 2003, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  124. Early (Ti, Zr)-late (Rh, Ir) heteronuclear complexes with bridging sulphido ligands

    Article • Comptes Rendus Chimie, January 2003, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  125. Unexpected formation and structural characterisation of a novel rhodium B12analogue

    Article • Chemical Communications, January 2002, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  126. Synthesis of Paramagnetic Tetranuclear Rhodium and Iridium Complexes with the 2,6-Pyridinedithiolate Ligand. Redox-Induced Degradation to Diamagnetic Triiridium Compounds

    Article • Inorganic Chemistry, August 2001, American Chemical Society (ACS)

    Prof. Dr. Jesús J. Pérez-Torrente

  127. Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2= 2,6-dimercaptopyr...

    Article • CrystEngComm, January 2000, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  128. Controlling the molecular architecture of low nuclearity rhodium and iridium complexes using bridging NCX (X=N, O, S) ligands

    Article • Coordination Chemistry Reviews, October 1999, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  129. Controlled Synthesis of Early-Late Zr-Ir-Rh Heterotrimetallic Compounds by Metal Exchange Reactions

    Article • Angewandte Chemie, September 1999, Wiley

    Prof. Dr. Jesús J. Pérez-Torrente

  130. Bimetallic reactivity: unusual change in the coordination mode of the bridging ligands arising from an oxidative addition process

    Article • Journal of Organometallic Chemistry, November 1994, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  131. The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond

    Article • Journal of Organometallic Chemistry, May 1994, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  132. Chemical evidence of polynuclear intermediates in a ligand redistribution equilibrium between dinuclear rhodium complexes. X-ray structure of [Rh2(μ-bzta)2(CO)3(PPh3)] (bzta = benzothiazole-2-thiolate)

    Article • Journal of Organometallic Chemistry, August 1993, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  133. Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium

    Article • Journal of Organometallic Chemistry, February 1993, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  134. Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium

    Article • Journal of Organometallic Chemistry, February 1993, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  135. Trinuclear aggregates of rhodium and iridium supported by thiolate bridges: synthesis and crystal structure

    Article • Journal of the Chemical Society Dalton Transactions, January 1992, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  136. Atropisomerism in asymmetric cis-diphosphine arylplatinum complexes

    Article • Tetrahedron Letters, January 1992, Elsevier

    Prof. Dr. Jesús J. Pérez-Torrente

  137. Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)]...

    Article • Journal of the Chemical Society Dalton Transactions, January 1991, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  138. Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3

    Article • Journal of the Chemical Society Dalton Transactions, January 1990, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  139. Rhodium complexes of the binucleating ligands pyridine-2-thiolate and benzothiazole-2-thiolate. Crystal structures of [{Rh(µ-SC5H4N)(CO)2}2] and [{Rh(µ-SC5H4N)(tfbb)}2]·Me

    Article • Journal of the Chemical Society Dalton Transactions, January 1989, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente

  140. Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H

    Article • Journal of the Chemical Society Chemical Communications, January 1986, Royal Society of Chemistry

    Prof. Dr. Jesús J. Pérez-Torrente